Composite anode active material, anode and lithium battery including the composite anode active material, and method of preparing the composite anode active material

Patent metadata

Field	Value
Publication number	US-10862107-B2
Application number	US-201715397910-A
Country	US
Kind code	B2
Filing date	Jan 4, 2017
Priority date	May 31, 2016
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

A composite anode active material includes a composite medium, the composite medium including a first medium block including a metal nanostructure capable of intercalation or deintercalation of lithium and a conductive medium disposed on the metal nanostructure; and a second medium block, disposed adjacent to the first medium block and including a medium which is free of the metal nanostructure.

First claim

What is claimed is:

1. A composite anode active material comprising a composite medium, the composite medium comprising:
a first medium block comprising a metal nanostructure capable of intercalation or deintercalation of lithium and a conductive medium disposed on the metal nanostructure; and
a second medium block disposed adjacent to the first medium block and comprising a metal nanostructure-free medium,
wherein the metal nanostructure-free medium of the second medium block is the same as the conductive medium of the first medium block.

2. The composite anode active material of claim 1 , wherein the second medium block is connected to an end of the first medium block, and the first medium block and the second medium block are a composite medium unit.

3. The composite anode active material of claim 2 , wherein the composite medium comprises a composite medium chain, and the composite medium chain comprises a plurality of the composite medium units disposed in a first direction.

4. The composite anode active material of claim 3 , wherein in the composite medium chain, the plurality of composite medium units are disposed such that the first medium block and the second medium block are alternately disposed in the first direction.

5. The composite anode active material of claim 2 , wherein the composite medium comprises a composite medium sheet, and the composite medium sheet comprises a plurality of composite medium units disposed in a first direction and a plurality of composite medium units disposed in a second direction different from the first direction.

6. The composite anode active material of claim 2 , wherein the composite medium comprises a composite medium cluster, and the composite medium cluster comprises a plurality of composite medium units disposed in a first direction, a plurality of composite medium units disposed in a second direction different from the first direction, and a plurality of composite medium units disposed in a third direction different from the first and second directions.

7. The composite anode active material of claim 6 , wherein the composite medium cluster further comprises a pore defined by a space between the plurality of composite medium units spaced apart from each other.

8. The composite anode active material of claim 1 , wherein the composite medium comprises a plurality of first medium blocks, the plurality of first medium blocks are spaced apart from each other at predetermined intervals and are periodically disposed.

9. The composite anode active material of claim 1 , wherein the metal nanostructure-free medium comprises a buffer medium capable of absorbing a volumetric change of the first medium.

10. The composite anode active material of claim 1 , wherein the first medium block and the second medium block each have a dimension of about 10 nanometers to about 10 micrometers.

11. The composite anode active material of claim 1 , wherein the conductive medium disposed on the metal nanostructure is a coating layer on a surface of the metal nanostructure.

12. The composite anode active material of claim 11 , wherein the coating layer has a thickness of about 1 nanometer to about 100 nanometers.

13. The composite anode active material of claim 1 , wherein the metal nanostructure is a one-dimensional metal nanostructure.

14. The composite anode active material of claim 13 , wherein the one-dimensional metal nanostructure comprises a metal nanowire.

15. The composite anode active material of claim 13 , wherein the one-dimensional metal nanostructure has a diameter of about 0.1 nanometer to about 100 nanometers.

16. The composite anode active material of claim 13 , wherein the one-dimensional metal nanostructure comprises at least one metal selected from Si, Ge, Sn, and Pb.

17. The composite anode active material of claim 13 , wherein the first medium block comprises a plurality of one-dimensional metal nanostructures.

18. The composite anode active material of claim 17 , wherein the first medium block comprises a three-dimensional metal nanostructure comprising the plurality of one-dimensional metal nanostructures.

19. The composite anode active material of claim 18 , wherein the three-dimensional metal nanostructure has a net structure.

20. The composite anode active material of claim 18 , wherein the three-dimensional metal nanostructure has a dimension in a range of about 10 nanometers to about 10 micrometers.

21. The composite anode active material of claim 1 , wherein the conductive medium of the first medium block comprises at least one element selected from C, O, F, CI, Br, I, P, N, S, B, Sb, As, Si, Ge, Sn, Pb, and Al.

22. The composite anode active material of claim 1 , wherein the conductive medium of the first medium block is a solid electrolyte.

23. The composite anode active material of claim 1 , wherein the second medium block is ionically conductive or electronically conductive.

24. The composite anode active material of claim 1 , wherein the second medium block comprises a halogen, and an amount of the halogen in the second medium block is greater than an amount of the halogen in the first medium block.

25. The composite anode active material of claim 1 , wherein the halogen is F.

26. The composite anode active material of claim 1 , wherein the second medium block comprises two or more elements which are present in the first medium block.

27. An anode comprising a composite anode active material, the composite anode active material comprising a composite medium, wherein the composite medium comprises:
a first medium block comprising a metal nanostructure capable of intercalation or deintercalation of lithium and a conductive medium disposed on the metal nanostructure; and
a second medium block disposed adjacent to the first medium block, and comprising a metal nanostructure-free medium.
wherein the metal nanostructure-free medium of the second medium block is the same as the conductive medium of the first medium block.

28. A lithium battery comprising:
a cathode; and
the anode of claim 27 .

29. The lithium battery of claim 28 , wherein a capacity retention ratio of the lithium battery is 70% or more after 300 charge/discharge cycles performed at a voltage range of about 2.5 volts to about 4.3 volts.

Assignees

• Samsung Electronics Co Ltd
• Samsung Sdi Co Ltd

Inventors

• Ogata Ken
• Jeon Seongho
• Takei Koichi
• Han Sungsoo

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/364 Primary

  as mixtures · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title