Porous films obtained from polymer latex

Patent metadata

Field	Value
Publication number	US-10988581-B2
Application number	US-201716082314-A
Country	US
Kind code	B2
Filing date	Feb 27, 2017
Priority date	Mar 8, 2016
Publication date	Apr 27, 2021
Grant date	Apr 27, 2021

Abstract

The invention relates to a porous material comprising particles of polymer P assembled by a block copolymer, said block copolymer comprising at least one block consisting of a polymer sequence immiscible with polymer P, and at least two blocks consisting of polymer sequences which are miscible with polymer P. The invention also relates to films produced with this material.

First claim

The invention claimed is:

1. A porous material comprising particles of polymer P assembled by a block copolymer, the block copolymer comprising at least one block consisting of a polymer sequence immiscible with the polymer P, and at least two blocks consisting of polymer sequences miscible with the polymer P,
wherein the block copolymer is a triblock copolymer of general formula ABA, in which A represents a block consisting of a polymer sequence miscible with the polymer P, and B represents a block consisting of a polymer sequence immiscible with the polymer P, and

wherein Polymer P comprises a fluoropolymer.

2. The material as claimed in claim 1 , wherein the diameter Dv50 of the particles of polymer P is from 30 to 1000 nm.

3. The material as claimed in claim 1 , wherein:
the block A consists of the same repeating unit(s) as the polymer P; or the block A is a homopolymer or copolymer block, selected from the group consisting of methacrylic polyesters, acrylic polyesters, polyvinylpyrrolidone, polyether glycols, polystyrenes, polylactic acids or polybutadienes; and/or
the block B is a homopolymer or copolymer sequence selected from the group consisting of acrylic or methacrylic polymers, polyvinyl polymers, polystyrene sulfonates, polyether glycols and cellulose-based polymers.

4. The material as claimed in claim 1 , wherein the block A and the block B are acrylic or methacrylic homopolymer or copolymer sequences; the block A being a poly(methyl methacrylate) block; and the block B being a poly(2-(dimethylamino)ethyl methacrylate) block.

5. The material as claimed in claim 1 , having:
a weight content of block copolymer ranging from 1% to 60% and/or
a weight content of polymer P ranging from 40% to 99%.

6. The material as claimed in claim 1 , wherein the block copolymer comprises:
a weight content of blocks consisting of polymer sequences miscible with the polymer P ranging from 10% to 90% and/or
a weight content of blocks consisting of polymer sequences immiscible with the polymer P ranging from 10% to 90%.

7. The material as claimed in claim 1 , wherein the particles of polymer P are linked to one another by said block copolymer.

8. A film comprising at least one layer of material as claimed in claim 1 .

9. The film as claimed in claim 8 , wherein said film is a membrane, or a filtration membrane.

10. The film as claimed in claim 8 , consisting of a coating deposited on a substrate, the substrate being a filtration membrane or a support which is woven or nonwoven.

11. A process for producing the material as claimed in claim 1 , comprising:
providing a suspension of particles of polymer P;
providing said block copolymer;
blending the suspension of particles and of the block copolymer, in the presence of a solvent; and
drying of this blend,

wherein polymer P comprises a fluoropolymer.

12. The process as claimed in claim 11 , wherein the block copolymer is provided in solution in the solvent.

13. A process for producing the material as claimed in claim 1 in latex form, comprising:
providing a solution of polymer P;
providing the block copolymer;
precipitating a blend of polymer P and of block copolymer in water, in the presence of a solvent, resulting in the obtaining of the latex; and
drying of this latex.

14. The process as claimed in claim 11 , further comprising spreading the blend over a surface before the drying step.

15. The process as claimed in claim 11 , wherein the solvent is selected from the group consisting of ethers, ketones, aromatic solvents, alcohols, esters, acetone and tetrahydrofuran.

16. The process as claimed in claim 11 , wherein the material obtained is in the form of a film or membrane and the morphology of the films or membranes obtained consists of an assembly of discrete or coalesced particles.

17. The process as claimed in claim 11 , wherein the material obtained is in the form of a film or membrane and the morphology of the films or membranes obtained consists of a honeycomb structure organized as a bees nest-like structure.

18. The material as claimed in claim 1 , wherein the fluoropolymer comprises at least 75% by weight of units of vinylidene fluoride monomer.

19. The material as claimed in claim 18 , wherein the fluoropolymer comprises vinylidene fluoride homopolymer.

20. The material as claimed in claim 1 , wherein the fluoropolymer comprises a copolymer of vinylidene fluoride with a least one other comonomer selected from the group consisting of chlorotrifluoroethylene (CTFE), hexafluoropropylene (HFP), trifluoroethylene (TrFE), tetrafluoroethylene (TFE) and ethylene.

21. The material as claimed in claim 1 , wherein the fluoropolymer comprises polytetrafluoroethylene (PTFE).

Assignees

• Arkema France
• Centre Nat Rech Scient
• Univ Montpellier
• Enscm

Inventors

• Beaume Francois
• Deratani Andre
• Quemener Damien
• Semsarilar Mona

Classifications

• B01D71/34 Primary

  Polyvinylidene fluoride · CPC title

• B01D2325/02

  Details relating to pores or porosity of the membranes · CPC title

• B01D71/4011

  Polymethylmethacrylate · CPC title

• B01D69/1411

  containing dispersed material in a continuous matrix · CPC title

• C08J2353/00

  Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers · CPC title