Water swellable lost circulation materials

Patent metadata

Field	Value
Publication number	US-10934469-B2
Application number	US-201415515981-A
Country	US
Kind code	B2
Filing date	Nov 21, 2014
Priority date	Nov 21, 2014
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

Lost circulation compositions, systems, and methods of using the same are described. A lost circulation composition comprises a water-swellable starch graft copolymer; and a carrier fluid. A method for bridging a lost circulation zone comprises providing a lost circulation composition comprising a water-swellable starch graft copolymer and a carrier fluid. Then introducing the lost circulation composition into a wellbore within a subterranean formation, wherein the subterranean formation comprises a lost circulation zone. Finally the lost circulation composition is placed into the lost circulation zone.

First claim

What is claimed is:

1. A method for treating a lost circulation zone comprising:
providing a lost circulation composition comprising;
a lost circulation material comprising:
a water-swellable starch graft copolymer, wherein the water-swellable starch graft copolymer is cross-linked, wherein the water-swellable starch graft copolymer has a particle size of from about 1 mesh to about 200 mesh, wherein the water-swellable starch graft copolymer consists of a single type of monomer grafted onto a starch, wherein the monomer is selected from the group consisting of methacrylamide, 2-acrylamido-2-methyl-propanesulfonic acid, vinyl sulfonic acid, ethyl acrylate, and potassium acrylate, and wherein a weight ratio of the starch to the monomer is in the range of 1:1 to 1:6;

a carrier fluid, wherein the carrier fluid is present in an amount of from about 50% to about 80% by weight of the lost circulation composition; and
a viscosifier, wherein the viscosifier is present in an amount of about 0.1% to about 2% by weight of the lost circulation composition;

introducing the lost circulation composition into a wellbore within a subterranean formation, wherein the subterranean formation comprises a lost circulation zone;
placing the lost circulation composition into the lost circulation zone;
contacting the lost circulation material in the lost circulation zone with an acid and at least partially dissolving the lost circulation material with the acid; and
removing at least a portion of the lost circulation material from the lost circulation zone.

2. The method of claim 1 wherein the water-swellable graft copolymer comprises at least one starch selected from the group consisting of corn starches, waxy maize starches, wheat starches, potato starches, dextrin starches, dextran starches, corn meal, peeled yucca root, unpeeled yucca root, oat flour, banana flour, tapioca flour, and combinations thereof.

3. The method of claim 1 wherein the water-swellable starch graft copolymer is up to about 40% acid-soluble.

4. The method of claim 1 wherein the carrier fluid is selected from the group consisting of petroleum oil, natural oil, synthetically derived oil, mineral oil, silicone oil, kerosene oil, diesel oil, an alpha olefin, an internal olefin, an ester, a diester of carbonic acid, a paraffin, and combinations thereof.

5. The method of claim 1 wherein the water-swellable starch graft copolymer has a multi-modal particle size distribution.

6. The method of claim 1 wherein the viscosifier is selected from the group consisting of colloidal agents, emulsion-forming agents, diatomaceous earth, biopolymers, synthetic polymers, chitosans, starches, gelatins, and combinations thereof.

7. The method of claim 1 wherein the lost circulation composition further comprise at least one additional lost circulation material selected from the group consisting of cedar bark, shredded cane stalks, mineral fiber, mica flakes, cellophane, ground rubber, polymeric materials, pieces of plastic, grounded marble, wood, nut hulls, plastic laminates, corncobs, cotton hulls, and combinations thereof.

8. The method of claim 1 wherein the lost circulation composition further comprises an acid-soluble filler selected from the group consisting of dolomite, magnesium carbonate, calcium carbonate, zinc carbonate, and combinations thereof.

9. The method of claim 1 wherein the lost circulation zone is in a producing zone.

10. The method of claim 1 wherein the acid is at least one of formic acid or hydrochloric acid.

11. The method of claim 8 , wherein the acid soluble filler is present in an amount of about 15 wt. % to about 50 wt. % by weight of the lost circulation material.

Assignees

• Halliburton Energy Services Inc

Inventors

• Walker Jonathan Paul
• Miller Matthew Lynn

Classifications

• C09K8/514 Primary

  of natural origin, e.g. polysaccharides, cellulose (C09K8/512 takes precedence) · CPC title

• C09K8/50

  Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls (compositions for consolidating loose sand or the like around wells C09K8/56) · CPC title

• C09K8/502 Primary

  Oil-based compositions · CPC title

• C09K8/512

  containing cross-linking agents · CPC title

• C09K8/487

  Fluid loss control additives; Additives for reducing or preventing circulation loss · CPC title