Multi-strand plant and process for producing olefins from oxygenates

Patent metadata

Field	Value
Publication number	US-10927050-B2
Application number	US-202016873554-A
Country	US
Kind code	B2
Filing date	May 1, 2020
Priority date	May 3, 2019
Publication date	Feb 23, 2021
Grant date	Feb 23, 2021

Abstract

The invention relates to a multi-strand plant and a corresponding process for producing olefins from oxygenates in which a plurality of reactor trains which each comprise one or more catalyst-containing oxygenate-to-olefin (OTO) reaction zones are arranged in parallel and operated in parallel, wherein at least one of the parallel reaction zones may be operated in a regeneration mode while the OTO synthesis reaction may be performed in the other reaction zones parallel thereto. The partial product streams obtained from the individual reactor trains operated in a synthesis mode are discharged via partial product conduits, combined into a complete product conduit using a connecting device, compressed using a compressor and separated into a plurality of olefin-containing hydrocarbon fractions using a multi-stage workup apparatus. The inventive configuration of the plant and of the process reduces pressure drops and thus enhances the yield for short-chain olefins, for example propylene.

First claim

What is claimed is:

1. A multi-strand plant for producing olefins from an oxygenates-containing fluid input mixture comprising the following constituents and assemblies in fluid connection with one another:
(a) at least two reactor trains arranged in parallel and operable in parallel, wherein each reactor train comprises:
(a1) at least one oxygenate-to-olefin reaction zone containing a catalyst active and selective for the conversion of the oxygenates into olefins under oxygenate conversion conditions, a means for supplying the oxygenates-containing input mixture to the reaction zone, a means for discharging an olefins-containing partial product stream from the reaction zone, a means for supplying a gaseous oxygen-containing regenerant to the reaction zone, and a means for discharging a carbon oxides-containing regeneration offgas from the reaction zone,
(a2) a thermal recovery apparatus arranged downstream of the reaction zone comprising at least one heat exchanger for performing indirect heat exchange between the product gas discharged from the reaction zone and a cooling fluid,
(a3) a partial product conduit arranged downstream of the thermal recovery apparatus for discharging the partial product stream from the reactor train,
(a4) a shutoff device in the conduit path of the partial product conduit for separating a reactor train from downstream plant parts and parallel reactor trains,

(b) a connecting device arranged downstream of the individual reactor trains for combining the individual partial product conduits into a complete product conduit,
(c) a compressor arranged downstream of the connecting device for compressing the complete product supplied using the complete product conduit,
(d) a multi-stage workup apparatus arranged downstream of the compressor for separating the compressed complete product into a plurality of olefin-containing hydrocarbon fractions,
(e) wherein furthermore at least one first quench zone for performing direct heat exchange between one or more partial product streams or the complete product stream and a first quenching medium is comprised, wherein the first quench zone is arranged downstream of the thermal recovery apparatus and upstream of the compressor.

2. The plant according to claim 1 , wherein arranged in every reactor train downstream of the thermal recovery apparatus are at least two partial product conduits for discharging the partial product stream from the reactor train which are arranged in parallel and operable in parallel, and wherein at least one shutoff device is present in the conduit path of each of the parallel partial product conduits.

3. The plant according to claim 1 , wherein a first quench zone for performing direct heat exchange between a partial product stream and a first quenching medium is comprised and is arranged downstream of the thermal recovery apparatus and upstream of the connecting device and in that a second quench zone for performing direct heat exchange between the complete product stream and a second quenching medium is further comprised and is arranged downstream of the connecting device and upstream of the compressor and is in fluid connection with all partial product conduits from the individual reactor trains.

4. The plant according to claim 3 , wherein the first quench zone is arranged downstream of the thermal recovery apparatus and upstream of the shutoff device.

5. The plant according to claim 1 , wherein the at least one reaction zone and the thermal recovery apparatus arranged downstream of the reaction zone are arranged in a common vessel, and wherein the partial product conduit arranged downstream of the thermal recovery apparatus is used to discharge the partial product stream from the vessel.

6. The plant according to claim 1 , wherein:
the at least one reaction zone and the thermal recovery apparatus arranged downstream of the reaction zone are arranged in a common vessel,
the partial product stream is discharged from the vessel using the partial product conduit arranged downstream of the thermal recovery apparatus,
all partial product conduits of the reactor trains are combined using the connecting device,
the first quench zone is arranged between the connecting device and the compressor and is in fluid connection with all partial product conduits of the individual reactor trains.

7. The plant according to claim 1 , wherein:
the at least one reaction zone, the thermal recovery apparatus arranged downstream of the reaction zone and the first quench zone arranged downstream of the thermal recovery apparatus are arranged in a common vessel,
the partial product stream is discharged from the vessel using the partial product conduit arranged downstream of the first quench zone,
all partial product conduits of the reactor trains are combined using the connecting device, and
the second quench zone is arranged between the connecting device and the compressor and is in fluid connection with all partial product conduits of the individual reactor trains.

8. The plant according to claim 1 , wherein:
the at least one reaction zone, the thermal recovery apparatus arranged downstream of the reaction zone, the first quench zone arranged downstream of the thermal recovery apparatus and the second quench zone arranged downstream of the first quench zone are arranged in a common vessel, and
the partial product stream is discharged from the vessel using the partial product conduit arranged downstream of the second quench zone,
all partial product conduits of the reactor trains are combined using the connecting device.

9. The plant according to claim 5 , wherein the common vessel is connected to a conduit for discharging a liquid condensate.

10. The plant according to claim 5 , wherein the thermal recovery apparatuses are in the form of plate heat exchangers.

11. The plant according to claim 10 , wherein the thermal recovery apparatuses comprise at least two plate heat exchangers operated with different cooling fluids.

12. The plant according to claim 5 , wherein the reaction zones are in a heat transfer relationship with plate heat exchangers by means of which the reaction zones are cooled with a cooling fluid by indirect heat exchange.

13. A process for producing olefins from an oxygenates-containing fluid input mixture comprising the following steps:
(a) providing the oxygenates-containing fluid input mixture,
(b) supplying the oxygenates-containing fluid input mixture to a plant according to claim 1 , and converting the input mixture into olefin-containing partial product streams under oxygenate conversion conditions,
(c) discharging at least one olefin-containing hydrocarbon fraction from the plant, wherein
the plant comprises at least two reactor trains arranged in parallel and operable in parallel, of which
at least one reactor train is supplied with oxygenates-containing, fluid input mixture, wherein the obtained partial product stream is discharged from the reactor train and via the opened shutoff device and the connecting device is supplied to the workup apparatus and in parallel therewith
at least one further reactor train is supplied with a gaseous oxygen-containing regenerant, wherein a carbon oxides-containing regeneration offgas is obtained which is discharged from the reactor train and wherein the shutoff device of this reactor train is closed.

14. The process according to claim 13 , wherein the plant comprises three reactor trains, of which two are supplied with oxygenates-containing, fluid input mixture and in parallel thereto one is supplied with a gaseous oxygen-containing regenerant.

15. The process acc

Assignees

• Air Liquide

Inventors

• Williams Bryce
• Haag Stephane
• Drosdzol Christopher
• Castillo-Welter Frank

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• F28D2021/0022

  for chemical reactors · CPC title

• F28D21/00

  Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00 · CPC title

• C10G3/54 Primary

  characterised by the catalytic bed · CPC title

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title