Thermoplastic resin composition for laser direct structuring, and molded article comprising same

Patent metadata

Field	Value
Publication number	US-10899900-B2
Application number	US-201716473302-A
Country	US
Kind code	B2
Filing date	Dec 20, 2017
Priority date	Dec 26, 2016
Publication date	Jan 26, 2021
Grant date	Jan 26, 2021

Abstract

The present invention relates to a thermoplastic resin composition for laser direct structuring, containing: a polycarbonate resin; an inorganic compound comprising titanium dioxide and zinc sulfide; a fibrous inorganic filler; and an additive for laser direct structuring. Therefore, the present invention can provide: a thermoplastic resin composition for laser direct structuring, capable of implementing excellent whiteness while maintaining excellent impact resistance and rigidity; and a molded article comprising the same.

First claim

The invention claimed is:

1. A thermoplastic resin composition for laser direct structuring, comprising:
about 50 wt % to about 80 wt % of a polycarbonate resin;
about 1 wt % to about 15 wt % of an inorganic compound including titanium dioxide and zinc sulfide;
about 10 wt % to about 40 wt % of a fibrous inorganic filler; and
about 1 wt % to about 10 wt % of an additive for laser direct structuring,
wherein the titanium dioxide and the zinc sulfide are present in a weight ratio of about 1:0.1 to about 1:5.

2. The thermoplastic resin composition for laser direct structuring according to claim 1 , wherein the titanium dioxide and the zinc sulfide have a hardness difference of about 2 to about 5, as calculated by Equation 1:
Hardness difference (ΔMohs)=|(MH1−MH2)|,  [Equation 1]

where MH1 indicates Mohs's hardness of the titanium dioxide and MH2 indicates Mohs's hardness of the zinc sulfide.

3. The thermoplastic resin composition for laser direct structuring according to claim 2 , wherein, in Equation 1, MH1 ranges from about 5.5 to about 7.5 and MH2 ranges from about 2.5 to about 3.5.

4. The thermoplastic resin composition for laser direct structuring according to claim 1 , wherein the fibrous inorganic filler comprises glass fibers, carbon fibers, silica fibers, and/or ceramic fibers.

5. The thermoplastic resin composition for laser direct structuring according to claim 4 , wherein the fibrous inorganic filler comprises glass fibers having an average diameter of about 5 μm to about 20 μm in cross-section, as measured by an optical microscope, and a pre-processing average length of about 2 mm to about 5 mm.

6. The thermoplastic resin composition for laser direct structuring according to claim 1 , wherein the additive for laser direct structuring comprises a heavy metal composite oxide spinel and/or a copper salt.

7. The thermoplastic resin composition for laser direct structuring according to claim 6 , wherein the additive for laser direct structuring is the copper salt, the copper salt comprising copper hydroxide phosphate, copper phosphate, copper sulfate, cuprous thiocyanate, and/or copper chromite.

8. The thermoplastic resin composition for laser direct structuring according to claim 6 , wherein the additive for laser direct structuring is the heavy metal composite oxide spinel, the heavy metal composite oxide spinel being a compound represented by Formula 1:
AB 2 O 4 ,  [Formula 1]

where A is cadmium, chromium, manganese, nickel, zinc, copper, cobalt, iron, magnesium, tin, or titanium, and B is chromium, iron, aluminum, nickel, manganese, molybdenum, antimony, bismuth, or tin.

9. The thermoplastic resin composition for laser direct structuring according to claim 1 , wherein the polycarbonate resin and the additive for laser direct structuring are present in a weight ratio of about 3:1 to about 80:1.

10. A molded article formed of the thermoplastic resin composition for laser direct structuring according to claim 1 .

11. The molded article according to claim 10 , wherein the molded article has an Izod impact strength of about 10 kgf·cm/cm to about 20 kgf·cm/cm, as measured on a ⅛″ thick notched Izod specimen in accordance with ASTM D256.

12. The molded article according to claim 10 , wherein the molded article has a flexural modulus of about 60,000 kgf/cm 2 to about 80,000 kgf/cm 2 , as measured in accordance with ASTM D790.

13. The molded article according to claim 10 , wherein the molded article has an average weight-dropping fracture height of about 65 cm to about 90 cm, at which dropping a weight on an injection-molded specimen having a size of 2 mm×5 cm×20 cm (thickness×width×length) results in 50% breakage of the specimen in a DuPont drop test after aging at room temperature for 6 hours.

14. The molded article according to claim 10 , wherein the molded article has a luminance (L*) of about 65 to about 90, as measured in accordance with the Commission Internationale de l'Eclairage (CIE) Lab.

15. The molded article according to claim 10 , wherein the molded article has an average weight-dropping fracture height of about 65 cm to about 90 cm, at which dropping a weight on an injection-molded specimen having a size of 2 mm×5 cm×20 cm (thickness×width×length) results in 50% breakage of the specimen in a DuPont drop test after aging at room temperature for 6 hours; and a luminance (L*) of about 65 to about 90, as measured in accordance with the Commission Internationale de l'Eclairage (CIE) Lab.

16. The thermoplastic resin composition for laser direct structuring according to claim 1 , wherein a molded article formed of the thermoplastic resin composition has an average weight-dropping fracture height of about 65 cm to about 90 cm, at which dropping a weight on an injection-molded specimen having a size of 2 mm×5 cm×20 cm (thickness×width×length) results in 50% breakage of the specimen in a DuPont drop test after aging at room temperature for 6 hours; and a luminance (L*) of about 65 to about 90, as measured in accordance with the Commission Internationale de l'Eclairage (CIE) Lab.

Assignees

• Lotte Advanced Mat Co Ltd

Inventors

• Jung Yoo Jin
• Kim Ik Mo
• Kim Jung Ki
• Park Jee Kwon
• Hong Sang Hyun

Classifications

• C08K2003/2241

  Titanium dioxide · CPC title

• C08K7/04

  inorganic · CPC title

• C08K3/30

  Sulfur-, selenium- or tellurium-containing compounds · CPC title

• C08K3/22 Primary

  of metals · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title