Method and system for manufacturing a lithium metal negative electrode

Patent metadata

Field	Value
Publication number	US-10919112-B2
Application number	US-201815967079-A
Country	US
Kind code	B2
Filing date	Apr 30, 2018
Priority date	Apr 30, 2018
Publication date	Feb 16, 2021
Grant date	Feb 16, 2021

Abstract

A negative electrode for an electrochemical cell of a lithium metal battery may be manufactured by joining together a metallic current collector piece and a lithium metal piece. The metallic current collector piece may be positioned adjacent the lithium metal piece in an at least partially lapped configuration at a weld site. A laser beam may be directed at an upper surface of the metallic current collector piece at the weld site to melt a portion of the lithium metal piece adjacent the metallic current collector piece and produce a lithium metal molten weld pool. The second laser beam may be terminated to solidify the lithium metal molten weld pool into a solid weld joint that physically bonds the lithium metal piece and the metallic current collector piece together at the weld site.

First claim

What is claimed is:

1. A method of manufacturing a negative electrode for an electrochemical cell of a lithium metal battery, the method including the following steps:
(a) delivering a continuous lithium metal sheet to a cutting station;
(b) directing a first laser beam at an upper surface of the lithium metal sheet and advancing the first laser beam relative to the upper surface of the lithium metal sheet to cut off an end portion of the lithium metal sheet and form a lithium metal piece;
(c) delivering the lithium metal piece to a joining station;
(d) positioning a metallic current collector piece adjacent the lithium metal piece in an at least partially lapped configuration such that a faying surface of the metallic current collector piece confronts a faying surface of the lithium metal piece to establish a faying interface between the pieces at a weld site;
(e) positioning a transparent cover over the metallic current collector piece at the weld site such that the transparent cover presses against an upper surface of the metallic current collector piece and the faying surfaces of the metallic current collector piece and the lithium metal piece press against each other at the weld site;
(f) directing a second laser beam at the upper surface of the metallic current collector piece at the weld site to melt a portion of the lithium metal piece adjacent the faying surface of the metallic current collector piece and produce a lithium metal molten weld pool that wets the faying surface of the metallic current collector piece;
(g) terminating the second laser beam to solidify the lithium metal molten weld pool into a solid weld joint that physically bonds the lithium metal piece and the metallic current collector piece together at the weld site; and
(h) continuously repeating and coordinating steps (a) through (g) so that steps (b) and (f) are performed at different times using the same laser scanning head,
wherein the continuous lithium metal sheet and the lithium metal piece are respectively delivered to the cutting station and to the joining station by a first platform traveling in a first direction, and wherein the metallic current collector piece is delivered to the joining station by a second platform traveling in a second direction opposite the first direction.

2. The method of claim 1 wherein the first laser beam is a pulsed laser beam having a power density in the range of 5.0×10 5 W/cm 2 to 1.0×10 9 W/cm 2 and a pulse repetition rate in the range of 1 kHz to 100 kHz.

3. The method of claim 1 wherein the second laser beam is a pulsed laser beam having a power density in the range of 3×10 5 W/cm 2 to 1×10 7 W/cm 2 and a pulse repetition rate in the range of 100 kHz to 10 MHz.

4. The method of claim 1 wherein the first and second laser beams are generated by the same laser beam generator and movement of the first and second laser beams is accomplished by a plurality of moveable mirrors housed within the same laser scanning head.

5. The method of claim 1 including:
prior to step (c), transferring the lithium metal piece to a shaping station; and
directing a third laser beam at an upper surface of the lithium metal piece; and
advancing the third laser beam relative to the upper surface of the lithium metal piece to trim the lithium metal piece into a desired shape,
wherein the first, second, and third laser beams are generated by the same laser beam generator and movement of the first, second, and third laser beams is accomplished by a plurality of moveable mirrors housed within the same laser scanning head.

6. The method of claim 1 wherein step (b) includes:
advancing the first laser beam relative to the upper surface of the lithium metal sheet in a linear path across an entire width of the lithium metal sheet.

7. The method of claim 1 wherein step (f) includes:
advancing the second laser beam relative to the upper surface of the metallic current collector piece in a non-linear path at the weld site.

8. The method of claim 7 wherein the second laser beam is advanced relative to the upper surface of the metallic current collector piece from a start point toward an end point in a forward direction and back and forth in a lateral direction transverse to the forward direction.

9. The method of claim 7 wherein the second laser beam is advanced relative to the upper surface of the metallic current collector piece from a start point toward an end point in a forward direction while gyrating the second laser beam.

10. The method of claim 1 including:
enclosing the cutting station and the joining station in a chamber; and
establishing a subatmospheric pressure environment or an inert gas environment within the chamber to prevent oxidation and combustion of the lithium metal sheet and the lithium metal piece during steps (b) and (f).

11. The method of claim 1 including:
prior to step (d), directing a fourth laser beam at an upper surface of a metallic current collector sheet; and
advancing the fourth laser beam relative to the upper surface of the metallic current collector sheet to cut off an end portion of the metallic current collector sheet and form the metallic current collector piece,
wherein the first, second, and fourth laser beams are generated by the same laser beam generator and movement of the first, second, and fourth laser beams is accomplished by a plurality of moveable mirrors housed within the same laser scanning head.

12. The method of claim 1 wherein the metallic current collector piece comprises a non-porous metallic foil, a perforated metallic sheet, or a porous metallic mesh, and wherein the metallic current collector piece comprises at least one metal or metal alloy selected from the group consisting of copper, nickel, stainless steel, and titanium.

13. The method of claim 1 wherein the solid weld joint is formed between the lithium metal piece and the metallic current collector piece without use of a flux, filler, or solder material.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Dai Fang
• Wang Hongliang
• Cai Wayne
• Cai Mei

Classifications

• H01M50/533

  characterised by the shape of the leads or tabs · CPC title

• H01M50/536

  characterised by the method of fixing the leads to the electrodes, e.g. by welding · CPC title

• H01M50/534

  characterised by the material of the leads or tabs · CPC title

• B23K26/0622 Primary

  by shaping pulses · CPC title

• B23K26/40

  taking account of the properties of the material involved · CPC title