Cellulose resin, material for molding, molded body and process for producing cellulose resin

Patent metadata

Field	Value
Publication number	US-10934368-B2
Application number	US-201616066521-A
Country	US
Kind code	B2
Filing date	Dec 9, 2016
Priority date	Dec 28, 2015
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

A cellulose resin formed by substituting hydrogen atoms of hydroxy groups of a cellulose with a long-chain component being a linear saturated aliphatic acyl group having 14 or more carbon atoms and a short-chain component being an acyl group having 2 or 3 carbon atoms, in which a degree of substitution with the long-chain component (DS Lo ) and a degree of substitution with the short-chain component (DS Sh ) satisfy conditional expressions (1) and (2) shown below:

DS Lo +DS Sh ≥2.1  (1)

4≤DS Sh /DS Lo ≤12  (2).

First claim

The invention claimed is:

1. A cellulose resin formed by substituting hydrogen atoms of hydroxy groups of a cellulose with a long-chain component being a linear saturated aliphatic acyl group having 14 or more carbon atoms and a short-chain component,
wherein the short-chain component is a propionyl group,
the cellulose resin has a reinforcing crystal structure due to a cellulose main-chain crystal of the cellulose, and
a degree of substitution with the long-chain component (DS Lo ) and a degree of substitution with the short-chain component (DS Sh ) satisfy conditional expressions (1) and (2) shown below:
DS Lo +DS Sh ≥2.1  (1)

4≤DS Sh /DS Lo ≤12  (2).

2. The cellulose resin according to claim 1 , wherein the long-chain component is an acyl group moiety of at least one fatty acid selected from myristic acid, palmitic acid, stearic acid, arachidic acid and behenic acid.

3. A molding material comprising the cellulose resin according to claim 1 .

4. A molded body formed by using the molding material according to claim 3 .

5. A process for producing the cellulose resin according to claim 1 , comprising:
acylating hydroxy groups of a cellulose constituting pulp by reacting
the pulp dispersed in an organic solvent with
a short-chain reactant selected from the group consisting of propionic anhydride and propionyl chloride, and
a long-chain reactant being an acid chloride of a long-chain fatty acid and having the long-chain component,
in the presence of an acid trapping component while warming; and

separating an acylated cellulose obtained in the acylating from the organic solvent.

6. The process for producing the cellulose resin according to claim 5 , wherein the organic solvent is a solvent providing a liquid holding rate by cellulose of 90% by volume or more.

7. The process for producing the cellulose resin according to claim 5 , wherein the acid trapping component contains triethylamine or pyridine.

8. The process for producing the cellulose resin according to claim 5 , wherein the acylating is carried out at a reaction temperature of 50 to 100° C.

9. The process for producing the cellulose resin according to claim 5 , wherein the organic solvent is used in an amount 10 to 50 times as large as the dry mass of the pulp.

10. The process for producing the cellulose resin according to claim 5 , further comprising, after the acylating, a holding step at 25 to 75° C. for 1 to 5 hours after an aqueous alkaline solution is added.

11. The cellulose resin according to claim 1 , wherein DS Lo is 0.2 or more, and DS Sh is 1.7 or more.

12. The cellulose resin according to claim 1 , wherein DS Lo is in a range of 0.2 to 0.6, and DS Sh is in a range of 1.7 to 2.8.

13. The cellulose resin according to claim 1 , wherein in X-ray diffraction using CuKα, a peak is present in the vicinity of either one or both of 2 θ=22°, 34°.

14. The cellulose resin according to claim 1 , wherein a polymerization degree of the cellulose is in a range of 50 to 5000.

Assignees

• Nec Corp

Inventors

• Tanaka Shukichi
• Shimura Midori
• Iji Masatoshi

Classifications

• C08L1/14

  Mixed esters, e.g. cellulose acetate-butyrate · CPC title

• C08B3/16 Primary

  Preparation of mixed organic cellulose esters {, e.g. cellulose aceto-formate or cellulose aceto-propionate} · CPC title