Treatment agent for image recording, set of ink and treatment agent for image recording, and recording method
US-10774468-B2 · Sep 15, 2020 · US
US11001964B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11001964-B2 |
| Application number | US-201816059472-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 9, 2018 |
| Priority date | Sep 29, 2017 |
| Publication date | May 11, 2021 |
| Grant date | May 11, 2021 |
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There is provided a treatment agent applicable to a recording surface of a recording medium which is recording paper or fabric. The treatment agent contains: a non-cationic sizing agent; and at least one cationic substance which is selected from the group consisting of: a cationic polymer capable of forming a flexible film in a case that the cationic polymer is dried, a cationic surfactant, a polyvalent metal salt and a polyvalent metal ion.
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What is claimed is: 1. A treatment agent applicable to a recording surface of a recording medium which is recording paper or fabric, the treatment agent comprising: a non-cationic sizing agent; and at least one cationic substance which is selected from the group consisting of: a cationic polymer capable of forming a flexible film in a case that the cationic polymer is dried, and a cationic surfactant, wherein the cationic polymer is a cationic polymer having a urethane structure or a water-soluble polymer having diallylamines represented by the following formula (2) as a constituent of the water-soluble polymer: wherein in the formula (2), R 2 and R 3 are each a substituted or non-substituted, straight-chain or branched-chain alkyl group, and the R 2 and the R 3 are identical with each other or different from each other; X − is an anion, and wherein a number of the constituent represented by the formula (2) in the water-soluble polymer is in a range of 5 to 1000. 2. The treatment agent according to claim 1 , wherein a blending amount of the cationic substance in an entire amount of the treatment agent is in a range of 1% by weight to 15% by weight. 3. The treatment agent according to claim 1 , wherein a blending amount of the cationic substance in an entire amount of the treatment agent is in a range of 10% by weight to 15% by weight. 4. The treatment agent according to claim 1 , wherein the cationic polymer is the cationic polymer having a urethane structure. 5. The treatment agent according to claim 4 , wherein a ratio of the urethane structure is not less than 10% by weight in the cationic polymer having the urethane structure. 6. The treatment agent according to claim 4 , wherein the treatment agent contains an emulsion of the cationic polymer having the urethane structure. 7. The treatment agent according to claim 4 , wherein the cationic polymer having the urethane structure further has at least one of an acrylic structure and a styrene structure. 8. The treatment agent according to claim 7 , wherein the cationic polymer having the urethane structure has the acrylic structure. 9. The treatment agent according to claim 4 , wherein the urethane structure is obtained by: an aliphatic isocyanate; and a polyether polyol or polyester polyol. 10. The treatment agent according to claim 1 , wherein the cationic polymer is the water-soluble polymer having diallylamines represented by the formula (2) as a constituent of the water-soluble polymer. 11. The treatment agent according to claim 10 , wherein the R 2 and the R 3 in the formula (2) are each a methyl group; and the X − is a methylsulfate ion or a chloride ion. 12. The treatment agent according to claim 1 , wherein a blending amount of the non-cationic sizing agent in an entire amount of the treatment agent is in a range of 0.2% by weight to 10% by weight. 13. The treatment agent according to claim 1 , wherein a blending amount of the non-cationic sizing agent in an entire amount of the treatment agent is in a range of 1% by weight to 5% by weight. 14. The treatment agent according to claim 1 , wherein the non-cationic sizing agent is at least one selected from the group consisting of: sodium alginate, pregelatinized starch and carboxymethyl cellulose. 15. The treatment agent according to claim 1 , wherein a ratio (X/Y) of a blending amount (X: % by weight) of the cationic substance to a blending amount (Y: % by weigh) of the non-cationic sizing agent is in a range of 3.3 to 5. 16. The treatment agent according to claim 1 , wherein in a case that the recording medium is the recording paper, an application amount of the treatment agent per unit area of the recording surface is not more than 1.3 mg/cm 2 ; and in a case that the recording medium is the fabric, the application amount of the treatment agent per the unit area of the recording surface is in a range of 5.0 mg/cm 2 to 48 mg/cm 2 . 17. A treatment agent applicable to a recording surface of a recording medium which is recording paper or fabric, the treatment agent comprising: a non-cationic sizing agent; and at least one cationic substance which is selected from the group consisting of: a cationic polymer capable of forming a flexible film in a case that the cationic polymer is dried, a cationic surfactant, a polyvalent metal salt and a polyvalent metal ion, wherein in a case that the recording medium is the fabric, the non-cationic sizing agent applied to the recording surface is washed by water. 18. An ink set comprising: a water-based ink for ink-jet recording containing an anionic coloring agent and water; and the treatment agent as defined in claim 1 .
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