Nitrogen oxides and hydrocarbon storage catalyst and methods of using the same

Patent metadata

Field	Value
Publication number	US-10953366-B2
Application number	US-201815958020-A
Country	US
Kind code	B2
Filing date	Apr 20, 2018
Priority date	Apr 20, 2018
Publication date	Mar 23, 2021
Grant date	Mar 23, 2021

Abstract

A nitrogen oxides (NOx) and hydrocarbon (HC) storage catalyst for treating an exhaust gas flow is provided. The NOx and HC storage catalyst includes (a) a zeolite, (b) noble metal atoms, and (c) a metal oxide, a non-metal oxide, or a combination thereof. One or more of the noble metal atoms is present in a complex with the metal oxide, the non-metal oxide or a combination thereof. The complex is dispersed within a cage of the zeolite. Methods of preparing the NOx and HC storage catalyst and methods of using the NOx and HC storage catalyst for treating an exhaust gas stream flowing from a vehicle internal combustion engine during a period following a cold-start of the engine are also provided.

First claim

What is claimed is:

1. A nitrogen oxides (NO x ) and hydrocarbon (HC) storage catalyst for treating an exhaust gas flow comprising:
(a) a zeolite comprising cages and having a framework structure selected from the group consisting of BEA, MFI, CHA, AEI, EMT, ERI, MOR, MER, FER, FAU, LEV, MWW, CON, EUO, and combinations thereof;
(b) noble metal atoms selected from the group consisting of Pd atoms, Pt atoms, Rh atoms, Ag atoms, Ru atoms, Au atoms, Ir atoms and combinations thereof; and
(c) a metal oxide, a non-metal oxide, or a combination thereof, wherein the metal of the metal oxide is selected from the group consisting of alkali metals, alkaline-earth metals, transition metals, lanthanides, and combinations thereof, and the non-metal of the non-metal oxide is phosphorus; and
wherein one or more of the noble metal atoms are present in a complex with: (i) the metal oxide; (ii) the non-metal oxide; or (iii) the metal oxide and the non-metal oxide; and wherein the complex is dispersed within the cage of the zeolite.

2. The storage catalyst of claim 1 , wherein the noble metal atoms are present in an amount of about 0.1 wt. % to about 10 wt. % based on total weight of the NO x and HC storage catalyst.

3. The storage catalyst of claim 1 , wherein the metal oxide, the non-metal oxide, or a combination thereof is present in an amount of about 1 mol % to about 8 mol %.

4. The storage catalyst of claim 1 , wherein the zeolite is selected from the group consisting of chabazite, SSZ-13, DAF-5, LZ-218, UiO-21, ZK-14, and ZYT-6.

5. The storage catalyst of claim 1 , wherein the noble metal atoms are Pd atoms, Pt atoms, or a combination thereof.

6. The storage catalyst of claim 1 , wherein the metal of the metal oxide is selected from the group consisting of Na, K, Mg, Ca, Ba, Ti, Ce, and combinations thereof.

7. A method of preparing a NO x and HC storage catalyst comprising:
incorporating noble metal atoms into a zeolite to form a noble metal-substituted zeolite, wherein the noble metal atoms are selected from the group consisting of Pd atoms, Pt atoms, Rh atoms, Ag atoms, Ru atoms, Au atoms, Ir atoms and combinations thereof, and the zeolite comprises cages and has a framework structure selected from the group consisting of BEA, MFI, CHA, AEI, EMT, ERI, MOR, MER, FER, FAU, LEV, MWW, CON, EUO, and combinations thereof;
adding a metal oxide precursor, a non-metal oxide precursor, or a combination thereof in an amount less than about 8 mol. % to the noble metal-substituted zeolite to form an intermediate catalyst, wherein the metal of the metal oxide precursor is selected from the group consisting of alkali metals, alkaline-earth metals, transition metals, lanthanides, and combinations thereof, and the non-metal is phosphorus; and
calcining the intermediate catalyst at a ramp rate of less than about 5° C./minute to a temperature up to about 800° C. to form a complex dispersed within the cage of the zeolite, wherein the complex comprises one or more of the noble metal atoms with: (i) a metal oxide; (ii) a non-metal oxide; or (iii) the metal oxide and the non-metal oxide.

8. The method of claim 7 , wherein the noble metal atoms are incorporated into the zeolite via ion-exchange, incipient wetness impregnation, or grinding.

