Metal carboxylate salts as H2S scavengers in mixed production or dry gas or wet gas systems

Patent metadata

Field	Value
Publication number	US-9480946-B2
Application number	US-201414221501-A
Country	US
Kind code	B2
Filing date	Mar 21, 2014
Priority date	Apr 15, 2013
Publication date	Nov 1, 2016
Grant date	Nov 1, 2016

Abstract

A transition metal carboxylate scavenger may be used to scavenge contaminants from systems from mixed production and/or gas, either dry or wet hydrocarbon gas. The contaminants scavenged or otherwise removed may include, but are not necessarily limited to, H 2 S, mercaptans, sulfides, and combinations thereof. Suitable transition metal carboxylates in the scavenger include, but are not limited to, zinc octoate, zinc dodecanoate, zinc naphthenate, and combinations thereof.

First claim

What is claimed is:

1. A method for at least partially scavenging a contaminant from a system selected from the group consisting of wet hydrocarbon gas, and dry hydrocarbon gas, the method comprising:
contacting the system with a transition metal carboxylate scavenger in an effective amount to at least partially scavenge a contaminant from the system, where the contaminant is selected from the group consisting of H 2 S, a mercaptan, a sulfide and combinations thereof, where a carboxylic acid complexed with the transition metal has 8 to 25 carbon atoms; and
at least partially scavenging the contaminant from the system.

2. The method of claim 1 where the transition metal carboxylate scavenger comprises from about 10 to about 100 wt % transition metal carboxylate and about 90 to about 5 wt % aromatic solvent.

3. The method of claim 2 where the transition metal in the transition metal carboxylate is selected from the group consisting of zinc, iron, copper, cobalt, calcium, manganese, and combinations thereof.

4. The method of claim 2 where the transition metal carboxylate is selected from the group consisting of zinc octoate, zinc dodecanoate, zinc naphthenate, and combinations thereof.

5. The method of claim 1 where the effective amount of the transition metal carboxylate scavenger is from about 1 to about 50,000 ppm by volume based on the system.

6. The method of claim 1 where the system consists of dry hydrocarbon gas.

7. The method of claim 1 where the system consists of wet hydrocarbon gas.

8. A method for at least partially scavenging a contaminant from a system selected from the group consisting of wet hydrocarbon gas, and dry hydrocarbon gas, the method comprising:
contacting the system with a transition metal carboxylate scavenger in an amount from about 1 to about 50,000 ppm by volume based on the system, where the transition metal in the transition metal carboxylate is selected from the group consisting of zinc, iron, copper, cobalt, calcium, manganese, and combinations thereof, and where the contaminant is selected from the group consisting of H 2 S, a mercaptan, a sulfide and combinations thereof, where a carboxylic acid complexed with the transition metal has 8 to 25 carbon atoms; and
at least partially scavenging the contaminant from the system.

9. The method of claim 8 where the transition metal carboxylate scavenger comprises from about 10 to about 100 wt % transition metal carboxylate and about 90 to about 5 wt % aromatic solvent.

10. The method of claim 9 where the transition metal carboxylate is selected from the group consisting of zinc octoate, zinc dodecanoate, zinc naphthenate, and combinations thereof.

11. A system treated for a contaminant, where the system comprises a composition selected from the group consisting of wet hydrocarbon gas, and dry hydrocarbon gas, where:
the system comprises a contaminant selected from the group consisting of H 2 S, a mercaptan, a sulfide and combinations thereof; and
the system comprises a transition metal carboxylate scavenger in an effective amount to at least partially scavenge the contaminant from the system, where a carboxylic acid complexed with the transition metal has 8 to 25 carbon atoms.

12. The system of claim 11 where the transition metal carboxylate scavenger comprises from about 10 to about 100 wt % transition metal carboxylate and about 90 to about 5 wt % aromatic solvent.

13. The system of claim 12 where the transition metal in the transition metal carboxylate is selected from the group consisting of zinc, iron, copper, cobalt, calcium, manganese, and combinations thereof.

14. The system of claim 12 where the transition metal carboxylate is selected from the group consisting of zinc octoate, zinc dodecanoate, zinc naphthenate, and combinations thereof.

15. The system of claim 11 where the effective amount of the transition metal carboxylate scavenger is from about 1 to about 10,000 ppm by volume based on the system.

16. The system of claim 11 where the composition consists of dry hydrocarbon gas.

17. The system of claim 11 where the composition consists of wet hydrocarbon gas.

Assignees

• Baker Hughes Inc

Inventors

• Ramachandran Sunder
• Lehrer Scott E
• Jovancicevic Vladimir

Classifications

• C10L3/103

  Sulfur containing contaminants · CPC title

• C10L3/00

  Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas · CPC title

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D2256/24

  Hydrocarbons · CPC title

• B01D2251/80

  Organic bases or salts · CPC title