Conversion material for white or colored light source, method of production, and light source having the conversion material

Patent metadata

Field	Value
Publication number	US-10988408-B2
Application number	US-201815916403-A
Country	US
Kind code	B2
Filing date	Mar 9, 2018
Priority date	Apr 29, 2008
Publication date	Apr 27, 2021
Grant date	Apr 27, 2021

Abstract

A conversion material for a white or colored light source is provided. The material includes a matrix glass that, as bulk material, for a thickness of about 1 mm, has a pure transmission of greater than 80% in the wavelength region from 350 to 800 nm and in the region in which the primary light source emits light, wherein the sum of transmission and reflection of the sintered matrix glass without luminophore is at least greater than 80% in the spectral region from 350 nm to 800 nm and in the spectral region in which the primary light source emits light.

First claim

What is claimed is:

1. A conversion material for a white or colored light source, comprising:
a matrix glass comprising a lanthanum borosilicate glass with a zinc fraction; and
at least one luminophore,
wherein the matrix glass and the at least one luminophore are formed as a sintered compact from a powder of the matrix glass, the powder having a grain size distribution d10≥0.7 μm, d50≥3 μm and d90≤150 μm.

2. The conversion material according to claim 1 , wherein the grain size is sufficient such that the matrix glass has a sum of transmission and reflection in the spectral region from 350 nm to 800 nm and in a spectral region in which the light source emits light is at least greater than 80%.

3. The conversion material according to claim 1 , wherein the sintered compact has a reflection in a spectral region in which the light source emits light of less than 30% and has a sum of transmission and reflection in a spectral region from 350 nm to 800 nm, except for the spectral region in which the light source emits the light, that is at least greater than 80%.

4. The conversion material according to claim 1 , wherein the at least one luminophore has a grain size distribution having a mean diameter d50 between 1 μm and 50 μm.

5. The conversion material according to claim 1 , wherein the at least one luminophore has a grain size distribution having a mean diameter d50 between 1 μm and 20 μm.

6. The conversion material according to claim 1 , wherein the at least one luminophore has a grain size distribution having a mean diameter d50 between 1 μm and 15 μm.

7. The conversion material according to claim 1 , wherein the sintered compact has, in a spectral region from 350 to 800 nm, but without a region in which the light source emits light, maximum and minimum contributions to the difference of reflection and transmission established over this spectral region differ by no more than 40%, and has an internal conversion quantum yield of the at least one luminophore is reduced in relation to the internal conversion yield of non- embedded luminophores by no more than 20%.

8. The conversion material according to claim 1 , wherein the matrix glass comprises in weight percent:

SiO 2
3-7;

B 2 O 3
16-22;

Al 2 O 3
0-1;

ZnO
 3-26;

TiO 2
 1-11;

ZrO 2
1-8;

La 2 O 3
32-45;

Nb 2 O 5
 5-16;

WO 3
0-7;

Y 2 O 3
0-5;

BaO
0-6;

MgO
0-6;

CaO
0-6;

SrO
0-6;

sum of alkaline-earth oxides
0-10; and

refining agent
0-2.

9. The conversion material according to claim 1 , wherein the matrix glass, as a bulk material, has a refractive index of 1.43 to 1.6.

10. The conversion material according to claim 1 , wherein the matrix glass, as a bulk material, has a refractive index of 1.45 to 1.59.

11. The conversion material according to claim 1 , wherein the zinc fraction comprises zinc phosphates.

12. The conversion material according to claim 1 , wherein the matrix glass is free of Tl 2 O, TeO 2 , and As 2 O 3 .

13. The conversion material according to claim 1 , wherein the at least one luminophore comprises a host material that is at least one substance selected from the group consisting of oxides, nitrides, oxynitrides, sulfides, oxysulfides, halides, halooxides, halosulfides, tellurides, and selenides, and wherein the host material is doped with at least one substance selected from the group consisting of rare earths, transition metals, and heavy metals.

14. A conversion material for a white or colored light source, comprising:
a matrix glass comprising an aluminum borosilicate glass with an yttrium fraction; and
at least one luminophore,
wherein the matrix glass and the at least one luminophore are formed as a sintered compact from a powder of the matrix glass, the powder having a grain size distribution d10≥0.7 μm, d50≥3 μm and d90≥150 μm.

15. The conversion material according to claim 14 , wherein the matrix glass comprises alkaline-earth silicates.

16. A method of producing a conversion material, comprising the steps of:
providing a matrix glass comprising a lanthanum borosilicate glass with a zinc fraction or an aluminum borosilicate glass with an yttrium fraction;
grinding the matrix glass to a powder with a grain size distribution of grain sizes d10≥0.7 μm, d50≥3 μm, and d90≤150 μm;
mixing the powder with a powdered luminophore to form a mixture;
pressing the mixture to form a pressed mixture; and
sintering the pressed mixture to form a sintered compact.

17. A light source, comprising:
a matrix glass comprising a lanthanum borosilicate glass with a zinc fraction or an aluminum borosilicate glass with an yttrium fraction;
at least one luminophore, wherein the matrix glass and the at least one luminophore are formed as a sintered compact from a pressed mixture of a powder of the matrix glass and a powder of the at least one luminophore, the powder of the matrix glass having a grain size distribution d10≥0.7 μm, d50≥3 μm and d90≤150 μm; and
a primary light source that emits light with wavelengths in a region from 225 nm to 520 nm.

18. The light source according to claim 17 , wherein the primary light source comprises an LED that emits the light with a wavelength in a region from 400 nm to 480 nm.

19. The light source according to claim 18 , wherein the light is emitted at color coordinates in (X, Y) color space comprising:
A=(0.16,0.02)
B=(0.05,0.30)
C=(0.02,0.76)
D=(0.21,0.76)
E=(0.72,0.28).

20. The light source according to claim 19 , wherein the light has a color space defined within a polygon traverse ABCDE within which essentially light of all color coordinates.

Assignees

• Schott Ag

Inventors

• Liebald Rainer
• Stolz Claudia
• Brix Peter
• Ritter Simone Monika
• Nass Peter
• Goedeke Dieter
• Pichler-Wilhelm Sabine
• Wimmer Sabrina

Classifications

• C09K11/7774

  Aluminates · CPC title

• C03C3/095

  containing rare earths · CPC title

• C03C3/091

  containing aluminium · CPC title

• C03C3/093

  containing zinc or zirconium · CPC title

• C03C3/16

  containing phosphorus · CPC title