Resin composition including acrylic block copolymer and light diffusing agent

Patent metadata

Field	Value
Publication number	US-10935697-B2
Application number	US-201816486058-A
Country	US
Kind code	B2
Filing date	Feb 9, 2018
Priority date	Feb 16, 2017
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

A resin composition is provided which has high transparency, light guiding properties and luminescent properties and can guide light therethrough with little change in chromaticity. A shaped article such as an optical element including the resin composition is also provided. The resin composition includes an acrylic block copolymer (A) and a light diffusing agent (B), wherein the acrylic block copolymer (A) has at least one structure in which polymer blocks (a1) based on methacrylic acid ester units are bonded to both ends of a polymer block (a2) based on acrylic acid ester units, and has a weight average molecular weight of 10,000 to 150,000 and a tensile elastic modulus of 1 to 1,500 MPa, the light diffusing agent (B) is rutile titanium oxide having an average particle size of 0.5 to 2.0 μm, and the content of the light diffusing agent (B) is 0.5 to 10 ppm (on mass basis) based on the acrylic block copolymer (A).

First claim

The invention claimed is:

1. A resin composition, comprising an acrylic block copolymer (A), a light diffusing agent (B), an antioxidant (C), and a colorant (D),
wherein the acrylic block copolymer (A) comprises at least one structure in which polymer blocks (a 1 ) based on methacrylic acid ester units are bonded to both ends of a polymer block (a 2 ) based on acrylic acid ester units, and has a weight average molecular weight of 10,000 to 150,000 and a tensile elastic modulus of 1 to 1,500 MPa,
the light diffusing agent (B) is rutile titanium oxide having an average particle size of 0.5 to 2.0 μm, a content of the light diffusing agent (B) is 0.5 to 10 ppm by mass, based on the acrylic block copolymer (A), and
the colorant (D) is selected from the group consisting of a blue colorant with a maximum absorption wavelength in a range of from 590 to 610 nm, and a purple colorant with a maximum absorption wavelength in a range of from 510 to 530 nm.

2. The resin composition of claim 1 , which comprises 0.01 to 1 part by mass of a phosphite compound of formula (i) below as the antioxidant (C) per 100 parts by mass of the acrylic block copolymer (A),

wherein
R 1 is an optionally substituted aromatic group,
R 2 and R 3 are each independently a hydrogen atom or an organic group,
R 1 and R 2 or R 3 may be bonded to each other to form a ring together with the phosphorus atom and the oxygen atom constituting the phosphite, and
R 2 and R 3 may be bonded to each other to form a ring together with the phosphorus atom and the oxygen atom constituting the phosphite.

3. The resin composition of claim 1 , wherein a refractive index of the acrylic block copolymer (A) is 1.485 to 1.495.

4. The resin composition of claim 1 , wherein an order-disorder transition temperature (ODTT) of the acrylic block copolymer (A) is not more than 260° C.

5. The resin composition of claim 1 , wherein the polymer block (a 2 ) is a copolymer block comprising 50 to 90 mass % of an acrylic acid alkyl ester and 50 to 10 mass % of an acrylic acid aromatic ester.

6. The resin composition of claim 1 , wherein the polymer blocks (a 1 ) and the polymer block (a 2 ) each have a refractive index of 1.485 to 1.495.

7. The resin composition of claim 1 , which comprises 0.1 to 4 ppm by mass, based on the acrylic block copolymer (A), of the blue colorant with a maximum absorption wavelength in a range of from 590 to 610 nm as a colorant (D).

8. The resin composition of claim 1 , which comprises 0.1 to 10 ppm by mass, based on the acrylic block copolymer (A), of the purple colorant with a maximum absorption wavelength in a range of from 510 to 530 nm as a colorant (D).

9. A shaped article, comprising the resin composition of claim 1 .

10. The shaped article of claim 9 , which is an optical element.

11. The shaped article of claim 9 , which is a light guide.

Assignees

• Kuraray Co

Inventors

• Sugawara Toshiaki
• Akai Makoto
• Kataoka Dai

Classifications

• G02B6/0065

  Manufacturing aspects; Material aspects · CPC title

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title

• C08K5/52

  Phosphorus bound to oxygen only · CPC title

• C08K3/22 Primary

  of metals · CPC title