Device and method of manufacturing high aspect ratio structures

Patent metadata

Field	Value
Publication number	US-10923729-B2
Application number	US-201615744628-A
Country	US
Kind code	B2
Filing date	Jul 15, 2016
Priority date	Jul 15, 2015
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A method of manufacturing a Lithium battery ( 100 ) with a current collector formed of pillars ( 11 ) on a substrate face ( 10 ), wherein the method comprises: forming elongate and aligned structures forming electrically conductive pillars ( 11 ) on the substrate face ( 10 ) with upstanding pillar walls extending from a pillar base to a pillar top; wherein the pillars are covered with a laminate comprising a first electrode ( 12 ), a solid state electrolyte layer ( 13 ); a second electrode layer ( 14 ), and a topstrate ( 20 ) forming an electrode part; and wherein at least one of the first electrode layer, second electrode layer and topstrate layer is non-conformally coated to prevent Lithium intercalation into the first or second electrode near the pillar base by limiting cracking at the pillar base when volume expansion/contraction of the electrode layers happens during the battery charge/discharge cycles.

First claim

The invention claimed is:

1. A method of manufacturing a lithium battery with a current collector formed of pillars on a substrate face, wherein the method comprises: forming elongate and aligned structures forming electrically conductive pillars on the substrate face, each of the pillars having an upstanding pillar wall that extends from a pillar base to a pillar top,
wherein individual ones of the pillars are each covered with a laminate comprising:
a first electrode layer comprising a first electrode;
a solid state electrolyte layer;
a second electrode layer comprising a second electrode; and
a topstrate forming an electrode part; and
wherein the first electrode layer has a minimum distance above the pillar base ranging between 300 and 1000 nanometers, and
wherein the first electrode layer and the second electrode layer do not extend between the pillars,
thereby preventing lithium intercalation into the first electrode and/or the second electrode at a location near the pillar base.

2. The method according to claim 1 , wherein at least one of the group consisting of the first electrode, the electrolyte layer and the second electrode layer does not extend to the pillar top, such that a laminate structure is provided that is severed near axial ends of the pillars.

3. The method according to claim 1 , wherein a minimum interdistance between pillar walls, of neighboring one of the pillars, ranges between 1-10 micrometers.

4. The method according to claim 1 , wherein the current collector is manufactured in a roll-to-roll process.

5. A lithium battery comprising a current collector, wherein the current collector is formed of pillars on a substrate face, and wherein the pillars are each elongate and aligned structures forming electrically conductive pillars on the substrate face, each of the pillars having an upstanding pillar wall that extends from a pillar base to a pillar top;
wherein individual ones of the pillars are each covered with a laminate comprising:
a first electrode layer comprising a first electrode;
a solid state electrolyte layer;
a second electrode layer comprising a second electrode; and
a topstrate forming an electrode part; and
wherein the first electrode layer has a minimum distance above the pillar base ranging between 300 and 1000 nanometers; and
wherein the first electrode layer and the second electrode layer do not extend between the pillars,
thereby preventing lithium intercalation into the first electrode and/or the second electrode at a location near the pillar base.

6. The lithium battery according to claim 5 wherein the current collector is a high-aspect ratio structure wherein individual ones of the pillars have a radius of curvature larger than 50 nanometers.

7. The lithium battery according to claim 5 , wherein the substrate is a metal foil having both faces forming a high-aspect ratio structure.

8. The lithium battery according to claim 5 , having a plurality of current collectors, and wherein one of the plurality of current collectors are alternatingly stacked with respect to neighboring ones of the current collectors.

9. The lithium battery according to claim 5 , wherein at least one of the group consisting of the first electrode, the solid state electrolyte layer and the second electrode layer does not extend to the pillar top, such that a laminate structure is provided that is severed near axial ends of the pillars.

10. The lithium battery according to claim 5 , wherein a minimum interdistance between pillar walls, of neighboring one of the pillars, ranges between 1-10 micrometers.

11. The lithium battery according to claim 5 , wherein the current collector is manufactured in a roll-to-roll process.

Assignees

• TNO

Inventors

• Unnikrishnan Sandeep
• Haverkate Lucas A

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M10/0562

  Solid materials · CPC title

• H01M4/667

  in the form of layers, e.g. coatings · CPC title