Grey colored coated article with low-E coating having absorber layer and low visible transmission

Patent metadata

Field	Value
Publication number	US-10947153-B2
Application number	US-201616343264-A
Country	US
Kind code	B2
Filing date	Oct 18, 2016
Priority date	Oct 18, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

A low-emissivity (low-E) coating on a substrate (e.g., glass substrate) includes at least first and second infrared (IR) reflecting layers (e.g., silver based layers) that are spaced apart by contact layers (e.g., NiCr based layers), a layer comprising silicon nitride, and an absorber layer of or including a material such as niobium zirconium which may be oxided and/or nitrided. The absorber layer is designed to allow the coated article to realize glass side reflective (equivalent to exterior reflective in an IG window unit when the coating is on surface #2 of the IG unit) grey color. In certain example embodiments, the coated article (monolithic form and/or in IG window unit form) has a low visible transmission (e.g., from 20-45%, more preferably from 22-39%, and most preferably from 25-37%). In certain example embodiments, the coated article may be heat treated (e.g., thermally tempered and/or heat bent).

First claim

The invention claimed is:

1. A coated article including a coating supported by a glass substrate and having grey glass side reflective color, the coating comprising:
first and second infrared (IR) reflecting layers comprising silver, the first IR reflecting layer being located closer to the glass substrate than is the second IR reflecting layer;
a first contact layer located over and directly contacting the first IR reflecting layer comprising silver;
a dielectric layer comprising silicon nitride located over and directly contacting the first contact layer;
wherein the dielectric layer comprising silicon nitride is split by a splitting absorber layer comprising Nb and Zr, so that the splitting absorber layer comprising Nb and Zr is located between and contacting a first portion of the dielectric layer comprising silicon nitride and a second portion of the dielectric layer comprising silicon nitride;
a second contact layer located over the layer comprising silicon nitride;
the second IR reflecting layer comprising silver located over and directly contacting the second contact layer;
a third contact layer located over and directly contacting the second IR reflecting layer;
another dielectric layer comprising silicon nitride located over the third contact layer;
wherein the coated article has a visible transmission of from 20-45%, and a glass side visible reflectance of from 10-24%; and
wherein the coated article has grey glass side reflective coloration so that the coated article has a glass side reflective a* value from −2.5 to 0 and a glass side reflective b* value from −7.0 to −1.0 (Ill. C, 2 degree observer).

2. The coated article of claim 1 , wherein the absorber layer comprises a suboxide of NbZr.

3. The coated article of claim 1 , wherein the absorber layer comprises a subnitride of NbZr.

4. The coated article of claim 1 , wherein the absorber layer comprises NbZrO x N y .

5. The coated article of claim 1 , wherein the first and third contact layers comprise Ni and/or Cr.

6. The coated article of claim 1 , wherein the second contact layer comprises Ni and Cr.

7. The coated article of claim 1 , further comprising a contact layer comprising NiCr located under and directly contacting the first IR reflecting layer.

8. The coated article of claim 1 , wherein the coated article has a transmissive a* value from −8.0 to −1.0 and a transmissive b* value from −8.0 to +1.0.

9. The coated article of claim 1 , wherein the coated article has a visible transmission from 22-39%.

10. The coated article of claim 1 , wherein the coating has a sheet resistance no greater than 7.0 ohms/square.

11. The coated article of claim 1 , wherein respective thicknesses of the first and second IR reflecting layers comprising silver are the same +/−10%.

12. The coated article of claim 1 , wherein the absorber layer contains more Nb than Zr.

13. The coated article of claim 1 , wherein the absorber layer contains from 3-30% oxygen (atomic %).

14. The coated article of claim 1 , wherein a metal content of the absorber layer is from 70-95% Nb (atomic %).

15. The coated article of claim 1 , further comprising a base layer comprising silicon nitride located between the glass substrate and the first IR reflecting layer.

