Electrolytic capacitor

Patent metadata

Field	Value
Publication number	US-10865494-B2
Application number	US-201916725752-A
Country	US
Kind code	B2
Filing date	Dec 23, 2019
Priority date	Oct 31, 2016
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

An electrolytic capacitor includes an anode body having a dielectric layer; a solid electrolyte layer in contact with the dielectric layer of the anode body; and an electrolyte solution. The solid electrolyte layer includes a π-conjugated conductive polymer. The electrolyte solution contains a solvent and a solute, and the solvent contains a glycol compound and a sulfone compound. A proportion of the glycol compound contained in the solvent is 10% by mass or more. A proportion of the sulfone compound contained in the solvent is 30% by mass or more. A total proportion of the glycol compound and the sulfone compound contained in the solvent is 70% by mass or more.

First claim

What is claimed is:

1. An electrolytic capacitor comprising:
a capacitor element including an anode body having a dielectric layer and a solid electrolyte layer in contact with the dielectric layer of the anode body;
a case that houses the capacitor element;
an electrolyte solution that is contained in the case; and
a sealing member that seals an opening of the case, wherein:
the solid electrolyte layer includes a π-conjugated conductive polymer,
the electrolyte solution contains a solvent and a solute,
the solvent contains a glycol compound other than a polyalkylene glycol having a weight average molecular weight of 300 or more, a sulfone compound, and a lactone compound,
a proportion of the glycol compound contained in the solvent is 10% by mass or more,
a proportion of the sulfone compound contained in the solvent is greater than 30% by mass,
a total proportion of the glycol compound and the sulfone compound contained in the solvent is 70% by mass or more,
a proportion of the lactone compound contained in the solvent is more than 0% by mass and less than or equal to 30% by mass, and
the sealing member includes a butyl rubber.

2. The electrolytic capacitor according to claim 1 , wherein:
the solvent further contains the polyalkylene glycol having a weight average molecular weight of 300 or more.

3. The electrolytic capacitor according to claim 2 , wherein a proportion of the polyalkylene glycol contained in the solvent ranges from 5% by mass to 30% by mass, inclusive.

4. The electrolytic capacitor according to claim 1 , wherein the proportion of the sulfone compound contained in the solvent is more than the proportion of the glycol compound contained in the solvent.

5. The electrolytic capacitor according to claim 1 , wherein the proportion of the sulfone compound contained in the solvent is greater than 40% by mass.

6. The electrolytic capacitor according to claim 1 , wherein the proportion of the sulfone compound contained in the solvent is 50% by mass or more and 90% by mass or less.

7. The electrolytic capacitor according to claim 1 , wherein the sulfone compound includes sulfolane.

8. The electrolytic capacitor according to claim 1 , wherein the lactone compound includes γ-butyrolactone.

9. The electrolytic capacitor according to claim 1 , wherein the proportion of the glycol compound contained in the solvent ranges from 10% by mass to 70% by mass, inclusive.

10. The electrolytic capacitor according to claim 1 , wherein the glycol compound includes at least one selected from the group consisting of ethylene glycol, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, and hexaethylene glycol.

11. The electrolytic capacitor according to claim 1 , wherein the glycol compound includes ethylene glycol.

12. The electrolytic capacitor according to claim 1 , wherein:
the solute includes an acid component and a base component, and
a proportion of the solute contained in the electrolyte solution ranges from 10% by mass to 40% by mass, inclusive.

13. The electrolytic capacitor according to claim 12 , wherein:
the acid component includes an organic carboxylic acid compound, and
the base component includes at least one selected from the group consisting of an amine compound, a quaternary amidinium compound, and a quaternary ammonium compound.

14. The electrolytic capacitor according to of claim 13 , wherein the amine compound includes at least one selected from the group consisting of a primary amine compound, a secondary amine compound, and a tertiary amine compound.

15. The electrolytic capacitor according to of claim 13 , wherein the quaternary amidinium compound includes at least one selected from the group consisting of a quaternary imidazolinium compound and a quaternary imidazolium compound.

16. The electrolytic capacitor according to of claim 1 , wherein the electrolyte solution further contains a boric acid ester compound.

17. The electrolytic capacitor according to of claim 1 , wherein the proportion of the lactone compound contained in the solvent is 10% by mass or more.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Tsubaki Yuichiro
• Aoyama Tatsuji
• Saito Kazuyo

Classifications

• H01G9/055

  Etched foil electrodes · CPC title

• C25D11/16

  Pretreatment {, e.g. desmutting} · CPC title

• H01G9/145

  Liquid electrolytic capacitors (H01G11/00 takes precedence) · CPC title

• H01G9/151

  with wound foil electrodes · CPC title

• H01G9/028

  Organic semiconducting electrolytes, e.g. TCNQ · CPC title