9. The method of claim 7 , wherein the noble metal atoms are present in the NO x and HC storage catalyst in an amount of about 0.1 wt. % to about 10 wt. % based on total weight of the NO x and HC storage catalyst.

10. The method of claim 7 , wherein the zeolite is selected from the group consisting of chabazite, SSZ-13, DAF-5, LZ-218, UiO-21, ZK-14, and ZYT-6.

11. The method of claim 7 , wherein the noble metal atoms are Pd atoms, Pt atoms, or a combination thereof.

12. The method of claim 7 , wherein the metal of the metal oxide is selected from the group consisting of Na, K, Mg, Ca, Ba, Ti, Ce, and combinations thereof.

13. A method of treating an exhaust gas stream flowing from a vehicle internal combustion engine during a period following a cold-start of the engine, the method comprising:
contacting the exhaust gas stream comprising one or more of NOR, HCs, carbon monoxide (CO), hydrogen (H 2 ), water (H 2 O), carbon dioxide (CO 2 ), oxygen (O 2 ), and nitrogen (N 2 ) with a NO x and HC storage device under adsorption conditions and storing at least a portion of the NOR, HC, or a combination thereof from the exhaust gas stream in the NOR and HC storage device;
wherein the NO x and HC storage device comprises a NOR and HC storage catalyst disposed on a substrate, wherein the NOR and HC storage catalyst comprises:
(a) a zeolite comprising cages and having a framework structure selected from the group consisting of BEA, MFI, CHA, AEI, EMT, ERI, MOR, MER, FER, FAU, LEV, MWW, CON, EUO, and combinations thereof;
(b) noble metal atoms selected from the group consisting of Pd atoms, Pt atoms, Rh atoms, Ag atoms, Ru atoms, Au atoms, Ir atoms and combinations thereof; and
(c) a metal oxide, a non-metal oxide, or a combination thereof, wherein the metal of the metal oxide is selected from the group consisting of alkali metals, alkaline-earth metals, transition metals, lanthanides, and combinations thereof, and the non-metal of the non-metal oxide is phosphorus; and
wherein one or more of the noble metal atoms are present in a complex with: (i) the metal oxide; (ii) the non-metal oxide; or (iii) the metal oxide and the non-metal oxide; and wherein the complex is dispersed within the cage of the zeolite; and

releasing at least a portion of the stored NOR, HC, or a combination thereof from the NO x and HC storage device to the exhaust stream under desorption conditions.

14. The method of claim 13 , wherein the adsorption conditions comprise the exhaust gas stream at a temperature less than or equal to about 200° C., the desorption conditions comprise the exhaust gas stream at a temperature greater than 200° C., or a combination thereof.

15. The method of claim 13 , further comprising passing the exhaust gas stream through a downstream oxidation reactor, a downstream reduction reactor, or a combination thereof for further oxidation or reduction of constituents of the exhaust gas stream as the exhaust gas stream increases in temperature and heats the downstream oxidation reactor to an oxidation operating temperature, the downstream reduction reactor to a reduction operating temperature, or combinations thereof.

16. The method of claim 13 , wherein the exhaust gas stream contacting the NO x and HC storage catalyst comprises one or more of:
(i) an H 2 content of about 50 ppm to about 5000 ppm;
(ii) a CO content of about 50 ppm to about 16000 ppm; and
(iii) an HC content of about 50 ppm to about 8000 ppm.

17. The method of claim 13 , wherein the noble metal atoms are present in the NO x and HC storage catalyst in an amount of about 0.1 wt. % to about 10 wt. %, based on total weight of the NO x and HC storage catalyst.

18. The method of claim 13 , wherein the zeolite is selected from the group consisting of chabazite, SSZ-13, DAF-5, LZ-218, UiO-21, ZK-14, and ZYT-6.

19. The method of claim 13 , wherein the noble metal atoms are Pd atoms, Pt atoms, or a combination thereof.

20. The method of claim 13 , wherein the metal of the metal oxide is selected from the group consisting of Na, K, Mg, Ca, Ba, Ti, Ce, and combinations thereof.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Yang Ming
• Wang Lei
• Ren Shouxian
• Li Wei

Classifications

• B01J29/00

  Catalysts comprising molecular sieves {(molecular sieves per se C01B)} · CPC title

• B01J23/58 Primary

  with alkali- or alkaline earth metals · CPC title

• B01D2255/912

  HC-storage component incorporated in the catalyst · CPC title

• B01D2258/01

  Engine exhaust gases · CPC title

• F01N3/0842

  Nitrogen oxides · CPC title