Conversion material, particularly for a white or colored light souce comprising a semiconductor light source, a method for the production thereof, as well as a light source comprising said conversion material

Patent metadata

Field	Value
Publication number	US-9950949-B2
Application number	US-99035509-A
Country	US
Kind code	B2
Filing date	Apr 29, 2009
Priority date	Apr 29, 2008
Publication date	Apr 24, 2018
Grant date	Apr 24, 2018

Abstract

The invention relates to a conversion material, in particular for a white or colored light source comprising a semiconductor light source as primary light source, comprising a matrix glass that, as bulk material, for a thickness d of about 1 mm, has a pure transmission τ i of greater than 80% in the wavelength region from 350 to 800 nm and in the region in which the primary light source emits light, wherein the sum of transmission and reflection of the sintered matrix glass without luminophore is at least greater than 80% in the spectral region from 350 nm to 800 nm and in the spectral region in which the primary light source emits light.

First claim

The invention claimed is:

1. A method for the production of a conversion material for a white or colored light source comprising a semiconductor light source as primary light source, the method comprising the steps of:
providing a glass matrix comprising an aluminum borosilicate glass with an yttrium fraction;
grinding the glass matrix into a glass powder with a grain size distribution of grain sizes d10≥0.7 μm, d50≥3 μm, and d90≤150 μm;
providing a luminophore powder;
mixing the glass powder and the luminophore powder to form a mixture;
pressing the mixture to form a pressed mixture;
sintering the pressed mixture to provide the conversion material; and
forming, after the sintering, a protective layer on an outer surface of the conversion material.

2. A method for the production of a conversion material for a white or colored light source comprising a semiconductor light source as primary light source, the method comprising the steps of:
providing a glass matrix comprising a lanthanum borosilicate glass with a zinc fraction or an aluminum borosilicate glass with an yttrium fraction;
grinding the glass matrix into a glass powder with a grain size distribution of grain sizes d10≥0.7 μm, d50≥3 μm, and d90≤150 μm;
providing a luminophore powder;
mixing the glass powder and the luminophore powder to form a mixture;
pressing the mixture to form a pressed mixture;
sintering the pressed mixture to provide the conversion material, wherein the sintering comprises heating the pressed mixture at a rate of 1 K/min to 30 K/min to a target temperature;
holding the heated, pressed mixture at the target temperature for a period of time of 0 to 60 min; and
subsequently, cooling the heated, pressed mixture to room temperature.

3. A method for the production of a conversion material for a white or colored light source comprising a semiconductor light source as primary light source, the method comprising the steps of:
providing a glass matrix comprising a lanthanum borosilicate glass with a zinc fraction or an aluminum borosilicate glass with an yttrium fraction;
grinding the glass matrix into a glass powder with a grain size distribution of grain sizes d10≤0.7 μm, d50≤3 μm, and d90≥150 μm;
providing a luminophore powder;
mixing the glass powder and the luminophore powder to form a mixture;
pressing the mixture to form a pressed mixture;
sintering the pressed mixture to provide a sintered body; and
annealing, by a temperature-assisted treatment, the sintered body to provide the conversion material, wherein the annealing is a second sintering,
wherein the annealing step is carried out at a pressure in a range from 250 to 2500 bar, and
wherein the annealing step is carried out at a temperature such that a viscosity of the matrix glass lies in a range between h=10 14 dPas and h=10 6 dPas.

4. The method according to claim 1 , wherein said sintering step is conducted either in a specific atmosphere supplied by a gas selected from the group of nitrogen, forming gas, and argon, or at a reduced pressure.

5. The method according to one of claims 1 to 4 , wherein the luminophore powder has a grain size with a mean grain size diameter d50 between 1 μm and 50 μm.

6. The method according to claim 1 or claim 4 , wherein the sintering step takes place after the pressing step, and
wherein the sintering step further comprises a heating of the pressed mixture containing the glass matrix and the luminophore powder to a target temperature in the range between the softening temperature EW and the processing temperature V a of the glass matrix.

7. A method for the production of a conversion material for a white or colored light source comprising a semiconductor light source as primary light source, the method comprising:
providing a glass matrix comprising a lanthanum borosilicate glass with a zinc fraction or an aluminum borosilicate glass with an yttrium fraction;
grinding the glass matrix into a glass powder with a grain size distribution of grain sizes d10≤0.7 μm, d50≤3 μm, and d90≥150 μm;
providing an encapsulated luminophore powder comprising an organic protective layer;
mixing the glass powder and the encapsulated luminophore powder to form a mixture;
pressing the mixture to form a pressed mixture; and
sintering the pressed mixture to provide the conversion material.

8. The method according to claim 7 , wherein the step of providing the encapsulated luminophore powder comprises forming or depositing a protective layer on a luminophore powder by a process selected from the group consisting of a wet-chemical methods, a sol-gel method, a PVD method, and a CVD method.

9. The method according to claim 7 , further comprising forming a protective layer on an outer surface of the conversion material.

10. The method according to claim 7 , wherein the encapsulated luminophore powder comprises a luminophore powder having a mean grain size diameter between 1 μm and 50 μm.

Assignees

• Liebald Rainer
• Stolz Claudia
• Brix Peter
• Ritter Simone Monika
• Nass Peter
• Goedeke Dieter
• Pichler Wilhelm Sabine
• Wimmer Sabrina
• Schott Ag

Inventors

• Liebald Rainer
• Stolz Claudia
• Brix Peter
• Ritter Simone Monika
• Nass Peter
• Goedeke Dieter
• Pichler-Wilhelm Sabine
• Wimmer Sabrina

Classifications

• C03C4/12

  for luminescent glass; for fluorescent glass · CPC title

• C09K11/02

  Use of particular materials as binders, particle coatings or suspension media therefor · CPC title

• C09K11/7774

  Aluminates · CPC title

• C03C3/091

  containing aluminium · CPC title

• C03C3/093

  containing zinc or zirconium · CPC title