Coextrusion processes for making multilayer films and films made thereby

Patent metadata

Field	Value
Publication number	US-9296182-B2
Application number	US-30221107-A
Country	US
Kind code	B2
Filing date	Jun 8, 2007
Priority date	Jun 9, 2006
Publication date	Mar 29, 2016
Grant date	Mar 29, 2016

Abstract

The invention relates to a blown film coextrusion process. The process involves extruding core contact layers through a die exit at a specified speed and cooling, orienting and crystallizing the multi-layer film formed at a specified deformation rate to form a the frost line is a specified distance from the die exit by withdrawing film at a take up speed. The core and core contact layers are of a film forming polymer composition comprising at least 90 wt % of ethylene based polymer. The ethylene based polymer of the core layer has an average density of ethylene based polymers equal to or higher than that of ethylene based polymer of the core contact layers. The invention specifically concerns the feature that the core layer composition contains a portion of and the composition of the core contact layers contains a portion of a linear polyethylene so as to make the core layer more resistant to deformation than the skin layers.

First claim

The invention claimed is:

1. A method for determining process conditions for a blown film coextrusion process, said coextrusion process comprising:
A) coextruding a film having a core layer and a pair of core contact layers adjacent both sides of the core layer through a die exit at a linear speed V o cm/s; and cooling, orienting and crystallizing the multi-layer film formed until a frost line is reached at a distance FLH from the die exit by withdrawing the film at a take up speed V f in cm/s; the core contact layers having a composition of at least 90 wt % of ethylene based polymer of which at least 75 wt % is a linear polyethylene with an I 2.16 linear pe-skin of 2.5 g/10 min or less and the core layer having a composition of at least 90 wt % of ethylene based polymer or other compatible linear olefin based polymer of which at least 5 wt % is an LDPE with a I 2.16 Idpe-core of 1.5 g/10 min or less;
and said method comprising:
B) subsequently increasing the deformation rate E avg =(V f −V o )/FLH to a level above at least 0.5 s −1 to lower the haze value; and
wherein the linear polyethylene of the core contact layers contain an LLDPE and at least 60 wt % of an mLLDPE based on the total weight of the linear polyethylene.

2. The method according to claim 1 in which the compositions are further adjusted by:
iv) increasing the average density of ethylene based polymer in the core layer or layers above that of the ethylene based polymer of the skin layers.

3. The method according to claim 1 in which one or both core contact layers is a skin layer forming one surface or are skin layers forming both film surfaces.

4. The method according to claim 1 in which the E avg >0.14a 2 +0.025a+0.64 wherein a I 2.16 Idpe-core and the film has a haze of less than 6 as determined by a method based on ASTM D-1003 described herein.

5. The method according to claim 1 in which the core layer composition contains no or less than 4 wt % of a linear polyolefin other than linear polyethylene and/or contains no or less than 4 wt % of a heterogeneously branched ethylene polymer other than LDPE.

6. The method according to claim 1 in which the core contact layers contain at least 95 wt %, of linear polyethylene.

7. The method according to claim 1 in which the core contact layers contain no or less than 2 wt % of an ethylene based polymer containing polar moieties and/or contain no or less than 5 wt % of a substantially homogenously branched linear polyethylene.

8. The method according to claim 1 in which the core contact layer composition contains at least 90 wt % of linear polyethylene and the core layer contains less than 10 wt % of the LDPE having a I 2.16 Idpe-core of 1.5 g/10 min or less.

Assignees

• Vinck Michael Jan
• Tierens Marc Desire
• Ohlsson Stefan Bertil
• Bastiaens Mario
• Exxonmobil Chem Patents Inc

Inventors

• Vinck Michael Jan
• Tierens Marc Desire
• Ohlsson Stefan Bertil
• Bastiaens Mario

Classifications

• B29K2023/083

  EVA, i.e. ethylene vinyl acetate copolymer · CPC title

• B32B27/32 Primary

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B29C48/10

  flexible, e.g. blown foils · CPC title

• B29C48/21

  the layers being joined at their surfaces · CPC title

• B29K2023/0625

  LLDPE, i.e. linear low density polyethylene · CPC title