Induced material segregation methods of manufacturing a polycrystalline diamond tool

Patent metadata

Field	Value
Publication number	US-10920303-B2
Application number	US-201515569908-A
Country	US
Kind code	B2
Filing date	May 28, 2015
Priority date	May 28, 2015
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

Induced material segregation methods of manufacturing a polycrystalline diamond compact (PDC) cutter result in formation of a polycrystalline diamond/tungsten carbide (WC) composite material having a smooth compositional gradient from maximum WC concentration at one face to maximum diamond concentration at another face. Because the compositional gradient is smooth, very little or no mismatch of coefficient of thermal expansion occurs, which improves a service lifetime of the PDC cutter.

First claim

What is claimed is:

1. A method of manufacturing a polycrystalline diamond compact (PDC) cutter, the method comprising:
introducing a polycrystalline diamond particulate, a substrate particulate, and a binder in a reactor, wherein the binder is a solid phase material at room temperature;
performing induced segregation of the polycrystalline diamond particulate and the substrate particulate in the reactor to form a segregated mixture having a continuous compositional gradient of the polycrystalline diamond particulate and the substrate particulate along an axis of the segregated mixture, wherein the continuous compositional gradient begins with a substrate-rich phase at one end of the axis and ends with a polycrystalline diamond-rich phase at the other end of the axis;
consolidating the segregated mixture to form a green-state material, including the binder immobilizing the polycrystalline diamond particulate and the substrate particulate in the green-state material;
placing the green-state material adjacent to a substrate at a first face of the green-state material, wherein the first face has a maximum concentration of substrate in the continuous compositional gradient;
placing the green-state material adjacent to thermally stable polycrystalline diamond at a second face of the green-state material opposite the first face, wherein the second face has a maximum concentration of polycrystalline diamond in the continuous compositional gradient; and
performing a high-temperature high-pressure (HTHP) sintering process on the green-state material to form the PDC cutter, including applying sintering process conditions to eliminate the binder during the HTHP sintering process.

2. The method of claim 1 , further comprising:
applying the binder prior to introduction into the reactor as a coating to at least one of the polycrystalline diamond particulate and the substrate particulate.

3. The method of claim 1 , wherein the binder includes a material that modifies the diffusion of a catalyst used in the HTHP sintering process.

4. The method of claim 1 , wherein performing the induced segregation further comprises:
using at least one of: a fluidized bed segregation process; a vibratory bed segregation process; and an electrophoresis segregation process.

5. The method of claim 1 , wherein the substrate particulate comprises tungsten carbide (WC), and wherein the binder is a resin.

6. The method of claim 5 , wherein performing the HTHP sintering process further comprises:
placing the green-state material adjacent to a WC substrate at the first face of the green-state material, wherein the first face has a maximum concentration of WC in the continuous compositional gradient.

7. The method of claim 6 , wherein performing the HTHP sintering process further comprises:
placing the green-state material adjacent to thermally stable polycrystalline diamond at the second face of the green-state material, wherein the second face has a maximum concentration of polycrystalline diamond in the continuous compositional gradient.

8. The method of claim 1 , further comprising:
mechanically forming the green-state material to a desired shape.

9. The method of claim 1 , further comprising:
manufacturing and storing the green-state material prior to performing the HTHP sintering process.

10. The method of claim 1 , wherein performing the HTHP process further comprises:
performing an intermediate stage during which a first temperature and a first pressure are applied to eliminate the binder; and
performing a final stage during which a second temperature and a second pressure are applied to sinter the PDC cutter.

11. A method of manufacturing a polycrystalline diamond compact (PDC) cutter, the method comprising:
introducing a polycrystalline diamond particulate and a substrate particulate in a reactor;
performing induced segregation of the polycrystalline diamond particulate and the substrate particulate in the reactor to form a segregated mixture having a continuous compositional gradient of the polycrystalline diamond particulate and the substrate particulate along an axis of the segregated mixture, wherein the continuous compositional gradient begins with a substrate-rich phase at one end of the axis and ends with a polycrystalline diamond-rich phase at the other end of the axis;
after performing the induced segregation, introducing a binder to the reactor, wherein the binder is a fluid phase material in the reactor;
consolidating the segregated mixture to form a green-state material, including the binder immobilizing the polycrystalline diamond particulate and the substrate particulate in the green-state material;
placing the green-state material adjacent to a substrate at a first face of the green-state material, wherein the first face has a maximum concentration of substrate in the continuous compositional gradient;
placing the green-state material adjacent to thermally stable polycrystalline diamond at a second face of the green-state material opposite the first face, wherein the second face has a maximum concentration of polycrystalline diamond in the continuous compositional gradient; and
performing a high-temperature high-pressure (HTHP) sintering process on the green state material to form the polycrystalline diamond tool element, including applying sintering process conditions to eliminate the binder during the HTHP sintering process.

12. The method of claim 11 , wherein the binder includes at least one of:
a liquid phase;
a dispersion;
an emulsion; and
a resin melt.

13. The method of claim 11 , further comprising:
prior to consolidating the segregated mixture, removing excess fluid from the reactor, and wherein consolidating the segregated mixture further comprises a consolidation mechanism selected from at least one of:
inducing a phase change to solidify the binder;
inducing a chemical change to solidify the binder; and
removing a solvent in which the binder is dissolved.

14. The method of claim 11 , wherein performing the induced segregation further comprises:
using at least one of: a fluidized bed segregation process; a vibratory bed segregation process; and an electrophoresis segregation process.

15. The method of claim 11 , further comprising:
mechanically forming the green-state material to a desired shape.

16. The method of claim 11 , wherein the substrate particulate comprises tungsten carbide (WC).

17. The method of claim 16 , wherein performing the HTHP sintering process further comprises:
placing the green-state material adjacent to a WC substrate at the first face of the green-state material, wherein the first face has a maximum concentration of WC in the continuous compositional gradient.

18. The method of claim 17 , wherein performing the HTHP sintering process further comprises:
placing the green-state material adjacent to thermally stable polycrystalline diamond at the second face of the green-state material opposite the first face, wherein the second face has a maximum concentration of polycrystalline diamond in the continuous compositional gradient.

19. The method of claim 11 , further comprising:
manufacturing and storing the green-state material prior to performing the HTHP sintering process.

20. The method of claim 11 , wherein performing the HTHP process further comprises:
performing an intermediate stage during which a first temperature and a first pressure are applied to eliminate the binder; and
performing a final stage during which a second temperature and

Assignees

• Halliburton Energy Services Inc

Inventors

• Murphree Zachary Ryan
• Chang Andy Cheng
• Saini Gagan

Classifications

• E21B10/02

  Core bits (characterised by wear resisting parts E21B10/48) · CPC title

• B22F2005/001

  Cutting tools, earth boring or grinding tool other than table ware · CPC title

• B22F7/06

  of composite workpieces or articles from parts, e.g. to form tipped tools {(B22F7/002 takes precedence)} · CPC title

• B22F5/00

  Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product · CPC title

• B22F3/15 Primary

  Hot isostatic pressing · CPC title