Polyester composition and film using same, sheet-like structure, electric insulation sheet, and solar cell back sheet, and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-9396836-B2
Application number	US-201214003032-A
Country	US
Kind code	B2
Filing date	Feb 29, 2012
Priority date	Mar 4, 2011
Publication date	Jul 19, 2016
Grant date	Jul 19, 2016

Abstract

A polyester composition contains polyester, a phosphoric acid and an alkali metal phosphate, a phosphorous element content P (mol/t) is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of the polyester composition. The polyester composition contains at least one metal element of Mn and Ca, any divalent metal element content other than Mn and Ca is 5 ppm or less, and when an alkali metal element content relative to the polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in the polyester composition which is calculated by expression (i) below and the phosphorous element content P (mol/t) satisfy expression (ii): (i) M=M1/2+M2 and (ii) 1.1≦M/P≦3.0.

First claim

The invention claimed is:

1. A polyester composition comprising polyester as a main component, wherein:
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca,
any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy expression (ii):
M=M1/2+M2  (i)

1.1≦M/P≦3.0.  (ii)

2. The polyester composition according to claim 1 , wherein said polyester which is the main component of said polyester composition contains a constituent ingredient having at least three carboxylic acid groups and/or hydroxyl groups as a copolymerization ingredient, and an amount of said constituent ingredient is 0.025 mol % or more and 1.5 mol % or less relative to the whole of constituent ingredients in said polyester.

3. A polyester film having a layer (layer P) containing a polyester composition comprising polyester as a main component, wherein:
said polyester is biaxially oriented,
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) in said polyester composition is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca,
any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy expression (ii):
M=M1/2+M2  (i)

1.1≦M/P≦3.0.  (ii)

4. The film according to claim 3 , wherein said layer P is layer P′ containing a coloring pigment, and, a content amount of white pigment as said coloring pigment is 1 wt % or more and 20 wt % or less relative to the whole of said layer P′, or a content amount of black pigment as said coloring pigment is 0.5 wt % or more and 5 wt % or less relative to the whole of said layer P′.

5. A solar cell back sheet comprising a polyester composition comprising polyester as a main component, wherein:
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) in said polyester composition is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca,
any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is represented by M1 (mol/t) and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is represented by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy expression (ii):
M=M1/2+M2  (i)

1.1≦M/P≦3.0.  (ii)

Assignees

• Suzuki Tadamasa
• Aoyama Shigeru
• Kojima Hiroji
• Takahashi Kozo
• Toray Industries

Inventors

• Suzuki Tadamasa
• Aoyama Shigeru
• Kojima Hiroji
• Takahashi Kozo

Classifications

• C08G63/80

  Solid-state polycondensation · CPC title

• Y10T156/10

  Methods of surface bonding and/or assembly therefor · CPC title

• H01B3/421 Primary

  Polyesters · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• Y10T428/2495

  Thickness [relative or absolute] · CPC title