Integrable redox-active polymer batteries

Patent metadata

Field	Value
Publication number	US-10892474-B2
Application number	US-201816211740-A
Country	US
Kind code	B2
Filing date	Dec 6, 2018
Priority date	Mar 11, 2013
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

The disclosed technology relates generally to apparatuses and methods of fabricating solid-state electrochemical cells having redox-active polymers. In one aspect, an electrochemical cell comprises a negative electrode including a first redox-active polymer and configured to be reversibly oxidized during a discharging operation and further configured to be reversibly reduced during a charging operation. The electrochemical cell additionally comprises a positive electrode including a second redox-active polymer and configured to be reversibly reduced during the discharging operation and further configured to be reversibly oxidized during the charging operation. The electrochemical cell further comprises an electrolyte including a solid ion-exchange polymer, the electrolyte interposed between positive and negative electrodes and configured to conduct ions therebetween. The electrochemical cell is configured to store energy for an associated device or apparatus and further configured to provide structural features of the associated device or apparatus. The electrochemical cell may constitute a part of the casing, packaging or containment of the device.

First claim

What is claimed is:

1. A device comprising at least one electrochemical cell, the at least one electrochemical cell comprising:
a negative electrode layer comprising a first redox-active polymer and configured to be reversibly oxidized during a discharging operation and further configured to be reversibly reduced during a charging operation;
a positive electrode layer comprising a second redox-active polymer and configured to be reversibly reduced during the discharging operation and further configured to be reversibly oxidized during the charging operation, wherein the second redox-active polymer includes one or both of poly(1-naphthol) and poly(10-hexylphenothiazine-3,7-diyl); and
an electrolyte layer comprising a solid ion-exchange polymer, the electrolyte layer interposed between the positive electrode layer and the negative electrode layer and configured to conduct ions therebetween,
wherein the at least one electrochemical cell is configured to store energy for an associated device and further configured to provide structural features of the associated device; and
wherein at least one of the positive electrode layer or the negative electrode layer comprises a protective compound adapted to protect at least one of the first redox-active polymer or the second redox-active polymer from over-charging or over-discharging, and the protective compound is selected from the group consisting of a phenothiazine, iodine, tri-iodine, benzoquinone, naphthoquinone, and anthraquinone, their derivatives and combinations thereof.

2. The device of claim 1 , wherein a thickness of each of the positive electrode layer and the negative electrode layer is less than 200 μm.

3. The device of claim 1 , wherein a thickness of the electrolyte layer is less than 100 μm.

4. The device of claim 1 , wherein a total thickness of the at least one electrochemical cell is less than 500 μm.

5. The device of claim 1 , wherein the solid ion-exchange polymer comprises at least one of polyethylene oxide (PEO), poly(siloxanes-g-oligo(ethylene oxide)), poly(trimethylene carbonate), poly(oxymethylene), poly(propylene oxide), poly(oxymethylene-oligo-oxyethylene), or poly(dimethyl siloxane).

6. The device of claim 1 , wherein at least one of the first redox-active polymer or the second redox-active polymer includes a quinoid structure.

7. The device of claim 1 , wherein the first redox-active polymer is selected from the group consisting of polyaniline, poly(aminoanthraquinone), polyvinylanthraquinone, poly(1-aminoanthraquinone), poly(3,7-dialkylbenzo [1,2-b:4,5-b′]dithiophene-4,8-dione-2,6-diyl), or combinations thereof.

8. The device of claim 1 , wherein at least one of the positive electrode layer or the negative electrode layer comprises a polymer blend.

9. The device of claim 1 , wherein at least one of the positive electrode layer or the negative electrode layer further comprises a structural material in the form of at least one of fibers, a woven material, whiskers, particles, or a porous matrix such that the at least one electrochemical cell is configured to provide mechanical stability to the device.

10. The device of claim 9 , wherein the structural material comprises at least one of carbon, metal, or glass.

11. A device comprising at least one electrochemical cell, the at least one electrochemical cell comprising:
a negative electrode layer comprising a first redox-active polymer and configured to be reversibly oxidized during a discharging operation and further configured to be reversibly reduced during a charging operation, wherein the first redox-active polymer is selected from the group consisting of polyaniline, poly(aminoanthraquinone), polyvinylanthraquinone, poly(1-aminoanthraquinone), poly(3,7-dialkylbenzo [1,2-b:4,5-b′]dithiophene-4,8-dione-2,6-diyl), and combinations thereof;
a positive electrode layer comprising a second redox-active polymer and configured to be reversibly reduced during the discharging operation and further configured to be reversibly oxidized during the charging operation, wherein the second redox-active polymer includes one or both of poly(1-naphthol) and poly(10hexylphenothiazine-3,7-diyl); and
an electrolyte layer comprising a solid ion-exchange polymer, the electrolyte layer interposed between the positive electrode layer and the negative electrode layer and configured to conduct ions therebetween,
wherein the at least one electrochemical cell comprises at least a portion of one of a packaging, casing or containment of the device; and
wherein at least one of the positive electrode layer or the negative electrode layer comprises a protective compound adapted to protect at least one of the first redox-active polymer or the second redox-active polymer from over-charging or over-discharging, and the protective compound is selected from the group consisting of a phenothiazine, iodine, tri-iodine, benzoquinone, naphthoquinone, and anthraquinone, their derivatives and combinations thereof.

12. The device of claim 11 , wherein the device comprises an electric vehicle comprising a structural exterior body panel, wherein at least a portion of the structural exterior body panel comprises the at least one electrochemical cell integrated therein.

13. The device of claim 11 , wherein the device comprises a portable computing device comprising a structural exterior casing, wherein at least a portion of the structural exterior casing comprises the at least one electrochemical cell integrated therein.

14. The device of claim 11 , wherein a thickness of each of the positive electrode layer and the negative electrode layer is less than 200 μm.

15. The device of claim 11 , wherein a thickness of the electrolyte layer is less than 100 μm.

16. The device of claim 11 , wherein a total thickness of the at least one electrochemical cell is less than 500 μm.

17. The device of claim 11 , wherein the solid ion-exchange polymer comprises at least one of polyethylene oxide (PEO), poly(siloxanes-g-oligo(ethylene oxide)), poly(trimethylene carbonate), poly(oxymethylene), poly(propylene oxide), poly(oxymethylene-oligo-oxyethylene), or poly(dimethyl siloxane).

Assignees

• Fluidic Inc
• Form Energy Inc

Inventors

• Friesen Cody A
• Bautista-Martinez Jose Antonio

Classifications

• H01M4/608

  containing heterocyclic rings · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/606

  containing aromatic main chain polymers · CPC title

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• H01M10/05

  Accumulators with non-aqueous electrolyte (H01M10/39 takes precedence) · CPC title