Copolymer foam with polyamide blocks and polyether blocks

Patent metadata

Field	Value
Publication number	US-11008464-B2
Application number	US-201716071351-A
Country	US
Kind code	B2
Filing date	Jan 27, 2017
Priority date	Jan 29, 2016
Publication date	May 18, 2021
Grant date	May 18, 2021

Abstract

The invention relates to a non-cross-linked copolymer foam with polyamide blocks and polyether blocks, wherein: the polyamide blocks of the copolymer have an average molar mass of from 200 to 1,500 g/mol; the polyether blocks of the copolymer have an average molar mass of from 800 to 2,500 g/mol; and the weight ratio of the polyamide blocks to the polyether blocks of the copolymer is from 0.1 to 0.9. The invention also relates to a method for manufacturing said foam and items manufactured from said foam.

First claim

What is claimed is:

1. A non-crosslinked polyamide polyether block copolymer foam, comprising:
polyamide blocks having a number average molecular weight of from 200 to 1500 g/mol; and
polyether blocks having a number average molecular weight of from 800 to 2500 g/mol,
wherein a mass ratio of the polyamide blocks relative to the polyether blocks of the copolymer is from 0.1 to 0.9, and
wherein the foam has a rebound resilience greater than or equal to 55%.

2. The foam of claim 1 , wherein:
the polyamide blocks have a number average molecular weight of from 400 to 1000 g/mol; and
the polyether blocks have a number average molecular weight of 1000 to 2000 g/mol,
wherein the mass ratio of the polyamide blocks relative to the polyether blocks of the copolymer is from 0.3 to 0.6.

3. The foam of claim 1 , wherein:
the polyamide blocks have a number average molecular weight of from 600 to 850 g/mol; and
the polyether blocks have a number average molecular weight of 1000 to 2000 g/mol,
wherein the mass ratio of the polyamide blocks relative to the polyether blocks of the copolymer is from 0.3 to 0.6.

4. The foam of claim 1 , wherein the polyamide blocks of the copolymer include at least one member selected from the group consisting of polyamide 6, polyamide 11, polyamide 12, polyamide 6.10, polyamide 10.10, and polyamide 10.12.

5. The foam of claim 2 , wherein the polyamide blocks of the copolymer include at least one member selected from the group consisting of polyamide 6, polyamide 11, polyamide 12, and polyamide 6.10.

6. The foam of claim 1 , wherein the polyether blocks of the copolymer include blocks of polyethylene glycol.

7. The foam of claim 1 , wherein the polyether blocks of the copolymer include blocks of polytetrahydrofuran.

8. The foam of claim 1 , wherein the foam has a density less than or equal to 800 kg/m 3 .

9. The foam of claim 1 , wherein the foam has a density less than or equal to 600 kg/m 3 .

10. The foam of claim 1 , wherein the foam has a density less than or equal to 400 kg/m 3 .

11. The foam of claim 1 , wherein the foam has a density less than or equal to 300 kg/m 3 .

12. The foam of claim 1 , further including at least one additive, selected from the group consisting of a copolymer of ethylene and vinyl acetate, a copolymer of ethylene and acrylate, and a copolymer of ethylene and of alkyl(meth)acrylate.

13. A method for manufacturing a foam of non-crosslinked polyamide polyether block copolymer, comprising:
a) mixing the copolymer in the molten state with an expansion agent, the copolymer including
polyamide blocks having a number average molecular weight of from 200 to 1500 g/mol; and
polyether blocks having a number average molecular weight of from 800 to 2500 g/mol, wherein a mass ratio of the polyamide blocks relative to the polyether blocks of the copolymer is from 0.1 to 0.9;
b) injecting the mixture of copolymer and expansion agent into a mold; and
c) foaming the copolymer and expansion agent mixture.

14. A method for manufacturing a foam of non-crosslinked polyamide polyether block copolymer according to claim 13 , further comprising adding and mixing at least one additive with the molten copolymer and the expansion agent and foaming the copolymer, expansion agent, and additive mixture.

15. The method of claim 13 , wherein the expansion agent is at least one physical expansion agent selected from the group consisting of dinitrogen, carbon dioxide, hydrocarbons, chlorofluorocarbons, hydrochlorocarbon, hydrofluorocarbons and hydrochlorofluorocarbons.

16. The method of claim 13 , comprising foaming the mixture by opening the mold.

17. An article that includes a foam, the foam comprising:
polyamide blocks having a number average molecular weight of from 200 to 1500 g/mol; and
polyether blocks having a number average molecular weight of from 800 to 2500 g/mol, wherein a mass ratio of the polyamide blocks relative to the polyether blocks of the copolymer is from 0.1 to 0.9; and
wherein the foam has a rebound resilience greater than or equal to 55%.

18. The article according to claim 17 , wherein the article is selected from the group consisting of a sole of a sport shoe, a ball, a glove, a personal protective article, a pad for a rail, an automobile part, a construction part, and electrical and electronic equipment parts.

Assignees

• Arkema France

Inventors

• Cocquet Clio
• Pineau Quentin
• Loyen Karine
• Fernagut François
• Cheminet Helena

Classifications

• C08G69/40 Primary

  Polyamides containing oxygen in the form of ether groups (C08G69/12, C08G69/32 take precedence) · CPC title

• C08J9/147

  containing carbon and halogen atoms only · CPC title

• C08J2431/04

  Homopolymers or copolymers of vinyl acetate · CPC title

• C08J9/0061

  characterized by the use of several polymeric components · CPC title

• C08J2433/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title