Napthol-Based Epoxy Resin Additives For Use In Well Cementing

Patent metadata

Field	Value
Publication number	US-2016046853-A1
Application number	US-201414401022-A
Country	US
Kind code	A1
Filing date	Aug 15, 2014
Priority date	Aug 15, 2014
Publication date	Feb 18, 2016
Grant date	—

Abstract

Disclosed are methods and compositions for cementing in a subterranean formation. A method comprises introducing a resin composition into a wellbore. The resin composition may comprise a resin, a napthol-based epoxy resin additive, and a hardening agent. The napthol-based epoxy resin additive may comprise two naphthalene functional groups and two epoxide functional groups.

First claim

What is claimed is:

1 . A method comprising:
introducing a resin composition into a wellbone, wherein the resin composition comprises a non-naphthol-based resin, a naphtbol-based epoxy resin additive, and a hardening agent, wherein the naphthol-based epoxy resin additive comprises two naphthalene functional groups and two epoxide functional groups, wherein the non-naphthol-based resin is present in an based epoxy resin additive is present in the resin composition in an amount of about 1% to about 40% by volume of the resin composition.

2 . The method of claim 1 wherein the naphthol-based epoxy resin additive comprises a resin additive selected from the group consisting of 1,1-bis(2-glycidyloxy-1-naphthyl)alkane, 1-(2,7-diglycidyloxy-1-naphthyl)-1-(2-glycidyoxy-1-naphthyl)alkane, 1,1-bis(2,7-diglycidyloxy-1-naphthyl)alkane, and any combination thereof.

3 . The method of claim 1 wherein the naphthol-based epoxy resin additive comprises 1,1-bis(2-glycidyloxy-1-naphthyl)methane.

4 . The method of claim 1 wherein the naphthol-based epoxy resin additive is present in an amount of about 1% to about 40%.

5 . The method of claim 1 wherein the non-naphthol-based resin is selected from the group consisting of an epoxy-based resin, a novolac resin, a polyepoxide resin, a phenol-aldehyde resin, a urea-aldehyde resin, a urethane resin, a phenolic resin, a furan/furfuryl alcohol resin, a phenolic/latex resin, a phenol formaldehyde resin, a bisphenol A diglycidyl ether resin, a butoxymethyl butyl glycidyl ether resin, a bisphenol A-epichlorohydrin resin, a bisphenol F resin, a glycidyl ether resin, a polyester resin and a hybrid and copolymer thereof, a polyurethane resin, an acrylate resin, and any combination thereof.

6 . The method of claim 1 wherein the hardening agent is selected from the group consisting of an aliphatic amine, an aliphatic tertiary amine, an aromatic amine, a cycloaliphatic amine, a heterocyclic amine, an amido amine, a polyamide, a polyethyl amine, a polyether amine, a polyoxyalkylene amine, a carboxylic anhydride, triethylenetetraamine, ethylene diamine N-cocoalkyltrimethylene, isophorone diamine, N-aminophenylpiperazine, imidazoline, 1,2-diaminocyclohexane, polytheramine, diethyltoluenediamine, 4,4′-diaminodiphenyl methane, methyltetrahydrophthalic anhydride, hexahydrophthalic anhydride, maleic anhydride, polyazelaic polyanhydride, plithalic anhydride, and any combination thereof.

7 . The method of claim 1 wherein the resin composition comprises a diluent.

8 . The method of claim 7 wherein the diluent is selected from the group consisting of butyl glycidyl ether, cyclohexane dimethanol diglycidyl ether, polyethylene glycol, butyl lactate, dipropylene glycol methyl ether, dipropylene glycol dimethyl ether, dimethyl formamide, diethyleneglycol methyl ether, ethylene butyl ether, diethyleneglycol butyl ether, propylene carbonate, d'limonene, fatty acid methyl esters, and any combinations thereof.

9 . The method of claim 1 wherein at least a portion of the resin composition is allowed to enter into and harden in a perforation in a casing within a wellbore.

10 . The method of claim 1 wherein at least a portion of the resin composition is allowed to enter into and harden in a perforation in a cement sheath within a wellbore.

11 . The method of claim 1 further comprising introducing the resin composition into an annular space formed between a pipe string and if the wellbore or a larger conduit.

12 . The method of claim 1 further comprising blending the resin composition and a cement composition, wherein the cement composition comprises water and hydraulic cement.

