Dye-labeled polymers and methods for preparing same
US-2024327655-A1 · Oct 3, 2024 · US
US9624402B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9624402-B2 |
| Application number | US-201414574816-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 18, 2014 |
| Priority date | Dec 27, 2013 |
| Publication date | Apr 18, 2017 |
| Grant date | Apr 18, 2017 |
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The method is a non-aqueous inkjet printing method including the steps of: ejecting droplets of a non-aqueous pigment ink containing at least a pigment and a non-aqueous solvent onto a surface of a printing medium to form dots composed of the non-aqueous pigment ink, and then ejecting droplets of a non-aqueous post-treatment liquid containing at least silica and an organic solvent toward the printing medium so that the droplets overlap with the dots composed of the non-aqueous pigment ink, wherein either of the non-aqueous pigment ink and the post-treatment liquid contains a water-soluble resin having an amino group.
Opening claim text (preview).
What is claimed is: 1. A non-aqueous inkjet printing method comprising: ejecting first droplets of a non-aqueous pigment ink containing at least a pigment and a non-aqueous solvent onto a surface of a printing medium to form dots composed of the non-aqueous pigment ink, and then ejecting second droplets of a non-aqueous post-treatment liquid containing at least silica and an organic solvent toward the printing medium so that the second droplets overlap with the dots composed of the non-aqueous pigment ink, wherein either of the non-aqueous pigment ink and the post-treatment liquid contains a water-soluble resin having an amino group; wherein the non-aqueous solvent consists of a petroleum-based hydrocarbon solvent. 2. The non-aqueous inkjet printing method according to claim 1 , wherein the organic solvent in the post-treatment liquid contains a glycol ether-based solvent. 3. The non-aqueous inkjet printing method according to claim 1 , wherein the dots composed of the non-aqueous pigment ink are formed on the surface of the printing medium in plural rows, and the post-treatment liquid is ejected so that the second droplets of the post-treatment liquid land on the respective dots of the non-aqueous pigment ink. 4. The non-aqueous inkjet printing method according to claim 2 , wherein the dots composed of the non-aqueous pigment ink are formed on the surface of the printing medium in plural rows, and the post-treatment liquid is ejected so that the second droplets of the post-treatment liquid land on the respective dots of the non-aqueous pigment ink. 5. The non-aqueous inkjet printing method according to claim 1 , wherein the dots composed of the non-aqueous pigment ink are formed on the surface of the printing medium in plural rows having gaps between adjacent dots, and the post-treatment liquid is ejected so that the second droplets of the post-treatment liquid land on the gaps between the adjacent dots of the non-aqueous pigment ink. 6. The non-aqueous inkjet printing method according to claim 2 , wherein the dots composed of the non-aqueous pigment ink are formed on the surface of the printing medium in plural rows having gaps between adjacent dots, and the post-treatment liquid is ejected so that the second droplets of the post-treatment liquid land on the gaps between the adjacent dots of the non-aqueous pigment ink. 7. The non-aqueous inkjet printing method according to claim 1 , wherein the non-aqueous pigment ink contains the water-soluble resin having an amino group. 8. The non-aqueous inkjet printing method according to claim 2 , wherein the non-aqueous pigment ink contains the water-soluble resin having an amino group. 9. The non-aqueous inkjet printing method according to claim 1 , wherein the post-treatment liquid contains the water-soluble resin having an amino group. 10. The non-aqueous inkjet printing method according to claim 2 , wherein the post-treatment liquid contains the water-soluble resin having an amino group. 11. The non-aqueous inkjet printing method according to claim 1 , wherein a ratio of the non-aqueous pigment ink droplets to the droplets of the post-treatment liquid is from 95:5 to 50:50 by a volume ratio. 12. The non-aqueous inkjet printing method according to claim 1 , wherein the water-soluble resin having an amino group comprises at least one selected from the group consisting of polyethyleneimine, a derivative of polyethyleneimine, polyvinylamine, a derivative of polyvinylamine, polyvinylpyridine, a derivative of polyvinylpyridine, and a dimethylamine ammonia epichlorohydrin resin. 13. The non-aqueous inkjet printing method according to claim 1 , wherein the pigment contained in the non-aqueous pigment ink comprises at least one selected from the group consisting of organic pigment, carbon black, and titanium oxide. 14. The non-aqueous inkjet printing method according to claim 1 , wherein the pigment comprises at least one selected from the group consisting of organic pigment and carbon black. 15. The non-aqueous inkjet printing method according to claim 1 , wherein the non-aqueous pigment ink further comprises a polar organic solvent.
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