Electrolytic capacitor

Patent metadata

Field	Value
Publication number	US-10563318-B2
Application number	US-201715724303-A
Country	US
Kind code	B2
Filing date	Oct 4, 2017
Priority date	Oct 31, 2016
Publication date	Feb 18, 2020
Grant date	Feb 18, 2020

Abstract

An electrolytic capacitor includes an anode body having a dielectric layer; a solid electrolyte layer in contact with the dielectric layer of the anode body; and an electrolyte solution. The solid electrolyte layer includes a π-conjugated conductive polymer. The electrolyte solution contains a solvent and a solute, and the solvent contains a glycol compound and a sulfone compound. A proportion of the glycol compound contained in the solvent is 10% by mass or more. A proportion of the sulfone compound contained in the solvent is 30% by mass or more. A total proportion of the glycol compound and the sulfone compound contained in the solvent is 70% by mass or more.

First claim

What is claimed is:

1. An electrolytic capacitor comprising:
an anode body having a dielectric layer;
a solid electrolyte layer in contact with the dielectric layer of the anode body; and
an electrolyte solution, wherein:
the solid electrolyte layer includes a π-conjugated conductive polymer,
the electrolyte solution contains a solvent and a solute,
the solvent contains a glycol compound, a sulfone compound, and a lactone compound,
a proportion of the glycol compound contained in the solvent is 10% by mass or more,
a proportion of the sulfone compound contained in the solvent is greater than 40% by mass,
a total proportion of the glycol compound and the sulfone compound contained in the solvent is 70% by mass or more, and
a proportion of the lactone compound contained in the solvent is more than 0% by mass and less than 10% by mass.

2. The electrolytic capacitor according to claim 1 , wherein the proportion of the glycol compound contained in the solvent ranges from 10% by mass to 70% by mass, inclusive.

3. The electrolytic capacitor according to claim 1 , wherein the proportion of the sulfone compound contained in the solvent is 50% by mass or more and 90% by mass or less.

4. The electrolytic capacitor according to claim 1 , wherein the glycol compound includes ethylene glycol.

5. The electrolytic capacitor according to claim 1 , wherein the sulfone compound includes sulfolane.

6. The electrolytic capacitor according to claim 1 , wherein:
the solute includes, as an acid component, an organic carboxylic acid compound, and includes, as a base component, an amine compound, a quaternary amidinium compound, or a quaternary ammonium compound, and
a proportion of the solute contained in the electrolyte solution ranges from 5% by mass to 40% by mass, inclusive.

7. The electrolytic capacitor according to of claim 1 , wherein the amine compound includes at least one selected from the group consisting of a primary amine compound, a secondary amine compound, and a tertiary amine compound.

8. The electrolytic capacitor according to of claim 1 , wherein the quaternary amidinium compound includes at least one selected from the group consisting of a quaternary imidazolinium compound and a quaternary imidazolium compound.

9. The electrolytic capacitor according to of claim 1 , wherein the electrolyte solution further contains a boric acid ester compound.

10. The electrolytic capacitor according to claim 1 , wherein:
the solute includes an acid component and a base component, and
a proportion of the solute contained in the electrolyte solution ranges from 10% by mass to 40% by mass, inclusive.

11. The electrolytic capacitor according to claim 1 , wherein:
the solute includes, as an acid component, an organic carboxylic acid compound, and includes, as a base component, an amine compound, a quaternary amidinium compound, or a quaternary ammonium compound, and
a proportion of the solute contained in the electrolyte solution ranges from 10% by mass to 40% by mass, inclusive.

12. The electrolytic capacitor according to claim 1 , wherein
the proportion of the sulfone compound contained in the solvent is more than the proportion of the glycol compound contained in the solvent.

13. The electrolytic capacitor according to claim 1 , wherein the solvent further contains a polyalkylene glycol having a weight average molecular weight ranging from 300 to 1000, inclusive.