13 . A composition comprising: a non-naphthol-based resin, a naphthol-based epoxy resin additive, and a hardening agent, wherein the non-naphthol-based resin is present in an amount of about 5% to about 99% by volume of the resin composition, and wherein the naphthol-based epoxy resin additive is present in the resin composition in an amount of about 1% to about 40% by volume of the resin composition.

14 . The composition of claim 13 wherein the naphthol-based epoxy resin additive comprises a resin additive selected from the group consisting of 1,1-bis(2-glycidyloxy-1-naphthyl)alkanes, 1-(2,7-diglycidyloxy-1-naphthyl)-1-(2-glycidyloxy-1-naphthyl)alkane, 1,1-bis(2,7-diglycidyloxy-1-naphthyl)alkane, and any combination thereof.

15 . The composition of claim 13 wherein the naphthol-based epoxy resin additive comprises 1,1-bis(2-glycidyloxy-1-naphthyl)methane.

16 . The composition of claim 13 wherein the non-naphthol-based resin is selected from the group consisting of an epoxy-based resin, a novolac resin, a polyepoxide resin, a phenol-aldehyde resin, a urea-aldehyde resin, a urethane resin, a phenolic resin, a furan/furfuryl alcohol resin, a phenolic/latex resin, a phenol formaldehyde resin, a bisphenol A diglycidyl ether resin, a butoxymethyl butyl glycidyl ether resin, a bisphenol A-epichlorohydrin resin, a bisphenol F resin, a glycidyl ether resin, a polyester resin and a hybrid and copolymer thereof, a polyurethane resin ,an acrylate resin, and any combination thereof, and wherein the hardening agent is selected from the group consisting of an aliphatic amine, an aliphatic tertiary amine, an aromatic amine, a cycloaliphatic amine, a heterocyclic amine, an atnido amine, a polyamide, a polyethyl amine, a polyether amine, a polyoxyalkylene amine, a carboxylic anhydride, triethylenetetraamine, ethylene diamine, N-cocoalkyltrimethylene, isophorone diamine, N-aminophenyl piperazine, imidazoline, 1,2-diaminocyclohexane, polytheramine, diethyltoluenediamine, 4,4″-diaminodiphenyl methane, methyltetrahydrophthalic anhydride, hexahydrophthalic anhydride, maleic anhydride, polyazelaic polyanhydride, phthalic anhydride, and any combination thereof.

17 . The composition of claim 13 wherein the composition further comprises water and a hydraulic cement.

18 . A system comprising:
a resin composition comprising a non-naphthol-based resin, a naphthol-based epoxy resin additive, and a hardening agent, wherein the non-naphthol-based resin is present in an amount of about 5% to about 99% by volume of the resin composition, and wherein the naphthol-based epoxy resin additive is present in the resin composition in an amount of about 1% to about 40% by volume of the resin composition: mixing equipment capable of mixing the resin composition; and pumping equipment capable of delivering the resin composition into a wellbore.

19 . The system of claim 18 wherein the non-naphthol-based epoxy resin additive comprises 1,1-bis(2-glycidyloxy-1-naphthyl)methane.

20 . The system of claim 18 wherein the non-naphthol-based resin is selected from the group consisting of an epoxy-bastxl resin, a novolac resin, a polyepoxide resin, a phenol-aldehyde resin, a urea-aldehyde resin, a urethane resin, a phenolic resin, a furan/furfuryl alcohol resin, a phenolic/latex resin, a phenol formaldehyde resin, a bisphenol A diglycidyl ether resin, a butoxymethyl butyl glyeidyl ether resin, a bisphenol A-epichlorohydrin resin, is bisphenol F resin, a glycidyl ether resin, a polyester resin, a polyurethane resin and a hybrid and copolymer thereof, an acrylate resin, and any combination thereof.

Assignees

• Chatterji Jiten
• Hundt Gregory Robert
• Halliburton Energy Services Inc

Inventors

• Chatterji Jiten
• Hundt Gregory Robert

Classifications

• C09K8/467 Primary

  containing additives for specific purposes · CPC title

• C09K8/426 Primary

  for plugging · CPC title

• E21B33/138

  Plastering the borehole wall; Injecting into the formation · CPC title

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title

• C09K8/428

  for squeeze cementing, e.g. for repairing · CPC title