Cathode and lithium battery including cathode

Patent metadata

Field	Value
Publication number	US-10879536-B2
Application number	US-201816166778-A
Country	US
Kind code	B2
Filing date	Oct 22, 2018
Priority date	Feb 22, 2018
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

A includes a cathode active material including a lithium transition metal oxide, wherein the lithium transition metal oxide includes nickel and a non-nickel transition metal, and an amount of the nickel in the lithium transition metal oxide is about 50 mole percent or greater with respect to a total number of moles of transition metals in the lithium transition metal oxide, a conducting agent including a linear carbonaceous conducting agent, and a binder, wherein the binder includes a first fluorinated binder not including a polar functional group, a second fluorinated binder including a polar functional group, a first non-fluorinated binder including a cyano group, and a second non-fluorinated binder including a cyanoalkyl group.

First claim

What is claimed is:

1. A cathode comprising:
a cathode active material comprising a lithium transition metal oxide, wherein the lithium transition metal oxide comprises nickel and a non-nickel transition metal, wherein a content of the nickel in the lithium transition metal oxide is about 50 mole percent or greater with respect to a total number of moles of transition metals in the lithium transition metal oxide;
a conducting agent comprising a linear carbonaceous conducting agent; and
a binder composition comprising
a first fluorinated binder not containing a polar functional group,
a second fluorinated binder comprising a polar functional group,
a first non-fluorinated binder comprising a cyano group, and
a second non-fluorinated binder comprising a cyanoalkyl group.

2. The cathode of claim 1 , wherein an amount of the second non-fluorinated binder is about 2 weight percent or less, based on a total weight of the cathode active material, the conducting agent, and the binder.

3. The cathode of claim 1 , wherein the second non-fluorinated binder comprises a non-fluorinated polymer comprising a cyanoalkyl group depending from a backbone of the non-fluorinated polymer.

4. The cathode of claim 1 , wherein the second non-fluorinated binder comprises a polymer comprising a group of the formula —OH and a group of the formula —O—RCN wherein R is an alkyl group.

5. The cathode of claim 1 , wherein the second non-fluorinated binder comprises a cyanoalkyl polyvinyl alcohol, a cyanoalkyl pullulan, a cyanoalkyl cellulose, a cyanoalkyl hydroxymethyl cellulose, a cyanoalkyl hydroxyethyl cellulose, a cyanoalkyl hydroxypropyl cellulose, a cyanoalkyl starch, a cyanoalkyl dextrin, a cyanoalkyl collagen, a cyanoalkyl carboxymethyl cellulose, or a combination thereof, and
the cyanoalkyl group comprises a C1-C10 alkyl group.

6. The cathode of claim 1 , wherein the second non-fluorinated binder comprises cyanoethyl polyvinyl alcohol, a cyanoethyl pullulan, a cyanoethyl cellulose, a cyanoethyl hydroxyethyl cellulose, a cyanoethyl hydroxymethyl cellulose, a cyanoethyl hydroxypropyl cellulose, a cyanoethyl starch, a cyanoethyl dextrin, a cyanoethyl collagen, a cyanoethyl carboxymethyl cellulose, or a combination thereof.

7. The cathode of claim 1 , wherein the second non-fluorinated binder is a cyanoethyl polyvinyl alcohol represented by Formula 1:

wherein, in Formula 1, n and m each denote a molar fraction of a repeating unit, 0≤n<1, 0<m<1, n+m=1, and x=2.

8. The cathode of claim 1 , wherein the first fluorinated binder is a vinylidene fluoride binder and has a weight average molecular weight of about 1,000,000 Daltons or less.

9. The cathode of claim 1 , wherein the second fluorinated binder comprises:
a repeating unit derived from a polar functional group-containing monomer;
a repeating unit derived from vinylidene fluoride; and
optionally, a repeating unit derived from a fluorine-containing monomer comprising tetrafluoroethylene, hexafluoropropylene, chlorotrifluoroethylene, fluorovinyl, perfluoroalkyl vinyl ether, or a combination thereof.

10. The cathode of claim 9 , wherein the second fluorinated binder has a weight average molecular weight of about 1,000,000 Daltons or greater.

11. The cathode of claim 1 , wherein the polar functional group of the second fluorinated binder comprises a carboxylic acid group, a sulfonic acid group, a phosphoric acid group, an amino group, a hydroxyl group, a salt thereof, or a combination thereof.

12. The cathode of claim 1 , wherein a weight ratio of the first fluorinated binder to the second fluorinated binder is about 90:10 to about 10:90.

13. The cathode of claim 1 , wherein the first non-fluorinated binder comprises a repeating unit derived from an acrylonitrile monomer and a repeating unit derived from an olefin monomer.

14. The cathode of claim 1 , wherein the linear carbonaceous conducting agent comprises a carbon nanotube, a carbon nanofiber, a carbon nanorod, or a combination thereof.

15. The cathode of claim 1 , wherein the linear carbonaceous conducting agent has an aspect ratio of about 2 or greater.

16. The cathode of claim 1 , wherein the conducting agent further comprises a particulate carbonaceous conducting agent, and
the particulate carbonaceous conducting agent has an aspect ratio of less than 2.

17. The cathode of claim 15 , wherein the particulate carbonaceous conducting agent comprises carbon black, acetylene black, Ketjen black, channel black, furnace black, lamp black, summer black, natural graphite, artificial graphite, or a combination thereof.

18. The cathode of claim 15 , wherein a weight ratio of the linear carbonaceous conducting agent to the particulate carbonaceous conducting agent is about 90:10 to about 10:90.

19. The cathode of claim 1 , wherein the lithium transition metal oxide is a compound represented by Formula 2:
Li a Ni x Co y M z O 2-b A b   Formula 2

wherein, in Formula 2, 1.0≤a≤1.2, 0≤b≤0.2, 0.7≤x<0.99, 0<y≤0.3, 0<z≤0.3, x+y+z=1,
M is Mn, V, Mg, Ga, Si, W, Mo, Fe, Cr, Cu, Zn, Ti, Al, B, or a combination thereof, and
A is F), S, Cl, Br, or a combination thereof.

20. The cathode of claim 1 , wherein the lithium transition metal oxide is a compound represented by Formula 3, Formula 4, or a combination thereof:
LiNi x Co y Mn z O 2 ,  Formula 3

or
LiNi x Co y Al z O 2 ,  Formula 4

wherein, in Formula 3 and Formula 4, 0.8≤x≤0.99, 0<y≤0.2, and 0<z≤0.1.

21. The cathode of claim 1 , wherein a loading level of the cathode is about 4.0 milliampere hours per square centimeter or greater.

22. The cathode of claim 1 , wherein the cathode does not break when bent about 90 degrees or greater, as measured by a flexural property test in accordance with ASTM D790.

23. A lithium battery comprising:
the cathode of claim 1 ;
an anode; and
an electrolyte between the cathode and the anode.

Assignees

• Samsung Electronics Co Ltd
• Samsung Sdi Co Ltd

Inventors

• Kim Youngsoo
• Yu Byongyong
• Moon San
• Ryu Younggyoon
• Park Jinhwan
• Yoon Jaegu
• Choi Byungjin

Classifications

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/623 Primary

  fluorinated polymers · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title