Application of formaldehyde sulfoxylates for scavenging H2S

Patent metadata

Field	Value
Publication number	US-10940407-B2
Application number	US-201816031876-A
Country	US
Kind code	B2
Filing date	Jul 10, 2018
Priority date	Jul 12, 2017
Publication date	Mar 9, 2021
Grant date	Mar 9, 2021

Abstract

A scavenger comprising a formaldehyde sulfoxylate may be used to scavenge hydrogen sulfide (H 2 S) from systems that are brine or mixed production. Suitable formaldehyde sulfoxylates include, but are not necessarily limited to, sodium formaldehyde sulfoxylate, zinc formaldehyde sulfoxylate, and calcium formaldehyde sulfoxylate, potassium formaldehyde sulfoxylate, magnesium formaldehyde sulfoxylate, iron formaldehyde sulfoxylate, copper formaldehyde sulfoxylate, alkene aldehyde sulfoxylates, and combinations thereof.

First claim

What is claimed is:

1. A method for at least partially scavenging hydrogen sulfide (H 2 S) from a system selected from the group consisting of mixed production and water, which system comprises H 2 S, the method consisting of:
contacting the system with a scavenger consisting of water as a solvent and a formaldehyde sulfoxylate in an effective amount to at least partially scavenge H 2 S from the system; and
at least partially scavenging the H 2 S from the system.

2. The method of claim 1 where the effective amount of the formaldehyde sulfoxylate ranges from about 2.5 kg/kg H 2 S to about 50 kg/kg H 2 S in the system.

3. The method of claim 1 where the formaldehyde sulfoxylate is selected from the group consisting of sodium formaldehyde sulfoxylate, zinc formaldehyde sulfoxylate, calcium formaldehyde sulfoxylate, potassium formaldehyde sulfoxylate, magnesium formaldehyde sulfoxylate, iron formaldehyde sulfoxylate, copper formaldehyde sulfoxylate, alkene aldehyde sulfoxylates, and combinations thereof.

4. The method of claim 1 where:
when the system comprises water, the contacting occurs for a time period of at least about one hour; and
when the system comprises mixed production, the contacting occurs for a time period of at least about four hours.

5. The method of claim 4 where the system is a mixed production system consisting of oil, a hydrocarbon gas and at least 50 wt % water.

6. The method of claim 1 where the method is practiced in a temperature range between about 0° C. and about 93° C.

7. The method of claim 1 where the system is present in an application selected from the group consisting of oil wells, gas wells, mixed phase pipelines, transport of sour water for disposal, frac-water systems, acid flow back wells, sour water strippers, and wastewater systems.

8. A method for at least partially scavenging hydrogen sulfide (H 2 S) from a system selected from the group consisting of mixed production and brine, which system comprises H 2 S, the method consisting of:
contacting the system with from about 2.5 kg/kg H 2 S to about 50 kg/kg H 2 S in the system of a scavenger consisting of water as a solvent and a formaldehyde sulfoxylate in an amount to at least partially scavenge H 2 S from the system, where the formaldehyde sulfoxylate is selected from the group consisting of sodium formaldehyde sulfoxylate, zinc formaldehyde sulfoxylate, calcium formaldehyde sulfoxylate, potassium formaldehyde sulfoxylate, magnesium formaldehyde sulfoxylate, iron formaldehyde sulfoxylate, copper formaldehyde sulfoxylate, alkene aldehyde sulfoxylates, and combinations thereof; and
at least partially scavenging the H 2 S from the system.

9. The method of claim 8 where:
when the system comprises brine, the contacting occurs for a time period of at least about one hour; and
when the system comprises mixed production, the contacting occurs for a time period of at least about four hours.

10. The method of claim 9 where the system is a mixed production system consisting of oil, a hydrocarbon gas and at least 50 wt % water.

11. The method of claim 8 where the method is practiced in a temperature range between about 0° C. and about 93° C.

12. The method of claim 8 where the system is present in an application selected from the group consisting of oil wells, gas wells, mixed phase pipelines, transport of sour water for disposal, frac-water systems, acid flow back wells, sour water strippers, and wastewater systems.

Assignees

• Baker Hughes A Ge Co Llc
• Baker Hughes Holdings Llc

Inventors

• Lehrer Scott E
• Chakraborty Soma
• Ramachandran Sunder
• Phan Kimchi T

Classifications

• B01D17/047

  with separation aids · CPC title

• C10G29/28

  containing sulfur as the only hetero atom, e.g. mercaptans, or sulfur and oxygen as the only hetero atoms · CPC title

• B01D19/0005 Primary

  with one or more auxiliary substances · CPC title

• C02F1/20

  by degassing, i.e. liberation of dissolved gases (degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D) · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title