14. The electrolytic capacitor according to claim 13 , wherein a proportion of the polyalkylene glycol contained in the solvent ranges from 5% by mass to 30% by mass, inclusive.

15. An electrolytic capacitor comprising:
an anode body having a dielectric layer;
a solid electrolyte layer in contact with the dielectric layer of the anode body; and
an electrolyte solution, wherein:
the solid electrolyte layer includes a π-conjugated conductive polymer,
the electrolyte solution contains a solvent and a solute,
the solvent contains a glycol compound, a sulfone compound, and a lactone compound,
a proportion of the glycol compound contained in the solvent is 10% by mass or more,
a proportion of the sulfone compound contained in the solvent is 30% by mass or more, and
a total proportion of the glycol compound and the sulfone compound contained in the solvent is 70% by mass or more,
a proportion of the lactone compound contained in the solvent is more than 0% by mass and less than 10% by mass,
the solute includes an acid component and a base component, and
a proportion of the solute contained in the electrolyte solution ranges from 10% by mass to 40% by mass, inclusive.

16. The electrolytic capacitor according to claim 15 , wherein:
the acid component includes an organic carboxylic acid compound, and
the base component includes at least one selected from an amine compound, a quaternary amidinium compound, and a quaternary ammonium compound.

17. The electrolytic capacitor according to claim 15 , wherein:
the proportion of the sulfone compound contained in the solvent is greater than 40% by mass.

18. The electrolytic capacitor according to claim 15 , wherein the glycol compound includes ethylene glycol.

19. The electrolytic capacitor according to claim 15 , wherein the sulfone compound includes sulfolane.

20. An electrolytic capacitor comprising:
an anode body having a dielectric layer;
a solid electrolyte layer in contact with the dielectric layer of the anode body; and
an electrolyte solution, wherein:
the solid electrolyte layer includes a m-conjugated conductive polymer,
the electrolyte solution contains a solvent and a solute,
the solvent contains a glycol compound, a sulfone compound, and a lactone compound,
a proportion of the sulfone compound contained in the solvent is greater than 40% by mass,
a total proportion of the glycol compound and the sulfone compound contained in the solvent is 70% by mass or more, and
a proportion of the lactone compound contained in the solvent is more than 0% by mass and less than 10% by mass.

21. The electrolytic capacitor according to claim 20 , wherein the solvent further contains a polyalkylene glycol having a weight average molecular weight ranging from 300 to 1000, inclusive.

22. The electrolytic capacitor according to claim 21 , wherein a proportion of the polyalkylene glycol contained in the solvent ranges from 5% by mass to 30% by mass, inclusive.

23. An electrolytic capacitor comprising:
an anode body having a dielectric layer;
a solid electrolyte layer in contact with the dielectric layer of the anode body; and
an electrolyte solution, wherein:
the solid electrolyte layer includes a π-conjugated conductive polymer,
the electrolyte solution contains a solvent and a solute,
the solvent contains a glycol compound and a sulfone compound,
a proportion of the glycol compound contained in the solvent is 10% by mass or more,
a proportion of the sulfone compound contained in the solvent is greater than 30% by mass,
a total proportion of the glycol compound and the sulfone compound contained in the solvent is 70% by mass or more, and
the solvent contains no lactone compounds.

24. The electrolytic capacitor according to claim 23 , wherein the proportion of the sulfone compound contained in the solvent is 50% by mass or more and 90% by mass or less.

25. The electrolytic capacitor according to claim 23 , wherein the solvent further contains a polyalkylene glycol having a w

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Tsubaki Yuichiro
• Aoyama Tatsuji
• Saito Kazuyo

Classifications

• C25D11/06

  characterised by the electrolytes used · CPC title

• C25D11/16

  Pretreatment {, e.g. desmutting} · CPC title

• H01G9/145

  Liquid electrolytic capacitors (H01G11/00 takes precedence) · CPC title

• H01G9/032

  Inorganic semiconducting electrolytes, e.g. MnO2 · CPC title

• H01G9/055

  Etched foil electrodes · CPC title