Wholly aromatic liquid crystalline polyester resin, molded article, and electric and electronic components

Patent metadata

Field	Value
Publication number	US-10822453-B2
Application number	US-201716314998-A
Country	US
Kind code	B2
Filing date	Jul 3, 2017
Priority date	Jul 4, 2016
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

The present invention provides a wholly aromatic liquid crystalline polyester resin having an excellent heat resistance while having an extremely low dielectric tangent.

First claim

The invention claimed is:

1. A wholly aromatic liquid crystalline polyester resin comprising,
structural unit (I) derived from 6-hydroxy-2-naphthoic acid,
structural unit (II) derived from an aromatic diol compound,
structural unit (III) derived from an aromatic dicarboxylic compound, wherein
structural unit (III) comprises structural unit (III A) derived from terephthalic acid, and structural unit (III B) derived from 2,6-naphthalene dicarboxylic acid, wherein
the composition ratio (mol %) of said structural units satisfies the following conditions:
45 mol %≤structural unit (I)≤7580 mol %
12 mol %≤structural unit (II)≤27.5 mol %
3 mol %≤structural unit (III A)≤25 mol %
2 mol %≤structural unit (III B)≤9 mol %
the dielectric tangent in measurement frequency 10 GHz is 0.85×10 −3 or lower, and
the melt tensile force at a measurement end point of the melt strand that was extruded under the conditions of the melting point of the liquid crystalline polyester resin +20° C. and shear rate of 1000 s −1 is 3 mN or more.

2. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
the composition ratio (mol %) of the structural units further satisfies the following conditions:
50 mol %≤structural unit (I)≤70 mol %
15 mol %≤structural unit (II)≤27 mol %
6 mol %≤structural unit (III A)≤24 mol %
3 mol %≤structural unit (III B)≤9 mol %.

3. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
said structural unit (II) is represented by the following formula:
O—Ar 1 —O   (II)

wherein Ar 1 is selected from the group consisting of phenyl, biphenyl, naphtyl, anthryl, and phenanthryl, optionally having a substituent group.

4. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
the melting point is 300° C. or more.

5. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
the elongation ratio of a melt strand extruded under the conditions of melting point of the liquid crystalline polyester resin+20° C. and shear rate of 1000 s −1 is 10 times or more.

6. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
the dielectric tangent in measurement frequency 82 GHz is less than 3.5×10 −3 .

7. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
the dielectric tangents of 30° C. and 100° C. in measurement frequency 34 GHz are less than 2.0×10 −3 and less than 4.0×10 −3 respectively.

8. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
the rate of change of dielectric tangent from 30° C. to 100° C. in measurement frequency 34 GHz is less than 3.0×10 −5 /° C.

9. The wholly aromatic liquid crystalline polyester resin according to claim 1 , wherein
the melt viscosity at the melting point of the liquid crystalline polyester resin+20° C. and shear rate of 1000 s −1 is from 20 to 100 Pa·s.

10. A molded article comprising the wholly aromatic liquid crystalline polyester resin according to claim 1 .

11. The molded article according to claim 10 , wherein
the molded article is in a film form.

12. The molded article according to claim 10 , wherein
the molded article is in a fiber form.

13. The molded article according to claim 10 , wherein
the molded article is an injection molded article.

14. Electric and electronic components comprising the molded article according to claim 10 .

Assignees

• Eneos Corp

Inventors

• Washino Gosuke

Classifications

• H01B3/421 Primary

  Polyesters · CPC title

• H01B3/42

  polyesters; polyethers; polyacetals · CPC title

• C08G63/60

  derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds · CPC title

• H01B17/56

  Insulating bodies · CPC title

• C08J2367/03

  the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings · CPC title