Heat-curable resin composition, heat-curable resin film and semiconductor device

Patent metadata

Field	Value
Publication number	US-10865304-B2
Application number	US-201916557467-A
Country	US
Kind code	B2
Filing date	Aug 30, 2019
Priority date	Sep 12, 2018
Publication date	Dec 15, 2020
Grant date	Dec 15, 2020

Abstract

Provided is a heat-curable resin composition exhibiting a superior handling property and workability in the form of a film, having a high adhesion to a base material, and capable of yielding a cured product with a low elasticity. The heat-curable resin composition contains:
(A) 90 to 10 parts by mass of a silicone-modified epoxy resin; (B) 10 to 90 parts by mass of a maleimide compound having a weight-average molecular weight (Mw) of 2,500 to 50,000; and (C) a curing catalyst,

provided that a total of the components (A) and (B) is 100 parts by mass.

First claim

What is claimed is:

1. A heat-curable resin composition comprising:
(A) 90 to 10 parts by mass of a silicone-modified epoxy resin;
(B) 10 to 90 parts by mass of a maleimide compound having a weight-average molecular weight (Mw) of 2,500 to 50,000; and
(C) a curing catalyst,

provided that a total of the components (A) and (B) is 100 parts by mass.

2. The heat-curable resin composition according to claim 1 , further comprising:
(A′) an epoxy resin other than the silicone-modified epoxy resin (A).

3. The heat-curable resin composition according to claim 1 , wherein the silicone-modified epoxy resin (A) is at least one of silicone-modified epoxy resins represented by the following formulae (8) and (9):

wherein each X independently represents a hydrogen atom, a substituted or unsubstituted monovalent hydrocarbon group having 1 to 6 carbon atoms, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted alkoxyalkyl group; R 3 represents a substituted or unsubstituted monovalent hydrocarbon group having no aliphatic unsaturated groups; R 4 represents a glycidyl group; R 5 represents a substituted or unsubstituted divalent hydrocarbon group that may have an oxygen atom(s); each R 6 independently represents a hydrogen atom, a methyl group or a trifluoromethyl group; k represents an integer of not smaller than 8; p represents an integer of not smaller than 0.

4. The heat-curable resin composition according to claim 1 , wherein the maleimide compound (B) is a bismaleimide compound represented by the following formula (1):

wherein n represents an integer of 1 to 50, R 1 independently represents one or more divalent groups selected from: a linear or branched alkylene group having 1 to 40 carbon atoms; a divalent cyclic hydrocarbon group that has 3 to 20 carbon atoms and may have a hetero atom(s); —O—; —NH—; —S—; and —SO 2 —.

5. The heat-curable resin composition according to claim 1 , wherein the maleimide compound (B) is represented by the following general formula (2):

wherein each A independently represents a tetravalent organic group having an aromatic or aliphatic ring; B represents an alkylene chain having 6 to 18 carbon atoms and a divalent aliphatic ring that may contain a hetero atom; each Q independently represents a linear alkylene group having not less than 6 carbon atoms; each R independently represents a linear or branched alkyl group having not less than 6 carbon atoms; n′ represents an integer of 1 to 10; m represents an integer of 0 to 10.

6. The heat-curable resin composition according to claim 5 , wherein A in the general formula (2) has any one of the following structures:

wherein bonds in the above structural formulae that are yet unbonded to substituent groups are to be bonded to carbonyl carbons forming cyclic imide structures in the general formula (2).

7. The heat-curable resin composition according to claim 1 , wherein the curing catalyst (C) is at least one selected from (C1) a curing agent for epoxy resin, (C2) a curing accelerator and (C3) a polymerization initiator.

8. The heat-curable resin composition according to claim 1 , wherein the curing catalyst (C) is an imidazole compound.

9. A heat-curable resin film containing the heat-curable resin composition according to claim 1 .

10. A semiconductor device encapsulated by the heat-curable resin film according to claim 9 .

Assignees

• Shinetsu Chemical Co

Inventors

• Kushihara Naoyuki
• Kudo Yuki
• Sumita Kazuaki
• Tsutsumi Yoshihiro
• Hamamoto Yoshihira

Classifications

• C08L79/085

  Unsaturated polyimide precursors · CPC title

• C08L63/00 Primary

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C08G59/686

  containing nitrogen · CPC title

• C08G59/4042

  Imines; Imides · CPC title