Reactor for the hydrothermal oxidation treatment of an organic material in a reaction medium

Patent metadata

Field	Value
Publication number	US-10828617-B2
Application number	US-201716468067-A
Country	US
Kind code	B2
Filing date	Dec 14, 2017
Priority date	Dec 16, 2016
Publication date	Nov 10, 2020
Grant date	Nov 10, 2020

Abstract

A reactor for treating an organic material in a reaction medium by hydrothermal oxidation, comprising: a longitudinal body provided with a cold interface flange; an inner tube, positioned in the body to form an annular area and comprising a cold end and a hot end, the inner tube delimiting an internal reaction area in fluid communication with the annular area via an opening provided in the hot end of the inner tube; blades for stirring the reaction medium situated in the internal reaction area and mounted rotating about the longitudinal axis of the body; a sleeve for injecting organic material to be treated into the inner tube. The inner tube is mounted rotating on the cold flange, so as to be rotated about the longitudinal axis; the sleeve being positioned inside the inner tube, having a bore that defines a passage for the organic material to be treated to pass.

First claim

What is claimed is:

1. A reactor for hydrothermal oxidation treatment of an organic material in a reaction medium, comprising:
a main body extending along a longitudinal axis, being provided at a first one of its ends with a cold interface flange, sealing means being disposed between the main body and the flange;
an inner tube placed inside the main body so as to form an annular zone along the main body, the inner tube comprising a cold first end sealingly contacting with the cold flange, and a warm second end, the inner tube delimiting a reaction internal zone which is in fluid communication with the annular zone through at least one aperture disposed in the warm end of the inner tube;
a stirring means for agitating the reaction mixture located in the reaction internal zone of the inner tube, the stirring means being rotatably mounted about the longitudinal axis;
a refrigerating means for cooling an effluent located in the reaction internal zone of the inner tube before being discharged from the reactor through an outlet of the main body;
an inlet for a water-oxidant mixture located on the side of the cold first end of the main body, the water-oxidant mixture running through the annular zone from the cold first end to the warm second end of the inner tube, before penetrating the reaction internal zone of the inner tube;
an effluent outlet located at the cold first end of the main body;
an injection means for injecting the organic material to be treated in the inner tube;
wherein the inner tube is rotatably mounted to the cold flange, so as to be rotatably driven about the longitudinal axis;
wherein the injection means includes a sleeve, placed inside the inner tube, the sleeve having a first end which is sealingly attached to the cold flange and a second end which is located in the proximity of the warm end of the inner tube, the sleeve further having a bore which defines a passageway of the organic material to be treated from the first end to the second end of the sleeve; and
wherein the stirring means comprises a plurality of blades attached to the inner wall of the inner tube and spaced apart from each other along a longitudinal direction of the inner tube, the blades being rotatably driven by the rotation of the inner tube, and a plurality of counter-blades attached to the outer wall of the sleeve and spaced apart from each other along a longitudinal direction of the sleeve.

2. The reactor according to claim 1 , wherein the stirring means further comprises a rotating shaft which is disposed in the reaction internal zone of the inner tube and which passes through the cold flange, the rotating shaft being housed in the bore of the sleeve of the injection means.

3. The reactor according to claim 1 , wherein the stirring means further comprises an annular geometry piece provided with a bore, which is coaxial with the bore of the sleeve and which defines a passageway for the rotating shaft, as well as a fixed counter-blade which connects the piece to the second end of the sleeve.

4. The reactor according to claim 1 , wherein the stirring means further comprises a plurality of blades attached to the outer wall of the inner tube and spaced apart from each other along the longitudinal direction of the inner tube.

5. The reactor according to claim 1 , wherein the sleeve further includes, on its outer wall, at least one radially projecting disc.

6. The reactor according to claim 1 , wherein the refrigerating means includes a heat exchanger forming a cold loop radiator, this heat exchanger being disposed in the annular zone in the proximity of, preferably contacting with, the cold flange.

7. The reactor according to claim 1 , further comprising a plurality of glove fingers, disposed in the annular zone and passing through the cold flange.

8. The reactor according to claim 1 , wherein, the refrigerating means including a heat exchanger forming a cold loop radiator, this heat exchanger being disposed in the annular zone in the proximity of, preferably contacting with, the cold flange, and the reactor further comprising a plurality of glove fingers, disposed in the annular zone and passing through the cold flange, the heat exchanger forming a cold loop radiator is an annular element which is coaxial with the inner tube and which is provided with channels, each channel defining a passageway for a glove finger.

9. The reactor according to claim 1 , further comprising a heat exchanger forming a warm loop radiator, obtained by circulating a coolant in contact with the outer wall of the main body.

10. The reactor according to claim 1 , further comprising a double jacket, which is kept at a pressure lower than or equal to 300 mbar and which is disposed about the main body and in contact with the cold flange.

Assignees

• Commissariat Energie Atomique

Inventors

• Ruiz Jean-Christophe
• Turc Hubert-Alexandre
• Leybros Antoine

Classifications

• B01J19/1843

  Concentric tube · CPC title

• B01J4/001

  Feed or outlet devices as such, e.g. feeding tubes · CPC title

• B01J2204/007

  Aspects relating to the heat-exchange of the feed or outlet devices · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title

• B01J3/008 Primary

  Processes carried out under supercritical conditions · CPC title