Water flux polymer membranes

Patent metadata

Field	Value
Publication number	US-9707524-B2
Application number	US-200913126670-A
Country	US
Kind code	B2
Filing date	Oct 9, 2009
Priority date	Oct 28, 2008
Publication date	Jul 18, 2017
Grant date	Jul 18, 2017

Abstract

The invention relates to a polymer membrane composition having improved water flux and stable pore size. The water flux is improved by increasing the hydrophilicity of the membrane using a matrix polymer blended with controlled architecture amphiphilic block copolymers. Preferred membranes are those having a fluoropolymer matrix and acrylic amphiphilic block copolymers. The addition of the amphiphilic block copolymers are especially useful in microfiltration and ultra filtration membranes when used in water filtration.

First claim

What is claimed is:

1. A polymeric membrane having uniform stable hydrophilicity and uniform pore size useful as a water microfiltration or ultrafiltration membrane consisting of a stable, uniform blend of:
a) 99-20 weight percent of a hydrophobic matrix polymer, said matrix polymer comprises a polyvinylidene fluoride homopolymer, or a polyvinylidene copolymer comprising at least 50 mole percent of vinylidene fluoride monomer units,
b) 1-80 weight percent of an amphiphilic block copolymer having 1) at least one hydrophilic bock and 2) at least one hydrophobic block compatible with said polymer matrix, wherein said hydrophilic and hydrophobic blocks comprise acrylic polymers, wherein said hydrophilic block is a gradient copolymer having two or more different monomer units, and wherein said hydrophilic block comprises one or more monomer units selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl methacrylate, polyethylene glycol acrylate (PEGA), polyethyeleneglycol-methylether acrylate (MPEGA), polyethylene glycol methacrylate (PEGMA), polyethyleneglycol-methylether-methacrylate (MPEGMA), acrylamido 2-methyl 2-propane sulfonate, styrene sulfonic acid and itaconic acid, and
c) optionally one or more hydrophilic additives selected from the group consisting of polyethylene-glycol (PEG), polyethylene glycol methacrylate (PEGMA), propylene glycol (PG), polyacrylic add (PAA), and polymethacrylic acid (PMA);
wherein said polymeric membrane has a maximum pore size of less than 0.3 um, and wherein said block copolymer is a controlled radical polymerized copolymer.

2. The polymeric membrane of claim 1 wherein said block copolymer is a di-, or tri-block copolymer.

3. The polymeric membrane of claim 1 wherein said amphiphilic block copolymer comprises residual nitroxide end-groups.

4. The polymeric membrane of claim 2 wherein said block copolymer is non-water soluble.

5. The polymeric membrane of claim 1 comprising 99-40 weight percent of hydrophobic matrix polymer and 1-60 weight percent of amphiphilic block copolymer.

6. The polymeric membrane of claim 1 comprising 90-70 weight percent of hydrophobic matrix polymer and 10-30 weight percent of amphiphilic block copolymer.

7. The polymeric membrane of claim 1 , wherein said amphiphilic block copolymer is partially or fully neutralized.

8. The polymeric membrane of claim 1 , wherein said hydrophobic matrix polymer and amphiphilic block copolymer form an intimate blend.

9. The polymeric membrane of claim 8 , wherein said intimate blend is an interpenetrating polymer network (IPN) or a core-shell morphology.

Assignees

• Kosar Walter
• Macy Noah E
• Schmidt Scott C
• Ness Jason S
• Biscarat Jennifer
• Arkema Inc

Inventors

• Kosar Walter
• Macy Noah E
• Schmidt Scott C
• Ness Jason S
• Biscarat Jennifer

Classifications

• B01D67/0006

  by chemical reactions (in-situ polymerisation, polycondensation, cross-linking or reaction for manufacturing composite membranes B01D69/125) · CPC title

• B01D71/40

  Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters · CPC title

• B01D2325/36

  Hydrophilic membranes · CPC title

• B01D71/34 Primary

  Polyvinylidene fluoride · CPC title

• B01D71/80 Primary

  Block polymers · CPC title