Reducing surface nodules in melt-infiltrated ceramic matrix composites

Patent metadata

Field	Value
Publication number	US-10822279-B2
Application number	US-201715499960-A
Country	US
Kind code	B2
Filing date	Apr 28, 2017
Priority date	May 2, 2016
Publication date	Nov 3, 2020
Grant date	Nov 3, 2020

Abstract

In some examples, a technique for infiltrating a porous preform with a slurry to form an infiltrated-preform, where the slurry includes a plurality of solid particles, where the plurality of solid particles include a plurality of fine ceramic particles defining an average fine particle diameter, a plurality of coarse ceramic particles defining an average coarse particle diameter, and a plurality of diamond particles, where the average fine particle diameter is less than the average coarse particle diameter, and infiltrating the infiltrated-preform with a molten metal infiltrant to form a ceramic matrix composite (CMC) article.

First claim

What is claimed is:

1. A method comprising:
infiltrating a porous preform with a slurry to form an infiltrated-preform, wherein the slurry comprises a plurality of solid particles, and wherein the plurality of solid particles comprise a plurality of fine ceramic particles defining an average fine particle diameter, a plurality of coarse ceramic particles defining an average coarse particle diameter, and a plurality of diamond particles, wherein the average fine particle diameter is less than the average coarse particle diameter; and
infiltrating the infiltrated-preform with a molten metal infiltrant to form a ceramic matrix composite (CMC) article, wherein the molten metal infiltrant reacts with the diamond particles to form a metal carbide material, and wherein substantially all of the plurality of diamond particles are converted to the metal carbide as a result of the infiltrating the infiltrated-preform with the molten metal infiltrant.

2. The method of claim 1 , wherein the plurality of solid particles comprise between about 1 percent by volume (vol. %) and about 10 vol. % of the plurality of diamond particles.

3. The method of claim 1 , wherein the plurality of diamond particles define an average diamond particle diameter between about 0.1 micrometers (μm) and about 5 μm.

4. The method of claim 1 , wherein the plurality of solid particles comprise between about 40 percent by volume (vol. %) and about 50 vol. % of the plurality of coarse ceramic particles.

5. The method of claim 1 , wherein the plurality of coarse ceramic particles define an average coarse particle diameter between about 10 micrometers (μm) and about 20 μm.

6. The method of claim 1 , wherein the plurality of solid particles comprise between about 40 percent by volume (vol. %) and about 59 vol. % of the plurality of fine ceramic particles.

7. The method of claim 1 , wherein the plurality of fine ceramic particles define an average fine particle diameter between about 0.5 micrometers (μm) to about 5 μm.

8. The method of claim 1 , wherein at least one of the plurality of coarse ceramic particles or the plurality of fine ceramic particles comprise at least one of boron carbide, silicon carbide, silicon nitride, or molybdenum carbide.

9. The method of claim 1 , wherein the slurry further comprises at least one carrier material, and wherein the solid particles comprise about 40 percent by volume (vol. %) to about 70 vol. % of the slurry.

10. The method of claim 1 , wherein the slurry defines a viscosity of less than about 1000 centipoise.

11. The method of claim 1 , wherein the molten infiltrant comprises silicon or silicon alloy.

12. The method of claim 1 , wherein at least one of the plurality of coarse ceramic particles or the plurality of fine ceramic particles comprise at least one of boron carbide, silicon nitride, or molybdenum carbide.

13. The method of claim 1 , wherein a combination of the fine ceramic particles, the coarse ceramic particle, and the diamond particles inhibit a formation of nodules on an exterior surface of the CMC article following the infiltration of the infiltrated-preform with the molten metal infiltrant.

14. The method of claim 1 , wherein the plurality of diamond particles inhibit a formation of nodules on an exterior surface of the CMC article following the infiltration of the infiltrated-preform with the molten metal infiltrant by at least reacting with the molten metal infiltrant to form the metal carbide material.

15. The method of claim 1 , further comprising forming at least one of a bond layer, environmental barrier coating, or abradable layer on the CMC article.

16. The method of claim 1 , wherein the plurality of diamond particles exhibit at least one of a calcium impurity content of less than about 0.05 percent by weight (wt. %) and an iron impurity content of less than about 0.05 wt. %.

17. The method of claim 1 , wherein the metal carbide material substantially fills the interstices between the coarse particles, the fine particles, and the porous preform after the infiltration of the infiltrated-preform with the molten metal or metal alloy.

18. A method comprising:
infiltrating a porous preform with a slurry to form an infiltrated-preform, wherein the slurry comprises a plurality of solid particles, and wherein the plurality of solid particles comprise a plurality of fine ceramic particles defining an average fine particle diameter, a plurality of coarse ceramic particles defining an average coarse particle diameter, and a plurality of diamond particles, wherein the average fine particle diameter is less than the average coarse particle diameter; and
infiltrating the infiltrated-preform with a molten silicon or silicon alloy infiltrant to form a ceramic matrix composite (CMC) article, wherein a combination of the fine ceramic particles, the coarse ceramic particle, and the diamond particles inhibit a formation of silicon nodules on an exterior surface of the CMC article, wherein the molten silicon or silicon alloy infiltrant reacts with the diamond particles to form a silicon carbide material, and wherein substantially all of the plurality of diamond particles are converted to the metal carbide as a result of the infiltrating the infiltrated-preform with the molten silicon or silicon alloy infiltrant.

19. The method of claim 18 , wherein the plurality of diamond particles inhibit the formation of silicon nodules on the exterior surface of the CMC article following the infiltration of the infiltrated-preform with the molten silicon or silicon alloy infiltrant by at least reacting with the molten silicon or silicon alloy infiltrant to form the silicon carbide material.

20. A method comprising:
infiltrating a porous preform with a slurry to form an infiltrated-preform, wherein the slurry comprises a plurality of solid particles, and wherein the plurality of solid particles comprise a plurality of fine ceramic particles defining an average fine particle diameter, a plurality of coarse ceramic particles defining an average coarse particle diameter, and a plurality of diamond particles, wherein the average fine particle diameter is less than the average coarse particle diameter; and
infiltrating the infiltrated-preform with a molten metal infiltrant to form a ceramic matrix composite (CMC) article, wherein the molten metal infiltrant reacts with the diamond particles to form a metal carbide material,
wherein substantially all of the plurality of diamond particles are converted to the metal carbide as a result of the infiltrating the infiltrated-preform with the molten metal infiltrant,
wherein the plurality of solid particles comprise between about 1 percent by volume (vol. %) and about 10 vol. % of the plurality of diamond particles,
wherein the plurality of solid particles comprise between about 40 percent by volume (vol. %) and about 50 vol. % of the plurality of coarse ceramic particles, and
wherein the plurality of solid particles comprise between about 40 percent by volume (vol. %) and about 59 vol. % of the plurality of fine ceramic particles.

Assignees

• Rolls Royce High Temperature Composites Inc

Inventors

• Shim Sungbo
• Shinavski Robert

Classifications

• C04B35/5607 Primary

  based on refractory metal carbides · CPC title

• C04B35/80

  Fibres, filaments, whiskers, platelets, or the like · CPC title

• C04B2235/5472

  Bimodal, multi-modal or multi-fraction · CPC title

• C04B35/6263

  characterised by their solids loadings, i.e. the percentage of solids · CPC title

• C04B2235/5232

  Silica or silicates other than aluminosilicates, e.g. quartz · CPC title