Desalination of polyaryl ethers by means of melt extraction

Patent metadata

Field	Value
Publication number	US-10889689-B2
Application number	US-201716086671-A
Country	US
Kind code	B2
Filing date	Mar 14, 2017
Priority date	Mar 21, 2016
Publication date	Jan 12, 2021
Grant date	Jan 12, 2021

Abstract

The present invention relates to a process for preparing a polyaryl ether by reacting components (a1) and (a2) in the presence of a carbonate compound (C) to obtain a salt-containing polymer (SP) comprising the polyaryl ether and a salt (S). After the reaction, the salt (S) is extracted from the salt-containing polymer (SP) to obtain a desalinated polymer (DP) comprising the polyaryl ether.

First claim

The invention claimed is:

1. A process for preparing a polyaryl ether having a softening temperature T S , comprising the steps of
I) reacting the components
(a1) at least one aromatic dihydroxyl compound and
(a2) at least one aromatic sulfone compound having, two halogen substituents
in the presence of a carbonate compound (C) at a first temperature T 1-I above the softening temperature T S of the polyaryl ether in a mixing kneader to obtain a salt-containing polymer (SP) comprising the polyaryl ether and a salt (S),

II) transferring the salt-containing polymer (SP) obtained in step I) from the mixing kneader into a reactor comprising a dynamic mixer, where the salt-containing polymer (SP) has a second temperature T 2-II above the softening temperature TS of the polyaryl ether, and where the reactor comprises an extractant (E) having a third temperature T 3-II above the softening Temperature T S of the polyaryl ether,
III) extracting the salt (S) from the salt-containing polymer (SP) with the extractant (E) in the reactor comprising a dynamic mixer at a fourth temperature T 4-III above the softening temperature T S of the polyaryl ether to obtain a desalinated polymer (DP) comprising the polyaryl ether and a salt-containing extractant (SE) comprising the extractant (E) and the salt (S).

2. The process according to claim 1 , wherein the fourth temperature T 4-III in step III) is in the range from 160 to 300° C.

3. The process according to claim 1 , wherein the third temperature T 3-II of the extractant (E) in step II) is in the range from 160 to 300° C.

4. The process according to claim 1 , wherein the second temperature T 2-II of the salt-containing polymer (SP) in step II) is in the range from 200 to 400° C.

5. The process according to claim 1 , wherein the first temperature T 1-I in step I) is in the range from 200 to 400° C.

6. The process according to claim 1 , wherein the softening temperature T S of the polyaryl ether is in the range from 150 to 230° C.

7. The process according to claim 1 , wherein the extractant (E) comprises water.

8. The process according to claim 1 , wherein the desalinated polymer (DP) obtained in step III) comprises not more than 150 ppm by weight of the salt (S), based on the total weight of the desalinated polymer (DP).

9. The process according to claim 1 , wherein the polyaryl ether is amorphous.

10. The process according to claim 1 , wherein component (a1) is selected from the group consisting of 4,4′-dihydroxybiphenyl, 2,2-bis(4-hydroxyphenyl)propane and bis(4-hydroxyphenyl) sulfone.

11. The process according to claim 1 , wherein component (a2) is selected from the group consisting of 4,4′-dichlorodiphenyl sulfone, 4,4′-difluorodiphenyl sulfone, 4,4′-dibromodiphenyl sulfone, 2,2′-dichlorodiphenyl sulfone and 2,2′-difluorodiphenyl sulfone.

12. The process according to claim 1 , wherein the polyaryl ether is a polyaryl ether sulfone.

13. The process according to claim 1 , wherein the salt (S) comprises potassium chloride and/or sodium chloride.

14. A desalinated polymer (DP) obtained by the method according to claim 1 , wherein the desalinated polymer (DP) comprises 0 to 100 ppm by weight of an aprotic polar solvent selected from the group consisting of N,N-dimethylformamide, N,N-dimethylacetamide, N-methylpyrrolidone, N-ethylpyrrolidone, dimethyl sulfoxide, di methyl sulfone, sulfolane, diphenyl sulfone and mixtures thereof, and less than 150 ppm by weight of the salt (S), where the ppm by weight are each based on the total weight of the desalinated polymer (DP).

15. The desalinated polymer (DP) according to claim 14 , wherein the polyaryl ether is polysulfone (PSU), polyphenylene sulfone (PPSU) or polyether sulfone (PESU).

16. A fiber, film, coating or molding comprising or produced using the desalinated polymer (DP) according to claim 14 .

Assignees

• Basf Se

Inventors

• Gramlich Simon
• Stammer Achim
• Ulzhoefer Angela
• Niedermaier Frank
• Gassmann Michel

Classifications

• C08G65/46 Primary

  Post-polymerisation treatment, e.g. recovery, purification, drying · CPC title

• C08G75/20

  Polysulfones · CPC title

• C08G75/00

  Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule · CPC title

• C08G75/02

  Polythioethers · CPC title

• C08G65/40

  from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group · CPC title