Crucible

Patent metadata

Field	Value
Publication number	US-10844518-B2
Application number	US-201716073184-A
Country	US
Kind code	B2
Filing date	Jan 26, 2017
Priority date	Feb 5, 2016
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A crucible includes a wall made of a base material of tungsten or molybdenum or of a material based on tungsten or molybdenum. A barrier layer is disposed at least in sections on an outer side of the wall and/or in the wall. The barrier layer is made of a metallic material having a greater affinity for carbon and/or oxygen than the base material. A method for using a crucible for producing single-crystal sapphire or fused quartz and a method for producing a crucible for high-temperature applications are also provided.

First claim

The invention claimed is:

1. A crucible, comprising:
a wall made of a base material of tungsten or molybdenum or a material based on tungsten or molybdenum, said wall having an outer side;
a barrier layer disposed at least one of on said outer side of said wall or in said base material of said wall, at least in sections, said barrier layer being made of a metallic material having greater affinity for at least one of carbon or oxygen than said base material; and
an outer layer at least partly covering said barrier layer, said outer layer being made of a material different than said barrier layer.

2. The crucible according to claim 1 , wherein said barrier layer is formed of tantalum, niobium or titanium or of a material based on tantalum, niobium or titanium.

3. The crucible according to claim 1 , wherein said outer layer is made of said base material.

4. The crucible according to claim 1 , wherein said barrier layer is disposed on an outer third of said wall.

5. The crucible according to claim 1 , wherein said barrier layer is a substantially dense layer.

6. The crucible according to claim 1 , wherein said barrier layer has a relative density of more than 90% and a porosity of less than 10%.

7. The crucible according to claim 1 , wherein said barrier layer has a relative density of more than 95% and a porosity of less than 5%.

8. The crucible according to claim 1 , wherein said barrier layer has a relative density of more than 99% and a porosity of less than 1%.

9. The crucible according to claim 1 , wherein said barrier layer has a thickness of between 25 μm and 500 μm.

10. The crucible according to claim 1 , wherein said barrier layer has a thickness of between 100 μm and 300 μm.

11. The crucible according to claim 1 , wherein said barrier layer has a thickness of between 175 μm and 225 μm.

12. The crucible according to claim 1 , wherein said barrier layer has characteristics of having been produced by a slurry process.

13. The crucible according to claim 1 , wherein said barrier layer has characteristics of having been produced by thermal spraying.

14. The crucible according to claim 1 , wherein said barrier layer has characteristics of having been produced by cold gas spraying.

15. The crucible according to claim 1 , wherein said barrier layer contains at least 90% by weight of said metallic material having a greater affinity for at least one of carbon or oxygen than said base material.

16. A method for using a crucible, the method comprising the following steps:
providing a crucible including:
a wall made of a base material of tungsten or molybdenum or a material based on tungsten or molybdenum, the wall having an outer side;
a barrier layer disposed at least one of on the outer side of the wall or in the base material of the wall, at least in sections, the barrier layer being made of a metallic material having greater affinity for at least one of carbon or oxygen than the base material; and
an outer layer at least partly covering the barrier layer, the outer layer being made of a material different than the barrier layer; and

producing single-crystal sapphire or fused quartz in the crucible.

17. A method for producing a crucible for high-temperature applications, the method comprising the following steps:
producing a blank made of a base material of refractory metal by at least one of pressing and sintering refractory metal powder or forming;
applying a barrier layer to an outer side of the blank, the barrier layer being made of a metallic material having a greater affinity for at least one of carbon or oxygen than the base material; and
carrying out the step of applying the barrier layer by thermal spraying or cold gas spraying or a slurry process.

18. The method according to claim 17 , wherein the refractory metal powder is formed of molybdenum or tungsten, or alloys of molybdenum or tungsten or powder mixtures of molybdenum or tungsten.

19. The method according to claim 17 , wherein the metallic material forming the barrier layer is tantalum, niobium or titanium or a material based on tantalum, niobium or titanium.

20. A method for producing a crucible for high-temperature applications, the method comprising the following steps:
producing a blank made of a base material of refractory metal by at least one of pressing and sintering refractory metal powder or forming;
applying a barrier layer to an outer side of the blank, the barrier layer being made of a metallic material having a greater affinity for at least one of carbon or oxygen than the base material; and
applying an outer layer made of a further material to the barrier layer.

21. The method according to claim 20 , wherein the outer layer is made of the base material.

22. A crucible, comprising:
a wall made of a base material of tungsten or molybdenum or a material based on tungsten or molybdenum, said wall having an outer side;
a barrier layer disposed at least one of on said outer side of said wall or in said base material of said wall, at least in sections, said barrier layer being made of a metallic material having greater affinity for at least one of carbon or oxygen than said base material; and
said barrier layer being a cold-gas-sprayed layer formed of tantalum or a material based on tantalum.

Assignees

• Plansee Se

Inventors

• Mark Michael
• Traxler Hannes
• O'Sullivan Michael
• Knabl Wolfram
• Lorich Alexander
• Schiftner Robert

Classifications

• C30B35/002 Primary

  Crucibles or containers · CPC title

• C30B29/20 Primary

  Aluminium oxides · CPC title