Filters comprising SiC membranes incorporating nitrogen

Patent metadata

Field	Value
Publication number	US-11007485-B2
Application number	US-201515536874-A
Country	US
Kind code	B2
Filing date	Dec 18, 2015
Priority date	Dec 18, 2014
Publication date	May 18, 2021
Grant date	May 18, 2021

Abstract

A filter for the filtration of a fluid, such as a liquid, includes or is composed of a support element made of a porous ceramic material, the element exhibiting a tubular or parallelepipedal shape delimited by an external surface and including, in its internal portion, a set of adjacent channels with axes parallel to one another and separated from one another by walls of the porous inorganic material, in which at least a portion of the channels and/or at least a portion of the external surface are covered with a porous separating membrane layer, wherein the separating membrane layer is made of a material essentially composed of silicon carbide (SiC), and the content by weight of elemental nitrogen of the layer constituting the porous separating membrane layer is between 0.1% and 2%.

First claim

The invention claimed is:

1. A filter for the filtration of a fluid, comprising or composed of a support element made of a porous ceramic material, said support element exhibiting a tubular or parallelepipedal shape delimited by an external surface and comprising, in its internal portion, a set of adjacent channels with axes parallel to one another and separated from one another by walls of said porous ceramic material, in which:
at least a portion of said channels are covered on their internal surface with a first porous separating membrane layer and/or at least a portion of said external surface is covered with a second porous separating membrane layer;
wherein:
said first and second porous separating membrane layers are made of a material consisting essentially of recrystallized silicon carbide (SiC), elemental nitrogen and elemental oxygen, and
a content by weight of elemental nitrogen of the first and second porous separating membrane layers is between 0.1% and 2%,
a porosity of the first and second porous separating membrane layers is between 30 and 70%,
a median pore diameter of the first and second porous separating membrane layers is between 10 nanometers and 5 micrometers,
the recrystallized SiC represents more than 97% of the weight of the material constituting the first and second porous separating membrane layers,
each of the first and second porous separating membrane layers is made of SiC grains and elemental nitrogen is present both in the SiC grains as well as at boundaries of the SiC grains, and
wherein a content by weight of elemental oxygen of the material constituting each of the first and second porous separating membrane layers is less than or equal to 0.5%.

2. The filter as claimed in claim 1 , wherein the content by weight of elemental nitrogen of each of the first and second porous separating membrane layers is between 0.1% and 1.5%.

3. The filter as claimed in claim 1 , wherein a median size of SiC grains in said material consisting essentially of silicon carbide, elemental nitrogen and oxygen is between 20 nanometers and 10 micrometers.

4. The filter as claimed in claim 1 , wherein the porous support element comprises or is composed of a material selected from the group consisting of silicon carbide, SiC, recrystallized SiC, silicon nitride, silicon oxynitride, silicon aluminum oxynitride or a combination of these.

5. The filter as claimed in claim 1 , wherein an open porosity of the porous ceramic material constituting the porous support element is between 20 and 60%, a median pore diameter of the porous ceramic material constituting the porous support element being between 5 and 50 micrometers.

6. The filter as claimed in claim 1 , further comprising one or more primer layers arranged between the porous ceramic material constituting the support element and the material constituting each of the first and second porous separating membrane layers.

7. The filter as claimed in claim 1 , wherein the fluid is a liquid.

8. A process for the manufacture of a separating membrane layer, in a tangential or frontal filter for the filtration of a fluid, comprising or composed of a support element made of a porous ceramic material, said support element exhibiting a tubular or parallelepipedal shape delimited by an external surface and comprising, in its internal portion, a set of adjacent channels with axes parallel to one another and separated from one another by walls of said porous ceramic material,
wherein
at least a portion of said channels are covered on their internal surface with a first porous separating membrane layer and/or at least a portion of said external surface is covered with a second porous separating membrane layer,
said first and second porous separating membrane layers are made of a material consisting essentially of recrystallized silicon carbide (SiC), elemental nitrogen and elemental oxygen,
a content by weight of elemental nitrogen of the first and second porous separating membrane layers is between 0.1% and 2%,
a porosity of the first and second porous separating membrane layers is between 30 and 70%,
a median pore diameter of the first and second porous separating membrane layers is between 10 nanometers and 5 micrometers,
the recrystallized SiC represents more than 97% of the weight of the material constituting the first and second porous separating membrane layers,
each of the first and second porous separating membrane layers is made of SiC grains and elemental nitrogen is present both in the SiC grains as well as at boundaries of the SiC grains, and
a content by weight of elemental oxygen of the material constituting each of the first and second porous separating membrane layers is less than or equal to 0.5%,

the process comprising:
preparing a slip from a powder of silicon carbide particles having a median size of between 20 nanometers and 10 micrometers,
applying said slip to the support element under conditions which make possible the formation of a thin layer of the slip on an internal part of the channels of said filter,
drying and then firing under an atmosphere containing nitrogen at a temperature of between 1400° C. and 2000° C. and for a time sufficient to obtain a porous separating membrane layer on their internal surface of said channels, said porous separating membrane layer consisting essentially of recrystallized silicon carbide (SiC), elemental nitrogen and elemental oxygen, and a content by weight of elemental nitrogen in said layer being between 0.1% and 2%.

9. A method comprising utilizing a filter for the filtration of a fluid, the filter comprising or composed of a support element made of a porous ceramic material, said support element exhibiting a tubular or parallelepipedal shape delimited by an external surface and comprising, in its internal portion, a set of adjacent channels with axes parallel to one another and separated from one another by walls of said porous ceramic material, in which:
at least a portion of said channels are covered on their internal surface with a first porous separating membrane layer and/or at least a portion of said external surface is covered with a second porous separating membrane layer;
wherein:
said first and second porous separating membrane layers are made of a material consisting essentially of recrystallized silicon carbide (SiC), elemental nitrogen and elemental oxygen, and
a content by weight of elemental nitrogen of the first and second porous separating membrane layers is between 0.1% and 2%,
a porosity of the first and second porous separating membrane layers is between 30 and 70%,
a median pore diameter of the first and second porous separating membrane layers is between 10 nanometers and 5 micrometers,
the recrystallized SiC represents more than 97% of the weight of the material constituting the first and second porous separating membrane layers,
each of the first and second porous separating membrane layers is made of SiC grains and elemental nitrogen is present both in the SiC grains as well as at boundaries of the SiC grains, and
a content by weight of elemental oxygen of the material constituting each of the first and second porous separating membrane layers is less than or equal to 0.5%.

10. The method as claimed in claim 9 , wherein the filter is utilized for filtering an aqueous liquid.

Assignees

• Saint Gobain Ct Recherches

Inventors

• Rodrigues Fabiano
• Sant Jérôme
• Rossiquet Gilles

Classifications

• B01D46/24492

  Pore diameter · CPC title

• B01D46/24491

  Porosity · CPC title

• B01D46/2429

  of the honeycomb walls or cells · CPC title

• B01D71/0215

  Silicon carbide; Silicon nitride; Silicon oxycarbide · CPC title

• B01D67/00416

  by deposition by filtration through a support or base layer · CPC title