16. The coated article of claim 1 , wherein the absorber layer has a thickness of from 15-100 angstroms.

17. The coated article of claim 1 , wherein the absorber layer has a thickness of from 20-60 angstroms.

18. The coated article of claim 1 , wherein the first and second portions of the dielectric layer comprising silicon nitride are of the same thickness +/−20%.

19. The coated article of claim 1 , wherein the absorber layer consists essentially of NbZrO x N y .

20. The coated article of claim 1 , wherein the absorber layer is thinner than both of the IR reflecting layers comprising silver.

21. The coated article of claim 1 , further comprising an overcoat layer comprising zirconium oxide located over and directly contacting the another dielectric layer comprising silicon nitride.

22. The coated article of claim 1 , wherein the first contact layer comprises NiCr and is substantially metallic or metallic, and contains no more than 5% (atomic %) oxygen.

23. The coated article of claim 1 , wherein the first, second, and third contact layers comprise NiCr and are substantially metallic or metallic, and contain no more than 5% (atomic %) oxygen.

24. The coated article of claim 1 , wherein the coated article is thermally tempered.

25. The coated article of claim 1 , wherein the coated article has a glass side visible reflectance from 12-20%.

26. The coated article of claim 1 , wherein the coated article has a film side reflective b* value from −3 to +7.

27. A IG window unit including the coated article of claim 1 , and another glass substrate which is coupled to said coated article, wherein the IG window unit has an SF value no greater than 0.28 and an SHGC value no greater than 0.29.

28. A IG window unit including the coated article of claim 1 , and another glass substrate which is coupled to said coated article, wherein the IG window unit has an SF value no greater than 0.25 and an SHGC value no greater than 0.25.

29. A IG window unit including the coated article of claim 1 , and another glass substrate which is coupled to said coated article, wherein the IG window unit has an SF value no greater than 0.23 and an SHGC value no greater than 0.23.

30. A coated article including a coating supported by a glass substrate and having grey glass side reflective color, the coating comprising:
first and second infrared (IR) reflecting layers comprising silver, the first IR reflecting layer being located closer to the glass substrate than is the second IR reflecting layer;
a first contact layer located over and directly contacting the first IR reflecting layer comprising silver;
a dielectric layer comprising silicon nitride located over and directly contacting the first contact layer;
wherein the dielectric layer comprising silicon nitride is split by a splitting absorber layer, so that the splitting absorber layer is located between and contacting a first portion of the dielectric layer comprising silicon nitride and a second portion of the dielectric layer comprising silicon nitride;
a second contact layer located over the layer comprising silicon nitride;
the second IR reflecting layer comprising silver located over and directly contacting the second contact layer;
a third contact layer located over and directly contacting the second IR reflecting layer;
another dielectric layer comprising silicon nitride located over the third contact layer;
wherein the coated article has a visible transmission of from 20-45%; and
wherein the coated article has grey glass side reflective coloration so that the coated article has a glass side reflective a* value from −2.5 to 0 and a glass side reflective b* value from −7.0 to −1.0 (Ill. C, 2 degree observer).

31. A coated article including a coating supported by a glass substrate, the coating comprising:
first and second infrared (IR) reflecting layers comprising silver, the first IR reflecting layer being located closer to the glass substrate than is the second IR reflecting layer;
a first contact layer located over and directly contacting the first IR reflecting layer

Assignees

• Guardian Glass Llc
• Guardian Glass Holding S P C
• Guardian Glass L L C

Inventors

• Biswas Aritra
• Boyce Brent
• Chu Allen
• Lingle Philip J
• Lord Kenneth
• Naidu Muniswami
• Vantaku Venkata Krishnaswamy Naidu

Classifications

• G02B5/282

  reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection · CPC title

• G02B5/208

  for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation · CPC title

• C03C17/366 Primary

  Low-emissivity or solar control coatings · CPC title

• C03C17/3652

  the coating stack containing at least one sacrificial layer to protect the metal from oxidation · CPC title

• C03C17/3649

  made of metals other than silver · CPC title