Oil-based inkjet ink

Patent metadata

Field	Value
Publication number	US-10894897-B2
Application number	US-201815904481-A
Country	US
Kind code	B2
Filing date	Feb 26, 2018
Priority date	Feb 28, 2017
Publication date	Jan 19, 2021
Grant date	Jan 19, 2021

Abstract

An oil-based inkjet ink can be provided which prevents dye conversion of a dye lake pigment contained in the ink, prevents adhesion of the ink to the nozzle plate, and yields excellent drying properties for printed items. The oil-based inkjet ink contains a dye lake pigment, a pigment dispersant and a non-aqueous solvent, wherein the non-aqueous solvent contains a silicone oil having a surface tension of at least 20 mN/m but not more than 28 mN/m. The surface tension of the silicone oil is preferably at least 22 mN/m but not more than 26 mN/m.

First claim

What is claimed is:

1. An oil-based inkjet ink comprising a dye lake pigment, a pigment dispersant and a non-aqueous solvent, wherein the non-aqueous solvent contains a silicone oil having a surface tension of at least 22 mN/m but not more than 28 mN/m at 23° C.

2. The oil-based inkjet ink according to claim 1 , wherein the surface tension of the silicone oil is at least 22 mN/m but not more than 26 mN/m at 23° C.

3. The oil-based inkjet ink according to claim 1 , comprising the silicone oil in an amount of at least 50% by mass relative to a total mass of the non-aqueous solvent, and further comprising an alcohol-based solvent of at least 6 carbon atoms in an amount of at least 2% by mass but not more than 15% by mass relative to a total mass of the non-aqueous solvent.

4. The oil-based inkjet ink according to claim 1 , wherein the dye lake pigment is a basic dye lake pigment.

5. The oil-based inkjet ink according to claim 4 , wherein the dye lake pigment is a xanthene-based basic dye lake pigment.

6. The oil-based inkjet ink according to claim 4 , wherein the dye lake pigment is at least one pigment selected from the group consisting of C.I. Pigment Red 81, C.I. Pigment Red 81:4 and C.I. Pigment Red 169.

7. The oil-based inkjet ink according to claim 1 , wherein the silicone oil contains a modified silicone oil having 2 to 6 silicon atoms in one molecule, having an organic group in which a carbon atom is bonded directly to a silicon atom and in which a total number of carbon atoms and oxygen atoms is at least 5, and having a total number of carbon atoms and oxygen atoms, contained within all of the organic groups in which the total number of carbon atoms and oxygen atoms is at least 5, that is from 5 to 20 within one molecule.

8. The oil-based inkjet ink according to claim 7 , wherein the organic group in which a total number of carbon atoms and oxygen atoms is at least 5 that is contained in the modified silicone oil is at least one group selected from the group consisting of alkyl groups having at least 7 carbon atoms, carboxylate ester linkage-containing groups in which a total number of carbon atoms and oxygen atoms is at least 5, aromatic ring-containing groups having at least 6 carbon atoms, and alkylene groups having at least 7 carbon atoms.

9. The oil-based inkjet ink according to claim 7 , wherein the modified silicone oil is a compound represented by general formula (X) shown below:

wherein R 1 represents an oxygen atom or a divalent organic group having a carbon atom bonded directly to each silicon atom, each R 2 independently represents a monovalent organic group having a carbon atom bonded directly to a silicon atom, each of m and n independently represents an integer of 0 to 4, each p independently represents an integer of 0 to 2, a number of silicon atoms within one molecule is from 2 to 6, at least one of R 1 and R 2 is an organic group in which a total number of carbon atoms and oxygen atoms is at least 5, and a total number of carbon atoms and oxygen atoms, contained within all of the organic groups in which a total number of carbon atoms and oxygen atoms is at least 5, is from 5 to 20 within one molecule.

10. An oil-based inkjet ink comprising a dye lake pigment, a pigment dispersant and a non-aqueous solvent, wherein the non-aqueous solvent contains a silicone oil having a surface tension of at least 20 mN/m but not more than 28 mN/m at 23° C., and
the silicone oil contains a modified silicone oil having 2 to 6 silicon atoms in one molecule, having an organic group in which a carbon atom is bonded directly to a silicon atom and in which a total number of carbon atoms and oxygen atoms is at least 5, and having a total number of carbon atoms and oxygen atoms, contained within all of the organic groups in which the total number of carbon atoms and oxygen atoms is at least 5, that is from 5 to 20 within one molecule.

11. The oil-based inkjet ink according to claim 10 , wherein the organic group in which a total number of carbon atoms and oxygen atoms is at least 5 that is contained in the modified silicone oil is at least one group selected from the group consisting of alkyl groups having at least 7 carbon atoms, carboxylate ester linkage-containing groups in which a total number of carbon atoms and oxygen atoms is at least 5, aromatic ring-containing groups having at least 6 carbon atoms, and alkylene groups having at least 7 carbon atoms.

12. The oil-based inkjet ink according to claim 10 , wherein the modified silicone oil is a compound represented by general formula (X) shown below:

wherein R 1 represents an oxygen atom or a divalent organic group having a carbon atom bonded directly to each silicon atom, each R 2 independently represents a monovalent organic group having a carbon atom bonded directly to a silicon atom, each of m and n independently represents an integer of 0 to 4, each p independently represents an integer of 0 to 2, a number of silicon atoms within one molecule is from 2 to 6, at least one of R 1 and R 2 is an organic group in which a total number of carbon atoms and oxygen atoms is at least 5, and a total number of carbon atoms and oxygen atoms, contained within all of the organic groups in which a total number of carbon atoms and oxygen atoms is at least 5, is from 5 to 20 within one molecule.

Assignees

• Riso Kagaku Corp

Inventors

• Morinaga Marie
• Shimura Shinichiro
• Ando Kazuyuki
• Sugiura Hikaru

Classifications

• C09D11/102

  containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title

• C09D11/36 Primary

  based on non-aqueous solvents · CPC title

• C09D11/037

  characterised by the pigment · CPC title

• C09D11/033

  characterised by the solvent · CPC title

• C09D11/322 Primary

  Pigment inks · CPC title