Nanotube-based nanomaterial membrane

Patent metadata

Field	Value
Publication number	US-8974967-B2
Application number	US-97455210-A
Country	US
Kind code	B2
Filing date	Dec 21, 2010
Priority date	Dec 21, 2009
Publication date	Mar 10, 2015
Grant date	Mar 10, 2015

Abstract

As consistent with various embodiments, an electronic device includes a carbon nanotube film having a plurality of carbon nanotubes. In certain embodiments, a coating, such as an inorganic coating, is formed on a surface of carbon nanotube. The nanotube film supports the device and facilitates electrical conduction therein. The coated nanotube is amenable to implementation with devices such as thin film batteries, a battery separator, thin film solar cells and high-energy Lithium ion batteries.

First claim

What is claimed is:

1. An electronic device comprising:
a carbon nanotube film having a plurality of carbon nanotubes that includes a porous structure;
an inorganic material configured and arranged to provide a membrane including the plurality of carbon nanotubes embedded within the membrane; and
a conductive electrode coupled to the carbon nanotube film for conducting current therefrom.

2. The device of claim 1 , wherein the porous structure is configured and arranged to maintain arrangement of the carbon nanotubes via interlayer bonding forces, via the plurality of carbon nanotubes, to sustain structural integrity and conductivity of the device, and further comprising a device coating on the carbon nanotubes in the film, the device coating including at least one of
a charge-mode coating configured to receive ions for storing energy in a charging mode, and
a discharge-mode coating configured to receive ions in a discharging mode.

3. The device of claim 1 , wherein the porous structure includes inter-layered carbon nanotubes forming pores between the nanotubes, and is configured to mechanically support the inorganic material and the conductive electrode of the device.

4. The device of claim 3 , wherein
the carbon nanotube film includes a plurality of p-type carbon nanotubes,
the inorganic material includes an n-type material, and
a p-n junction including a portion of each of the nanotubes and the material.

5. The device of claim 3 , wherein the inorganic material includes electrode material that forms the conductive electrode.

6. The device of claim 3 , further comprising:
a conduction channel including a portion of the carbon nanotube film; and
an electrode including an amorphous silicon coating coupled to the carbon nanotube film of the conduction channel.

7. The device of claim 6 , wherein the amorphous coating has a thickness of about one micrometer.

8. The device of claim 3 , further comprising:
at least one of a cathode material and an anode material coated on the carbon nanotube film; and
an insulative material coated on the carbon nanotube film and configured to electrically insulate the carbon nanotube film.

9. The device of claim 8 , wherein the insulative material includes at least one of Silicon and SiN and has at thickness of about 100 nm.

10. The device of claim 8 , wherein the carbon nanotube film is a current collector for the at least one of the cathode material and anode material.

11. The device of claim 8 , further including a current collector material on the coated carbon nanotube film.

12. The device of claim 8 ,
wherein the carbon nanotube film is coated with an anode material and forms an anode of a battery,
further including
another carbon nanotube film coated with a cathode material and forming a cathode of the battery, and
an electrolytic separator material between the anode and cathode and configured to pass ions between the respective anode and cathode.

13. The device of claim 8 ,
wherein the carbon nanotube film is coated with an anode material, and
further including
an anode current collector configured to collect current from the anode material of the carbon nanotube film and forming, with the coated carbon nanotube film, an anode of the battery device,
another carbon nanotube film coated with a cathode material,
a cathode current collector configured to collect current from the cathode material and forming, with the cathode material-coated carbon nanotube film, a cathode of the battery, and
an electrolytic separator material between the anode and cathode and configured to pass ions between the respective anode and cathode.

14. A thin-film cell comprising:
an n-type silicon material;
a thin film on the n-type silicon material and including p-type carbon nanotubes forming a p-n junction with the n-type silicon material, the thin film being configured and arranged to provide a membrane including the carbon nanotubes embedded within the membrane; and
electrodes respectively coupled to the n-type silicon material and the p-type carbon nanotubes and configured to couple current generated at the p-n junction in response to light, the carbon nanotubes forming a porous structure.

15. The cell of claim 14 , wherein the p-type carbon nanotubes are a carbon nanotube film, and the n-type silicon material is a layer on the film.

16. The cell of claim 14 , further including a load coupled to the electrodes and configured to draw current generated at the p-n junction.

17. An electronic device, comprising:
a carbon nanotube film having a plurality of carbon nanotubes that form a porous structure;
means, including an inorganic material, for providing a membrane including the plurality of carbon nanotubes embedded within the membrane; and
means, coupled to the carbon nanotube film, for conducting current therefrom.

18. The device of claim 1 , wherein the porous structure is configured and arranged to maintain arrangement of the carbon nanotubes via van der Waals forces between the plurality of carbon nanotubes, to sustain structural integrity and conductivity of the device.

19. The device of claim 1 , wherein the porous structure includes a plurality of pores, each with a respective size in the range of approximately 1-100 nm.

20. The device of claim 1 , wherein the porous structure includes a plurality of pores configured and arranged to facilitate transport of electrolytes.

21. The device of claim 1 , wherein the carbon nanotube film includes material-filled spaces between the plurality of carbon nanotubes.

22. The device of claim 1 , wherein the carbon nanotube film includes material-filled spaces between the plurality of carbon nanotubes, and further comprising a continuous film that fills the spaces.

23. The device of claim 1 , wherein the carbon nanotube film includes material-filled spaces between the plurality of carbon nanotubes, and the inorganic material is a continuous film that fills the spaces.

24. The device of claim 1 , wherein the plurality of carbon nanotubes are deposited to manifest a layer formed by a deposition of carbon nanotubes, with the plurality of carbon nanotubes crossing each other at a plurality of different angles.

25. The device of claim 17 , wherein the porous structure is configured and arranged to maintain arrangement of the carbon nanotubes via van der Waals forces between the plurality of carbon nanotubes, to sustain structural integrity and conductivity of the device.

26. The device of claim 17 , wherein the porous structure includes a plurality of pores with sizes of approximately 1-100 nm, and the plurality of pores are configured and arranged to facilitate transport of electrolytes.

27. The device of claim 1 , wherein the inorganic material is between 50 nanometers and 10 micrometers in thickness.

28. The device of claim 1 , wherein the inorganic material is further configured and arranged to coat and embed the plurality of carbon nanotubes within the membrane.

29. The device of claim 1 , wherein the membrane includes an upper surface, and further including another membrane constructed according to the membrane of claim 1 , and disposed on the upper surface of the first-recited membrane.

Assignees

• Cui li-feng
• Cui Yi
• Hu Liangbing
• Univ Leland Stanford Junior

Inventors

• Cui li-feng
• Cui Yi
• Hu Liangbing

Classifications

• H10F77/1226

  comprising multiple Group IV elements, e.g. SiC · CPC title

• H10F77/147

  Shapes of bodies · CPC title

• H10F10/165

  the heterojunctions being Group IV-IV heterojunctions, e.g. Si/Ge, SiGe/Si or Si/SiC photovoltaic cells · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• B32B5/26

  another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} · CPC title