Composite body

Patent metadata

Field	Value
Publication number	US-11001933-B2
Application number	US-201515575587-A
Country	US
Kind code	B2
Filing date	Dec 11, 2015
Priority date	May 18, 2015
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

A composite body has a cermet member, a metal member and an intermediate member. The cermet member includes a cermet oxide phase and a cermet metal phase. The cermet oxide phase contains a Ni-containing oxide or an Fe-containing oxide. The cermet metal phase contains Ni. The intermediate layer contains Cu. The mass proportions of Cu in the cermet metal phase at points which are spaced apart by 10, 50, 100 and 1000 μm from the interface between the cermet member and the intermediate layer to the cermet member side are denoted by C10, C50, C100 and C1000 (mass %). When the mass proportions of Cu in the cermet oxide phase at points which are spaced apart by 10 and 100 μm from the interface to the cermet member side are denoted by M10 and M100 (mass %), C10>C50>C100>C1000, and 5>M10−M100>−5.

First claim

The invention claimed is:

1. A composite body comprising a cermet member, a metal member, and an intermediate layer, wherein:
the cermet member includes a cermet oxide phase and a cermet metal phase,
the cermet oxide phase includes an oxide including Ni or an oxide including Fe,
the cermet metal phase includes Ni,
the intermediate layer includes Cu, and
when mass ratios of Cu in the metal phase at positions away by 10, 50, 100, 1000 μm from a boundary between the cermet member and the intermediate layer towards the cermet member are defined as C10, C50, C100 and C1000 (mass %), and
when mass ratios of Cu in the oxide phase at positions away by 10 and 100 μm from the boundary towards the cermet member side are defined as M10 and M100 (mass %), then the following Equation 1 and Equation 2 are satisfied simultaneously:
C 10> C 50> C 100> C 1000 (mass %):  (Equation 1)

5> M 10− M 100>−5 (mass %):  (Equation 2).

2. The composite body as set forth in claim 1 , wherein the metal member at least includes Ni.

3. The composite body as set forth in claim 1 , wherein when the mass ratio of Ni and Cu in the intermediate layer are expressed in terms of percentage, Ni is 10<Ni<70 (mass %) and Cu is 30<Cu<90 (mass %).

4. The composite body as set forth in claim 1 , wherein the intermediate layer at least comprises a first intermediate layer and a second intermediate layer,
the first intermediate layer is bonded to the cermet member,
the first intermediate layer at least includes Cu as a first metal,
the second intermediate layer at least includes M2 as a second metal,
a melting point of Cu as the first metal is lower than the melting point of M2 as the second metal,
a mass concentration of Cu in the first intermediate layer is higher than the mass concentration of Cu in the second intermediate layer, and
the mass concentration of M2 in the second intermediate layer is higher than the mass concentration of M2 in the first intermediate layer.

5. The composite body as set forth in claim 4 , wherein the first intermediate layer is also bonded to the second intermediate layer.

6. The composite body as set forth in claim 4 , wherein the second intermediate layer is also bonded to the metal member.

7. The composite body as set forth in claim 4 , wherein a mass ratio between Cu and M2 (Cu/M2) in the first intermediate layer is within the range of below Equation 3:
40/60≤ Cu/M 2≤90/10:  (Equation 3).

8. The composite body as set forth in claim 4 , wherein M2 is Ni.

9. The composite body as set forth in claim 4 , wherein the intermediate layer comprises a third intermediate layer in addition to the first intermediate layer and the second intermediate layer, and
the third intermediate layer is bonded to the metal member.

10. The composite body as set forth in claim 9 , wherein:
the mass concentration of Cu in the third intermediate layer is higher than the mass concentration of Cu in the second intermediate layer, and
the mass concentration of M2 in the third intermediate layer is lower than the mass concentration of M2 in the second intermediate layer.

11. The composite body as set forth in claim 9 , wherein the second intermediate layer is bonded to the first intermediate layer and the third intermediate layer.

12. The composite body as set forth in claim 1 , wherein the cermet oxide phase included in the cermet member at least includes an oxide of Ni.

13. The composite body as set forth in claim 1 , wherein at least part of the cermet oxide phase included in the cermet member is made of nickel ferrite.

14. The composite body as set forth in claim 1 , wherein the intermediate layer includes an intermediate oxide phase and an intermediate metal phase, and
the intermediate oxide phase includes at least one oxide of metal.

15. The composite body as set forth in claim 14 , wherein the at least one oxide of metal is selected from the oxide of metal included in the cermet oxide phase.

16. The composite body as set forth in claim 14 , wherein at a cross section face where the composite body is cut perpendicularly to the boundary between the cermet member and the intermediate member, in case a total of an area occupied by the intermediate oxide phase and an area occupied by the intermediate metal phase at an area where the intermediate oxide phase exists is 100%, then an area ratio occupied by the intermediate oxide phase is 10% to 50%.

17. The composite body as set forth in claim 14 , wherein at a cross section face where the composite body is cut perpendicularly to the boundary between the cermet member and the intermediate member, in case a total of an area occupied by an entirety of the intermediate layer exists is 100%, then 30% or less of the area is occupied by a void.

18. The composite body as set forth in claim 1 , in case an area of the cermet oxide phase at a cross section of the cermet member is S o , an area of the cermet metal phase is S m , and an area ratio between the cermet oxide phase and the cermet metal phase is S o /S m , then S o /S m , satisfies the following Equation 4:
60/40≤ S o /S m ≤90/10:  (Equation 4).

19. The composite body as set forth in claim 1 , wherein the cermet oxide phase comprises:
a spinel ferrite phase expressed by a compositional formula of Ni x Fe y M z O 4 (x+y+z=3, x≠0, y≠0, M is at least one selected from the group consisting of Al, Co, Cr, Mn, Ti, Zr, Sn, V, Nb, Ta, and Hf), and
a nickel oxide phase expressed by a compositional formula of Ni x′ Fe 1-x′ O (x′≠0), wherein in case entire the cermet member including the cermet oxide phase and the cermet metal phase is 100 mass %,
a content ratio of the spinel phase is 40 to 80 mass %,
a content ratio of the nickel oxide phase is 0 to 10 mass % (including 0 mass %), and
a content ratio of the cermet metal phase is 15 to 45 mass %.

20. The composite body as set forth in claim 19 , wherein an average composition of the spinel ferrite phase included in the cermet member is expressed by a compositional formula of Ni x1 Fe y1 M z1 O 4 (0.60≤x1≤0.90, 1.90≤y1≤2.40, 0.00≤z1≤0.20).

21. The composite body as set forth in claim 19 , wherein the nickel oxide phase is included in the cermet member, and an average composition of the nickel oxide phase is expressed by a compositional formula of Ni x′1 Fe 1-x′1 O (0.70≤x′1≤1.00).

Assignees

• Tdk Corp

Inventors

• Nakazawa Ryoma
• Yoshidome Kazuhiro

Classifications

• B32B2255/205

  Metallic coating · CPC title

• C22C29/12

  based on oxides · CPC title

• B32B2311/22

  Nickel or cobalt · CPC title

• B22F7/064

  using an intermediate powder layer · CPC title

• B22F5/00

  Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product · CPC title