Method of preparing pregelatinized, partially hydrolyzed starch and related methods and products

Patent metadata

Field	Value
Publication number	US-10875935-B2
Application number	US-201715787264-A
Country	US
Kind code	B2
Filing date	Oct 18, 2017
Priority date	Oct 23, 2012
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

Disclosed are methods relating to an extruded pregelatinized, partially hydrolyzed starch prepared by mixing at least water, non-pregelatinized starch, and acid to form a starch precursor. The acid can be a weak acid that substantially avoids chelating calcium ions or a strong acid in a small amount. In the method, pregelatinization and acid-modification of the starch precursor occurs in one step in an extruder. Also disclosed are methods of preparing board using the starch prepared according to the methods, as well as starches and boards prepared by various methods of the invention.

First claim

The invention claimed is:

1. A method of making a pregelatinized, partially hydrolyzed starch comprising:
(a) mixing at least water, non-pregelatinized unmodified starch, and a strong acid having a pKa of about −1.7 or less to make a wet starch precursor having a moisture content of from about 8 wt. % to about 25 wt. %, wherein the strong acid is in an amount of about 0.02 wt. % or less by weight of the non-pregelatinized unmodified starch;
(b) feeding the wet starch precursor including the mixed strong acid into an extruder having a heated die, rotating screws for imparting a compressive shearing force, and a rotating knife;
(c) pregelatinizing and acid-modifying the wet starch precursor in the extruder at a die temperature of about 150° C. to about 210° C. to form a pregelatinized partially hydrolyzed starch; and
(d) cutting the pregelatinized, partially hydrolyzed starch formed in the extruder die with the rotating knife,
wherein the pregelatinized, partially hydrolyzed starch is at least about 70% gelatinized, and wherein the pregelatinized, partially hydrolyzed starch has a cold water viscosity of from about 10 Brabender Unit (BU) to about 120 BU, wherein the cold water viscosity is determined by an Amylograph method for a 10% by weight solution of the starch at 25° C.

2. The method of claim 1 , wherein the strong acid is sulfuric acid, nitric acid, hydrochloric acid, or any combination thereof.

3. The method of claim 1 , wherein the strong acid is sulfuric acid.

4. The method of claim 1 , wherein the strong acid is in an amount of from about 0.0001 wt. % to about 0.02 wt. % the non-pregelatinized unmodified starch.

5. The method of claim 4 , wherein the strong acid is in an amount of from about 0.0001 wt. % to about 0.01 wt. % the non-pregelatinized unmodified starch.

6. The method of claim 1 , wherein the pregelatinized, partially hydrolyzed starch has a hot water viscosity of from about 5 Brabender Unit (BU) to about 33 BU for a 10% by weight solution of the starch at 30 min and 93° C. determined by the Amylograph method.

7. The method of claim 1 , wherein the pregelatinizing and acid-modifying occurs at a die temperature of from at least about 175° C. to about 205° C. in the extruder.

8. The method of claim 1 , wherein an output of the pregelatinized, partially hydrolyzed starch is at least about 100 kg/hr in the extruder.

9. The method of claim 1 , wherein the pregelatinizing and acid-modifying occurs in less than about 5 minutes.

10. The method of claim 1 , wherein the pregelatinizing and acid-modifying occurs in less than about 1 minute.

11. The method of claim 1 , wherein the method is free of purification and neutralization steps for the pregelatinized, acid-modified starch.

12. A pregelatinized, partially hydrolyzed starch prepared according to claim 1 .

13. A method of making board comprising:
(a) mixing at least water, non-pregelatinized unmodified starch, and a strong acid having a pKa of about −1.7 or less to make a wet starch precursor having a moisture content of from about 8 wt. % to about 25 wt. %, wherein the strong acid is in an amount of about 0.02 or less by weight of the starch;
(b) feeding the wet starch precursor including the strong acid into an extruder having a heated die, rotating screws for imparting a compressive shearing force, and a rotating knife; and (iii) pregelatinizing and acid-modifying the wet starch precursor in the extruder having the die at a temperature of about 150° C. to about 210° C. to form a pregelatinized, partially hydrolyzed starch, cutting the pregelatinized, partially hydrolyzed starch formed in the extruder die using the rotating knife, wherein the pregelatinized, partially hydrolyzed starch is at least about 70% gelatinized and wherein the pregelatinized, partially hydrolyzed starch has a cold water viscosity of from about 10 Brabender Unit (BU) to about 120 BU, wherein the cold water viscosity is determined by an Amylograph method for a 10% by weight solution of the starch at 25° C.;
(c) mixing the pregelatinized and partially hydrolyzed starch with at least water and stucco to form a slurry;
(d) disposing the slurry between a first cover sheet and a second cover sheet to form a wet assembly;
(e) cutting the wet assembly into a board: and
(f) drying the board.

14. The method of claim 13 , wherein the strong acid is sulfuric acid, nitric acid, hydrochloric acid, or any combination thereof.

15. The method of claim 14 , wherein the strong acid is sulfuric acid.

16. The method of claim 13 , wherein the strong acid is in an amount of from about 0.0001 wt. % to about 0.02 wt. % of the non-pregelatinized starch.

17. The method of claim 16 , wherein the strong acid is in an amount of from about 0.0001 wt. % to about 0.01 wt. % of the non-pregelatinized starch.

18. The method of claim 13 , wherein the pregelatinized, partially hydrolyzed starch has a hot water viscosity of from about 5 Brabender Unit(BU) to about 33 BU for a 10% by weight solution of the starch at 30 min and 93° C. determined by the Amylograph method.

19. The method of claim 13 , wherein the board has a density of from about 21 pcf to about 35 pcf.

20. The method of claim 4 , wherein the slurry further comprises sodium trimetaphosphate.

21. A board prepared according to claim 13 .

Assignees

• United States Gypsum Co

Inventors

• Sang Yijun
• Song Weixin D
• Chan Cesar
• Lee Chris C

Classifications

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• Y10T428/31971

  Of carbohydrate · CPC title

• C04B2111/00672

  Pointing or jointing materials · CPC title

• C08B30/14 Primary

  Cold water dispersible or pregelatinised starch · CPC title

• E04C2/26

  composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups {(of cement and mineral fibres E04C2/04)} · CPC title