Dehydrogenation of alkanes

Patent metadata

Field	Value
Publication number	US-10987646-B2
Application number	US-201615769450-A
Country	US
Kind code	B2
Filing date	Oct 24, 2016
Priority date	Oct 28, 2015
Publication date	Apr 27, 2021
Grant date	Apr 27, 2021

Abstract

A reactor system for dehydrogenation of alkanes in a given temperature range upon bringing a reactant stream including alkanes into contact with a catalytic mixture. The reactor system includes a reactor unit arranged to accommodate the catalytic mixture, where the catalytic mixture includes catalyst particles and a ferromagnetic material. The catalyst particles are arranged to catalyze the dehydrogenation of alkanes. The ferromagnetic material is ferromagnetic at least at temperatures up to an upper limit of the given temperature range. The reactor system moreover includes an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalytic mixture is heated to a temperature within the temperature range by means of the alternating magnetic field. Also, a catalytic mixture and a method of dehydrogenating alkanes.

First claim

The invention claimed is:

1. A method for dehydrogenating of alkanes in a given temperature range T in a reactor system, said reactor system comprising a reactor unit arranged to accommodate a catalytic mixture, said catalytic mixture comprising catalyst particles in intimate contact with a ferromagnetic material, wherein said catalyst particles are arranged to catalyze the dehydrogenation of alkanes, and said ferromagnetic material is ferromagnetic at least at temperatures up to an upper limit of the given temperature range T, and an induction coil arranged to be powered by a power source supplying alternating current and positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalytic mixture is heated to a temperature within the given temperature range T by means of said alternating magnetic field, said method comprising the steps of:
(i) generating an alternating magnetic field within the reactor unit upon energization by a power source supplying alternating current, said alternating magnetic field passing through the reactor unit, thereby heating catalytic mixture by induction of a magnetic flux in the material;
(ii) bringing a reactant stream comprising alkanes into contact with said catalyst particles;
(iii) heating said reactant stream within said reactor by the generated alternating magnetic field; and
(iv) letting the reactant stream react in order to provide a product stream to be outlet from the reactor,
wherein the catalytic mixture is selected from one of the following:
wherein the catalytic mixture comprises catalyst particles and ferromagnetic particles that are mixed and treated to provide bodies of catalytic mixture, said bodies having a predetermined ratio between catalyst and ferromagnetic particles,
wherein said catalytic mixture comprises bodies of catalyst particles mixed with bodies of ferromagnetic material, wherein the smallest outside dimension of the bodies is in the order of about 1-2 mm or larger, or
wherein said ferromagnetic material comprises one or more ferromagnetic macroscopic supports susceptible for induction heating, wherein said one or more ferromagnetic macroscopic supports are ferromagnetic at temperatures up to an upper limit of the given temperature range T, wherein said one or more ferromagnetic macroscopic supports is/are coated with an oxide and wherein the oxide is impregnated with catalyst particles.

2. The method according to claim 1 , wherein the temperature range T is the range from between about 350° C. and about 700° C.

3. The method according to claim 1 , wherein the reactant stream is preheated in a heat exchanger prior to step (ii).

4. The method according to claim 1 , wherein the catalytic mixture is wherein catalyst particles and ferromagnetic particles are mixed and treated to provide bodies of catalytic mixture, said bodies having a predetermined ratio between catalyst and ferromagnetic particles.

5. The method according to claim 1 , wherein the catalytic mixture is wherein said catalytic mixture comprises bodies of catalyst particles mixed with bodies of ferromagnetic material, wherein the smallest outside dimension of the bodies is in the order of about 1-2 mm or larger.

6. The method according to claim 1 , wherein the catalytic mixture is wherein said ferromagnetic material comprises one or more ferromagnetic macroscopic supports susceptible for induction heating, wherein said one or more ferromagnetic macroscopic supports are ferromagnetic at temperatures up to an upper limit of the given temperature range T, wherein said one or more ferromagnetic macroscopic supports is/are coated with an oxide and wherein the oxide is impregnated with catalyst particles.

Assignees

• Haldor Topsoe As

Inventors

• Højlund Nielsen Poul Erik
• Nielsen Rasmus Munksgård
• Hansen John Bøgild
• Temel Mckenna Burcin

Classifications

• B01J35/55

  Cylinders or rings · CPC title

• B01J23/825

  with gallium, indium or thallium · CPC title

• B01J37/342

  of electric, magnetic or electromagnetic fields, e.g. for magnetic separation · CPC title

• B01J2208/00433

  using electromagnetic heating · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title