Lost circulation material compositions and methods of isolating a lost circulation zone of a wellbore

Patent metadata

Field	Value
Publication number	US-10995256-B2
Application number	US-202016809892-A
Country	US
Kind code	B2
Filing date	Mar 5, 2020
Priority date	Aug 30, 2018
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

A lost circulation material (LCM) composition for sealing a lost circulation zone in a wellbore is disclosed that includes from 50 weight percent to 97 weight percent epoxy resin and from 2 weight percent to 30 weight percent curing agent. The epoxy resin may include at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, bisphenol-A-epichlorohydrin epoxy resin, or a compound having formula (OC 2 H 3 )—CH 2 —O—R 1 —O—CH 2 —(C 2 H 3 O), where R 1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms. A method for isolating a lost circulation zone using the LCM compositions is also disclosed and includes introducing a spacer fluid to the lost circulation zone, introducing the LCM composition to the lost circulation zone, and curing the LCM composition in the lost circulation zone to isolate the lost circulation zone.

First claim

What is claimed is:

1. A method of isolating a lost circulation zone of a wellbore, the method comprising
introducing a spacer fluid into the lost circulation zone;
introducing a lost circulation material (LCM) composition into the lost circulation zone, the LCM composition comprising:
from 50 weight percent to 97 weight percent epoxy resin, the epoxy resin comprising at least one of alkyl glycidyl ethers having from 12 to 14 carbon atoms, 2,3-epoxypropyl o-tolyl ether, or bisphenol-A-epichlorohydrin epoxy resin modified with an oxirane mono [(C12-C14)-alkyloxy)methyl] derivative,
where the epoxy resin has an epoxy equivalent weight of from 150 to 350 epoxy equivalents per gram; and
from 1 weight percent to 20 weight percent curing agent based on the total weight of the LCM composition; and

curing the LCM composition to form a cured LCM composition sealing the lost circulation zone.

2. The method of claim 1 where introducing the LCM composition to the lost circulation zone comprises injecting the LCM composition into the lost circulation zone.

3. The method of claim 2 where the lost circulation zone is a low-injectivity zone.

4. The method of claim 1 further comprising drilling through the cured LCM composition sealing the lost circulation zone to continue drilling the wellbore.

5. The method of claim 1 where the spacer fluid, the LCM composition, or both are introduced to the lost circulation zone through a drill string disposed within the wellbore.

6. The method of claim 1 further comprising introducing a displacement fluid after the LCM composition to displace the LCM composition into lost circulation zone.

7. The method of claim 1 where a cure time of the LCM composition is less than or equal to 3 hours.

8. The method of claim 1 where the epoxy resin comprises a combination of:
a compound having a formula (I):
(OC 2 H 3 )—CH 2 —O—R 1 —O—CH 2 —(C 2 H 3 O)  (I)

where R 1 is a hydrocarbyl having from 4 to 24 carbon atoms; and

bisphenol-A-epichlorohydrin epoxy resin modified with an oxirane mono [(C12-C14)-alkyloxy)methyl] derivative.

9. The method of claim 8 where the curing agent comprises at least one of TEPA or DETA.

10. The method of claim 9 where the composition comprises from 2 weight percent to 10 weight percent curing agent based on the total weight of the composition.

11. A method of isolating a lost circulation zone of a wellbore, the method comprising:
introducing a spacer fluid into the lost circulation zone;
introducing a lost circulation material (LCM) composition into the lost circulation zone, the LCM composition comprising:
from 50 weight percent to 97 weight percent epoxy resin, the epoxy resin comprising 2,3-epoxypropyl o-tolyl ether, where the epoxy resin has an epoxy equivalent weight of from 150 to 350 epoxy equivalents per gram; and
from 1 weight percent to 20 weight percent curing agent based on the total weight of the sealing composition; and

curing the LCM composition to form a cured LCM composition sealing the lost circulation zone.

12. The method of claim 11 where the curing agent comprises at least one of TEPA, DETA, TETA, or IPDA.

13. The method of claim 12 where the composition comprises from 2 weight percent to 20 weight percent curing agent based on the total weight of the composition.

14. The method of claim 11 where introducing the LCM composition to the lost circulation zone comprises injecting the LCM composition into the lost circulation zone.

15. The method of claim 11 where the lost circulation zone is a low-injectivity zone.

16. A method of isolating a lost circulation zone of a wellbore, the method comprising:
introducing a spacer fluid into the lost circulation zone;
introducing a lost circulation material (LCM) composition into the lost circulation zone, the LCM composition comprising:
from 50 weight percent to 97 weight percent epoxy resin, the epoxy resin bisphenol-A-epichlorohydrin epoxy resin modified with an oxirane mono [(C12-C14)-alkyloxy)methyl] derivative, where the epoxy resin has an epoxy equivalent weight of from 150 to 350 epoxy equivalents per gram; and from 1 weight percent to 20 weight percent curing agent based on the total weight of the sealing composition; and

curing the LCM composition to form a cured LCM composition sealing the lost circulation zone.

17. The method of claim 16 where introducing the LCM composition to the lost circulation zone comprises injecting the LCM composition into the lost circulation zone.

18. The method of claim 16 where the lost circulation zone is a low-injectivity zone.

19. The method of claim 16 where the epoxy resin comprises from 0.1 weight percent to 80 weight percent of the bisphenol-A-epichlorohydrin epoxy resin modified with an oxirane mono [(C12-C14)-alkyloxy)methyl] derivative based on the total weight of the epoxy resin.

20. The method of claim 19 where the curing agent comprises at least one of TEPA or DETA and the LCM composition comprises from 2 weight percent to 10 weight percent curing agent based on the total weight of the composition.

Assignees

• Saudi Arabian Oil Co

Inventors

• Al-Yami Abdullah
• Alsafran Ali
• Wagle Vikrant
• Alsaihati Zainab

Classifications

• E21B21/003

  Means for stopping loss of drilling fluid (plastering the borehole wall E21B33/138) · CPC title

• C09K8/512

  containing cross-linking agents · CPC title

• C09K8/5086 Primary

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09K8/501

  using spacer compositions · CPC title