Selective etch of silicon nitride
US-8956980-B1 · Feb 17, 2015 · US
US10892198B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10892198-B2 |
| Application number | US-201816131942-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 14, 2018 |
| Priority date | Sep 14, 2018 |
| Publication date | Jan 12, 2021 |
| Grant date | Jan 12, 2021 |
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Exemplary etching methods may include flowing a hydrogen-containing precursor into a semiconductor processing chamber. The methods may include flowing a fluorine-containing precursor into a remote plasma region of the semiconductor processing chamber. The methods may include forming a plasma of the fluorine-containing precursor in the remote plasma region. The methods may include etching a pre-determined amount of a silicon-containing material from a substrate in a processing region of the semiconductor processing chamber. The methods may include measuring a radical density within the remote plasma region during the etching. The methods may also include halting the flow of the hydrogen-containing precursor into the semiconductor processing chamber when the radical density measured over time correlates to a produced amount of etchant to remove the pre-determined amount of the silicon-containing material.
Opening claim text (preview).
The invention claimed is: 1. An etching method comprising: flowing a hydrogen-containing precursor into a semiconductor processing chamber; flowing a fluorine-containing precursor into a remote plasma region of the semiconductor processing chamber; forming a plasma of the fluorine-containing precursor in the remote plasma region; etching a pre-determined amount of a silicon-containing material from a substrate in a processing region of the semiconductor processing chamber; measuring a radical density within the remote plasma region during the etching; and halting the flow of the hydrogen-containing precursor into the semiconductor processing chamber when the radical density measured over time correlates to a produced amount of etchant to remove the pre-determined amount of the silicon-containing material. 2. The etching method of claim 1 , wherein the measuring is of an atomic trace of hydrogen within the remote plasma region of the semiconductor processing chamber. 3. The etching method of claim 2 , wherein the hydrogen-containing precursor comprises hydrogen, ammonia, or water. 4. The etching method of claim 2 , wherein the measuring is performed with an optical emission spectrometer positioned within a dielectric component at least partially defining the remote plasma region of the semiconductor processing chamber. 5. The etching method of claim 4 , wherein the measuring comprises measuring a peak intensity of radical hydrogen within the remote plasma region of the semiconductor processing chamber. 6. The etching method of claim 2 , further comprising, prior to halting the flow of the hydrogen-containing precursor, identifying an increase in the atomic trace within the remote plasma region. 7. The etching method of claim 6 , wherein the increase correlates to complete removal of the silicon-containing material. 8. The etching method of claim 1 , wherein the remote plasma region is a region defined within the semiconductor processing chamber and separated from the processing region by one or more chamber components. 9. The etching method of claim 1 , further comprising flowing an inert precursor into the remote plasma region and forming a plasma of the inert precursor within the remote plasma region. 10. The etching method claim 9 , wherein a stable plasma of the inert precursor is produced prior to flowing the fluorine-containing precursor into the remote plasma region. 11. The etching method of claim 1 , wherein the hydrogen-containing precursor is flowed to bypass the remote plasma region during the etching method. 12. An etching method comprising: flowing a hydrogen-containing precursor into a semiconductor processing chamber; flowing a fluorine-containing precursor into a remote plasma region of the semiconductor processing chamber; forming a plasma of the fluorine-containing precursor in the remote plasma region; etching in a first etch process a pre-determined amount of a silicon-containing material from a substrate in a processing region of the semiconductor processing chamber; measuring a radical density within the remote plasma region during the etching; halting the flow of the hydrogen-containing precursor into the semiconductor processing chamber when the radical density measured over time correlates to a produced amount of etchant to remove the pre-determined amount of the silicon-containing material; removing the substrate from the semiconductor processing chamber; forming a plasma of a fluorine-containing precursor in the semiconductor processing chamber; measuring a radical density of the hydrogen-containing precursor; extinguishing the plasma of the fluorine-containing precursor when the radical density of the hydrogen-containing precursor reaches a pre-determined threshold; and performing a second etch process. 13. The etching method of claim 12 , wherein the first etch process and the second etch process are different etch processes. 14. The etching method of claim 12 , wherein the first etch process comprises a first etch for a dual damascene etch process, and wherein the second etch process comprises a second etch for a dual damascene etch process.
of Group IV materials · CPC title
comprising acting in response to an ongoing measurement without interruption of processing, e.g. endpoint detection or in-situ thickness measurement · CPC title
for dual-damascene structures · CPC title
by chemical means · CPC title
Gas control, e.g. control of the gas flow · CPC title
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