Multilayer stretch films and methods thereof

Patent metadata

Field	Value
Publication number	US-10857768-B2
Application number	US-201716331757-A
Country	US
Kind code	B2
Filing date	Aug 30, 2017
Priority date	Sep 29, 2016
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

Embodiments disclosed herein include multilayer cast films having a first outer layer, a core layer, and a second outer layer, wherein the first outer layer comprises (a) a linear low density polyethylene (LLDPE), ultra-low density polyethylene (ULDPE), a first polyethylene composition, or combinations of two or more thereof, and (b) polyisobutylene, and the core layer comprises a core layer polyethylene composition.

First claim

We claim:

1. A multilayer cast film comprising a first outer layer, a core layer, and a second outer layer, wherein:
the first outer layer comprises (a) a linear low density polyethylene (LLDPE), ultra-low density polyethylene (ULDPE), a first polyethylene composition, or combinations of two or more thereof, and (b) polyisobutylene; and
the core layer comprises a core layer polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the core layer polyethylene composition is characterized by the following properties:
(a) a melt index, I2, of from 2.5 to 12.0 g/10 min;
(b) a density of from 0.910 to 0.925 g/cc;
(c) a melt flow ratio, I10/I2, of from 6.0 to 7.6; and
(d) a molecular weight distribution, (Mw/Mn) of from 2.5 to 3.6;
wherein the core layer polyethylene composition has a metal catalyst residual of greater than or equal to 1 parts by combined weight of at least three metal residues per one million parts of core layer polyethylene composition.

2. The film of claim 1 , wherein the first outer layer comprises from 0.5 to 10 weight percent, based on the total weight of polymers present in the first outer layer, of polyisobutylene.

3. The film of claim 1 , wherein the first outer layer further comprises a first polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the first polyethylene composition is characterized by the following properties:
(a) a melt index, I2, of from 2.5 to 12.0 g/10 min;
(b) a density of from 0.910 to 0.925 g/cc;
(c) a melt flow ratio, I10/I2, of from 6.0 to 7.6; and
(d) a molecular weight distribution, (Mw/Mn) of from 2.2 to 3.6.

4. The film of claim 1 , wherein the second outer layer comprises a linear low density polyethylene or a second polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the second polyethylene composition is characterized by the following properties:
(a) a melt index, I2, of from 2.5 to 12.0 g/10 min;
(b) a density of from 0.910 to 0.925 g/cc;
(c) a melt flow ratio, I10/I2, of from 6.0 to 7.6; and
(d) a molecular weight distribution, (Mw/Mn) of from 2.2 to 3.6.

5. The film of claim 4 , wherein the second outer layer further comprises polyisobutylene.

6. The film of claim 5 , wherein the second outer layer comprises from 0.5 to 10 weight percent, based on the total weight of polymers present in the second outer layer, of polyisobutylene.

7. The film of claim 1 , wherein the core layer polyethylene composition is formed in the presence of a catalyst composition comprising a multi-metallic procatalyst via solution polymerization.

8. The film of claim 1 , wherein the core layer polyethylene composition has a Comonomer Distribution Breadth Index (CDBI) of less than 60%, or from 52.5% to 60%.

9. The film of claim 1 , wherein the core layer polyethylene composition has a viscosity ratio (viscosity at 0.1 rad/s/viscosity at 100 rad/s, both measured at 190° C. using dynamic mechanical spectroscopy) of 2 to 6, or from 2.0 to 2.9.

10. The film of claim 1 , wherein the core layer polyethylene composition has a melt flow ratio, I10/I2, of from 6.0 to 7.4, or from 6.4 to 7.4.

11. A method of making a multilayer cast film, the method comprising:
coextruding a first outer layer composition, a core layer composition, and a second outer layer composition to form a multilayer cast film;
wherein the first outer layer composition comprises (a) a linear low density polyethylene (LLDPE), ultra-low density polyethylene (ULDPE), a first polyethylene composition, or combinations of two or more thereof, and (b) polyisobutylene;
wherein the core layer composition comprises a core layer polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the polyethylene composition is characterized by the following properties:
(a) a melt index, I2, of from 2.5 to 12.0 g/10 min;
(b) a density of from 0.910 to 0.925 g/cc;
(c) a melt flow ratio, I10/I2, of from 6.0 to 7.6; and
(d) a molecular weight distribution, (Mw/Mn) of from 2.2 to 3.6; and
wherein the second outer layer composition comprises a linear low density polyethylene or a second polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the polyethylene composition is characterized by the following properties:
(a) a melt index, I2, of from 2.5 to 12.0 g/10 min;
(b) a density of from 0.910 to 0.925 g/cc;
(c) a melt flow ratio, I10/I2, of from 6.0 to 7.6; and
(d) a molecular weight distribution, (Mw/Mn) of from 2.2 to 3.6.

12. The method of claim 11 , wherein the second outer layer composition further comprises polyisobutylene.

13. The method of claim 12 , wherein the second outer layer composition comprises from 0.5 to 10 weight percent, based on the total weight of polymers present in the second outer layer, of polyisobutylene.

Assignees

• Dow Global Technologies Llc
• Pbb Polisur Srl
• Dow Quim De Colombia S A
• Dow Glo
• Pbbpoiisur S R L

Inventors

• Oliveira Marlos Giuntini De
• Karjala Teresa P
• Bilgen Mustafa
• Gomes Jorge Caminero
• Zanetti Maximiliano
• Molano Niampira Miguel A
• Rodriguez Camelo Jorge Mario
• Valle Camila Do
• Raimondi Guillermo A

Classifications

• B32B27/32 Primary

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• C08F2410/03

  Multinuclear procatalyst, i.e. containing two or more metals, being different or not · CPC title

• B32B2274/00

  Thermoplastic elastomer material · CPC title

• B32B2439/46

  Bags · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title