Copper CHA zeolite catalysts

Patent metadata

Field	Value
Publication number	US-9656254-B2
Application number	US-201514973353-A
Country	US
Kind code	B2
Filing date	Dec 17, 2015
Priority date	Feb 27, 2007
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

First claim

What is claimed is:

1. A catalyst comprising a copper ion-exchanged aluminosilicate zeolite having a CHA crystal structure, the zeolite having a mole ratio of silica to alumina from about 20 to about 40 and an atomic ratio of copper to aluminum from about 0.25 to about 0.50, wherein the catalyst contains ion-exchanged copper and non-exchanged copper.

2. The catalyst according to claim 1 , wherein the mole ratio of silica to alumina is about 25 to about 40.

3. The catalyst according to claim 1 , wherein the mole ratio of silica to alumina is about 25.

4. The catalyst according to claim 1 , wherein the mole ratio of silica to alumina is about 26.

5. The catalyst according to claim 1 , wherein the mole ratio of silica to alumina is about 27.

6. The catalyst according to claim 1 , wherein the mole ratio of silica to alumina is about 28.

7. The catalyst according to claim 1 , wherein the mole ratio of silica to alumina is about 29.

8. The catalyst according to claim 1 , wherein the mole ratio of silica to alumina is about 30.

9. The catalyst according to claim 1 , wherein the zeolite having the CHA structure is SSZ-13.

10. The catalyst according to claim 1 , wherein the atomic ratio of copper to aluminum is about 0.30.

11. The catalyst according to claim 1 , wherein the atomic ratio of copper to aluminum is about 0.33.

12. The catalyst according to claim 1 , wherein the atomic ratio of copper to aluminum is about 0.38.

13. The catalyst according to claim 1 , wherein the atomic ratio of copper to aluminum is about 0.44.

14. The catalyst according to claim 1 , wherein the atomic ratio of copper to aluminum is about 0.46.

15. The catalyst according to claim 1 , wherein the atomic ratio of copper to aluminum is about 0.40.

16. The catalyst according to claim 1 , further comprising a binder.

17. The catalyst according to claim 16 , wherein the binder is ZrO 2 .

18. The catalyst according to claim 1 , wherein the zeolite contains at least about 2.00 weight percent copper, expressed as copper oxide.

19. An exhaust gas treatment system comprising the catalyst of claim 1 and further comprising a catalyzed soot filter.

20. The exhaust gas treatment system of claim 19 , wherein said catalyzed soot filter is upstream of said catalyst.

21. The exhaust gas treatment system of claim 19 , further comprising a diesel oxidation catalyst.

22. The exhaust gas treatment system of claim 21 , wherein the diesel oxidation catalyst is upstream of the catalyst comprising the zeolite having the CHA crystal structure.

23. A catalyst article comprising a substrate having deposited thereon the catalyst according to claim 1 .

24. The catalyst article according to claim 23 , wherein the substrate is metal or ceramic.

25. The catalyst article according to claim 24 , wherein the substrate is a honeycomb substrate.

26. The catalyst article according to claim 25 , wherein the honeycomb substrate is a flow through substrate.

27. The catalyst article according to claim 25 , wherein the honeycomb substrate is a wall flow substrate.

28. The catalyst according to claim 1 , wherein the non-exchanged copper is present in an amount exceeding the amount of the ion-exchanged copper.

Assignees

• Basf Corp

Inventors

• Bull Ivor
• Xue Wen-Mei
• Burk Patrick
• Boorse R Samuel
• Jaglowski William M
• Koermer Gerald Stephen
• Moini Ahmad
• Patchett Joseph A
• Dettling Joseph C
• Caudle Matthew Tyler

Classifications

• Y10T428/24149

  Honeycomb-like · CPC title

• B01J29/80

  Mixtures of different zeolites · CPC title

• B01J29/743

  CHA-type, e.g. Chabazite, LZ-218 · CPC title

• B01J29/723 Primary

  CHA-type, e.g. Chabazite, LZ-218 · CPC title

• B01J29/068

  Noble metals · CPC title