Process and plant for producing olefins from oxygenates

Patent metadata

Field	Value
Publication number	US-10214461-B2
Application number	US-201514843139-A
Country	US
Kind code	B2
Filing date	Sep 2, 2015
Priority date	Sep 5, 2014
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

A process for producing olefins from oxygenates can include the following steps: (i) heterogeneously catalyzed conversion of at least one oxygenate to a product stream containing C 2 olefins, C 3 olefins, C 4 olefins, C 5/6 hydrocarbon compounds, and C 7+ hydrocarbon compounds; and (ii) separation of a propylene stream consisting of C 3 olefins for at least 95 wt-%, wherein at least 10 wt-% of the propylene stream are recirculated into process step (i).

First claim

We claim:

1. A process for producing olefins from oxygenates, the process comprising a first mode of operation for the production of propylene and a second mode of operation for the production of butylene,
wherein the first mode of operation comprises the following steps:
(i) heterogeneously catalyzed converting of at least one oxygenate to a product stream containing C 2 olefins, C 3 olefins, C 4 olefins, C 5/6 hydrocarbon compounds, and C 7+ hydrocarbon compounds, wherein the step of heterogeneously catalyzed converting is effected in two stages, wherein in the first stage methanol is converted with an equilibrium reaction into dimethyl ether and in the second stage dimethyl ether and unconverted methanol are converted to the product stream containing C 2 olefins, C 3 olefins, C 4 olefins, C 5/6 hydrocarbon compounds and C 7+ hydrocarbon compounds, wherein the second stage of the heterogeneously catalyzed conversion is operated at an operating temperature of 390° C. to 500° C.,
(ii) recycling at least a portion of the C 4 olefins into the second stage;
(iii) separating a stream comprising the C 3 olefins from the product stream or a stream derived therefrom;
wherein the second mode of operation comprises the following steps:
(i) heterogeneously catalyzed converting of at least one oxygenate to a product stream containing C 2 olefins, C 3 olefins, C 4 olefins, C 5/6 hydrocarbon compounds, and C 7+ hydrocarbon compounds, wherein the step of heterogeneously catalyzed converting is effected in two stages, wherein in the first stage methanol is converted with an equilibrium reaction into dimethyl ether and in the second stage dimethyl ether and unconverted methanol are converted to the product stream containing C 2 olefins, C 3 olefins, C 4 olefins, C 5/6 hydrocarbon compounds and C 7+ hydrocarbon compounds, wherein the second stage of the heterogeneously catalyzed conversion is operated at an operating temperature of 390° C. to 500° C.,
(ii) recycling at least 10 wt-% of the C 3 olefins into the second stage;
(iii) separating a stream comprising the C 4 olefins from the product stream or a stream derived therefrom;
(iv) separating a stream comprising butane from the product stream or a stream derived therefrom;
(v) separating a stream comprising the C 5/6 hydrocarbon compounds from the product stream or a stream derived therefrom;
(vi) separating a stream comprising the C 7+ hydrocarbon compounds from the product stream or a stream derived therefrom;
(vii) recirculating of at least a portion of the C 5/6 hydrocarbon stream and the C 7+ hydrocarbon stream into the second stage in an amount effective to maintain the operating temperature of the second stage,
wherein the second mode of operation has a higher amount of C 3 olefins recirculated to the second stage as compared to the first mode of operation,
wherein the second mode of operation is configured to provide an increased yield in the C 4 olefins as compared to the first mode of operation.

2. The process as claimed in claim 1 , wherein, during the second mode of operation, a ratio of a molar sum of all recirculated olefins to a molar sum of the oxygenates used lies between 0.75 and 3.

3. The process as claimed in claim 1 , wherein if a determination is made that a service life of the catalyst is below a predetermined threshold, the amount of oxygenate used in step (ii) is increased in an amount to maintain olefin production.

4. The process as claimed in claim 1 , wherein, during the second mode of operation an operating pressure of the second stage is increased as compared to the second stage of the first mode of operation.

5. The process as claimed in claim 4 , wherein an inlet reactor pressure is 2-3 bar and an outlet reactor pressure is 1-2 bar.

6. The process as claimed in claim 1 , wherein, during the second mode of operation, the dimethyl ether is introduced to the second stage in a combination of a liquid phase and a gaseous phase, wherein the ratio of the liquid phase to the gaseous phase is adjusted in order to control the temperature within the second stage.

7. The process according to claim 1 , wherein during the second mode of operation, more than 90 wt-% of the C 3 olefins are recirculated into the second stage.

8. The process according to claim 1 , wherein during the second mode of operation, an amount of aromatic compounds in the recirculated C 5/6 and/or C 7+ hydrocarbon streams is ≤5 wt-%.

9. The process according to claim 1 , wherein up to 90 wt-% of the butane stream is recirculated into the second stage during the second mode of operation.

10. The process according to claim 1 , wherein during the second mode of operation, the process further comprises the step of recirculating a portion of the butane stream into step (i) in an amount effective to maintain the operating temperature of the second stage.

11. The process according to claim 1 , wherein during the first mode of operation, 100 wt-% of the C 4 olefins are recirculated into the second stage, and wherein the during the second mode of operation, 100 wt-% of the C 3 olefins and 0 wt-% of the C 4 olefins are recirculated into the second stage.

Assignees

• Air Liquide

Inventors

• Rothamel Martin
• Haag Stephane
• Castillo-Welter Frank
• Trabold Peter
• Gorny Martin
• Pohl Sven

Classifications

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• Y02P30/42

  Cross-Sectional Technologies · mapped topic

• C07C11/06

  Propene · CPC title

• B01J8/0453

  the beds being superimposed one above the other · CPC title