Method for marking workpieces and workpiece

Patent metadata

Field	Value
Publication number	US-10994320-B2
Application number	US-201816135833-A
Country	US
Kind code	B2
Filing date	Sep 19, 2018
Priority date	May 18, 2015
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

In an embodiment, a workpiece includes a hot-formed metal body and a marking, wherein the marking comprises a phosphor and/or pigments which are at least partly arranged on the metal body and which exhibit a reflection behavior and/or a reflectance behavior and/or an albedo behavior deviating from the metal body.

First claim

What is claimed is:

1. A workpiece comprising:
a hot-formed metal body; and
a marking consisting of an inorganic matrix material that is glass and of phosphor particles and/or ceramic colored particles which are at least partly arranged on the metal body and which are configured to exhibit a reflection behavior and/or a reflectance behavior and/or an albedo behavior deviating from the metal body,
wherein the matrix material acts as an adhesion promoter and as an adhesive between the metal body and the phosphor particles and/or the ceramic colored particles, and
wherein the phosphor particles consist of at least one of the following phosphors: Eu 2+ -doped nitrides; garnets from the general system (Gd,Lu,Tb,Y) 3 (Al,Ga,D) 5 (O,X) 12 :RE, where X=halide, N or divalent element, D=trivalent or tetravalent element and RE=rare earth metals; Eu 2+ -doped SiONs; SiAlONs; beta-SiAlONs from the system Si 6-x Al z O y N 8-y :RE Z ; nitrido-orthosilicates; orthosilicates; chlorosilicates; chlorophosphates; BAM phosphors from a BaO-MgO-Al 2 O 3 system; halophosphates; or (Sr,Ba,Ca) 5 (PO 4 ) 3 Cl:Eu 2 .

2. The workpiece of claim 1 , further comprising an anti-scaling protective layer applied to the metal body, wherein the marking is at least partly applied to the anti-scaling protective layer, and wherein the marking is configured to exhibit the reflection behavior and/or the reflectance behavior and/or the albedo behavior deviating from the metal body as well as from the anti-scaling protective layer.

3. The workpiece according to claim 2 , wherein a melting point of the marking is at least 25° C. above a melting point of the anti-scaling protective layer.

4. The workpiece according to claim 2 , wherein the anti-scaling protective layer comprises aluminum, silicon, zinc, iron and/or a metal oxide.

5. The workpiece according to claim 2 , wherein the marking is elevated above the anti-scaling protective layer.

6. The workpiece according to claim 2 , wherein the particles of the marking at least partly penetrate through the anti-scaling protective layer, are partly in contact with the metal body and do not project from the anti-scaling protective layer.

7. The workpiece according to claim 2 ,
wherein the marking comprises a plurality of continuous marking regions, a thickness of the marking regions being at least 0.5 μm and at most 25 μm,
wherein, in the marking regions, phosphor particles are present in a manner stacked one above another, the phosphor particles being embedded into a continuous matrix material, and
wherein the marking regions have a reduced surface roughness compared with the anti-scaling protective layer adjacent to the marking regions.

8. The workpiece according to claim 2 , wherein the marking is applied onto the anti-scaling protective layer and does not penetrate into the anti-scaling protective layer, the marking consisting of the inorganic matrix material and of the phosphor particles.

9. The workpiece according to claim 1 ,
wherein the marking, as seen in plan view, is formed by a plurality of punctiform, island-shaped partial regions having a mean diameter of at most 50 μm,
wherein the marking, as seen in plan view and considered with all partial regions taken together, has a mean extent of at least 20 times the mean diameter, and
wherein a mean roughness of a surface of the workpiece at the marking deviates from a mean roughness of remaining regions of the surface by at most a factor of 2.

10. The workpiece according to claim 1 ,
wherein the marking comprises at least one continuous marking region,
wherein the at least one marking region has a mean extent of at least 20 times a mean diameter of color pigments of the marking.

11. The workpiece according to claim 1 , wherein the marking is distant from the metal body.

12. The workpiece according to claim 1 , wherein the marking is completely located in a recess of the metal body.

13. The workpiece according to claim 12 , wherein a depth of the recess exceeds a thickness of the metal body.

14. The workpiece according to claim 1 , wherein the marking is completely located on an elevation of the metal body.

15. A workpiece comprising:
a hot-formed metal body;
an anti-scaling protective layer directly on the metal body and composed of aluminum oxide and configured to prevent oxidation of the workpiece in an oxygen-containing atmosphere; and
a marking composed of a decarbonized matrix material and a phosphor which are at least partly arranged on the metal body and which are configured to exhibit a reflection behavior and/or a reflectance behavior and/or an albedo behavior deviating from the metal body,
wherein the phosphor consists of at least one of the following phosphors: (Ca,Sr)AlSiN 3 :Eu 2+ ; Sr(Ca,Sr)Si 2 Al 2 N 6 :Eu 2+ ; (Sr,Ca)AlSiN 3 *Si 2 N 2 O:Eu 2+ ; (Ca,Ba,Sr) 2 Si 5 N 8 :Eu 2+ ; (Sr,Ca)[LiAl 3 N 4 ]:Eu 2+ ; Lu 3 (Al 1-x Ga x ) 5 O 12 :Ce 3+ ; Y 3 (Al 1-x Ga x ) 5 O 12 :Ce: 3+ ; (Ca,Sr,Ba)S:Eu 2+ ; (Ba,Sr,Ca)Si 2 O 2 N 2 :Eu 2+ ; Li x M y Ln z Si 12-(m+n) Al (m+n) O n N 16-n ; Si 6-x Al z O y N 8-y :RE Z ; AE 2-x-n RE x Eu a SiO 4-x N x , AE 2-x-n RE x Eu a Si 1-y O 4-x-2y N x , where RE=rear earth metal and AE=alkaline earth metal; (Ba,Sr,Ca,Mg) 2 SiO 4 :Eu 2+ ; Ca 8 Mg(SiO 4 ) 4 Cl 2 :Eu 2+ ; (Sr,Ba,Ca,Mg) 10 (PO 4 ) 6 Cl 2 :Eu 2+ ; BaMgAl 10 O 17 :Eu 2+ ; M 5 (PO 4 ) 3 (Cl,F):(Eu 2+ , Sb 3+ , Mn 2+ ); or (Sr,Ba,Ca) 5 (PO 4 ) 3 Cl:Eu 2+ , and
wherein the marking is applied directly to the anti-scaling protective layer.

Assignees

• Fraunhofer Ges Forschung

Inventors

• Zeh Christoph
• Härtling Thomas

Classifications

• B21C51/005 Primary

  Marking devices · CPC title

• B21D22/00

  Shaping without cutting, by stamping, spinning, or deep-drawing (otherwise than using rigid devices or tools or yieldable or resilient pads B21D26/00) · CPC title

• B41M1/28

  on metals · CPC title

• B05D7/26

  synthetic lacquers or varnishes (B05D7/08, B05D7/16 take precedence) · CPC title

• B41K99/00

  Subject matter not provided for in other groups of this subclass · CPC title