Block graft copolymer binders and their use in silicon-containing anodes of lithium-ion batteries

Patent metadata

Field	Value
Publication number	US-11005101-B2
Application number	US-201815958181-A
Country	US
Kind code	B2
Filing date	Apr 20, 2018
Priority date	Jan 19, 2018
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

A graft copolymer composition comprising the following structure:

wherein: A x represents a polymer backbone having a number of polymerized monomer units x; [B y ] represents a multiplicity of a graft polymer side chain having a number of polymerized monomer units y, and at least a portion of the monomer units in B y contains a group —C(O)OM, with M independently selected from H and alkali metals; [C] represents a multiplicity of positions on the polymer backbone A x where the graft polymer side chain B or any other graft polymer side chain is not attached; the subscript w represents a grafting density of the group B y , wherein w is an integer within a range of 10-50%; and the subscript z represents a density of the group C, wherein z=(100−w) %. The invention is also directed to lithium-ion batteries in which the above-described composition is incorporated in an anode of the battery.

First claim

What is claimed is:

1. A graft copolymer composition comprising the following structure:

wherein:
A x represents a polymer backbone having a number of polymerized monomer units x, wherein x is at least 20;
[B y ] represents a multiplicity of a graft polymer side chain having a number of polymerized monomer units y, wherein y is an integer of at least 10, and at least a portion of the monomer units in B y contains a group —C(O)OM, wherein M is independently selected in each occurrence from H and alkali metals;
[C] represents a multiplicity of functional groups on the polymer backbone A x selected from the group consisting of hydroxy, carboxylic acid, carboxylate, carboxylic acid ester, amino groups, and precursors of any of the foregoing functional groups, and wherein the graft polymer side chain B or any other graft polymer side chain is not attached to said functional groups;
the subscript w represents a grafting density of the group B y , wherein w is an integer within a range of 10-50%; and
the subscript z represents a density of the group C, wherein z=(100−w) %.

2. The graft copolymer composition of claim 1 , wherein w is an integer within a range of 10-30%.

3. The graft copolymer composition of claim 1 , wherein y is an integer within a range of 10-500.

4. The graft copolymer composition of claim 1 , wherein w is an integer within a range of 10-30%, and y is an integer within a range of 10-500.

5. The graft copolymer composition of claim 1 , wherein at least 10% of M is alkali metal.

6. The graft copolymer composition of claim 1 , wherein A x represents chitosan.

7. The graft copolymer composition of claim 6 , wherein w is an integer within a range of 10-30%.

8. The graft copolymer composition of claim 6 , wherein y is an integer within a range of 10-500.

9. The graft copolymer composition of claim 6 , wherein w is an integer within a range of 10-30%, and y is an integer within a range of 10-100.

10. A lithium-ion battery comprising:
(a) an anode comprising silicon nanoparticles and a graft copolymer composition comprising the following structure:

wherein:
A x represents a polymer backbone having a number of polymerized monomer units x, wherein x is at least 20;
[B y ] represents a multiplicity of a graft polymer side chain having a number of polymerized monomer units y, wherein y is an integer of at least 10, and at least a portion of the monomer units in B y contains a group —C(O)OM, wherein M is independently selected in each occurrence from H and alkali metals;
[C] represents a multiplicity of functional groups on the polymer backbone A x selected from the group consisting of hydroxy, carboxylic acid, carboxylate, carboxylic acid ester, amino groups, and precursors of any of the foregoing functional groups, and wherein the graft polymer side chain B or any other graft polymer side chain is not attached to said functional groups;
the subscript w represents a grafting density of the group B y , wherein w is an integer within a range of 10-50%; and
the subscript z represents a density of the group C, wherein z=(100−w) %;
(b) a cathode; and
(c) a lithium-containing electrolyte medium in contact with said anode and cathode.

11. The lithium-ion battery of claim 10 , wherein said anode further comprises graphite.

12. The lithium-ion battery of claim 10 , wherein said cathode is selected from lithium metal and lithium-intercalated materials.

13. The lithium-ion battery of claim 10 , wherein w is an integer within a range of 10-30%.

14. The lithium-ion battery of claim 10 , wherein y is an integer within a range of 10-500.

15. The lithium-ion battery of claim 10 , wherein w is an integer within a range of 10-30%, and y is an integer within a range of 10-100.

16. The lithium-ion battery of claim 10 , wherein at least 10% of M is alkali metal.

17. The lithium-ion battery of claim 10 , wherein A x represents chitosan.

18. The lithium-ion battery of claim 17 , wherein w is an integer within a range of 10-30%.

19. The lithium-ion battery of claim 17 , wherein y is an integer within a range of 10-500.

20. The lithium-ion battery of claim 17 , wherein w is an integer within a range of 10-30%, and y is an integer within a range of 10-500.

Assignees

• Ut Battelle Llc

Inventors

• Saito Tomonori
• Cao Pengfei
• Nanda Jagjit
• Abdelmalak Michael Naguib

Classifications

• C08F251/00

  Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof · CPC title

• C08B37/003 Primary

  Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof · CPC title

• C08F2438/03

  Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX] · CPC title

• C08F293/005

  using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent · CPC title

• H01M2004/027

  Negative electrodes · CPC title