Negative electrode active material for electrical device

Patent metadata

Field	Value
Publication number	US-10818920-B2
Application number	US-201916351064-A
Country	US
Kind code	B2
Filing date	Mar 12, 2019
Priority date	Jun 12, 2013
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

A negative electrode active material having high cycle durability contains an alloy represented by the following chemical formula (1):

Si x Sn y M z A a   (1)

wherein M is Zn, A is unavoidable impurities, x, y, z, and a represent % by mass values, and in that case, 0<x<100, 0<y<100, 0<z<100, 0≤a<0.5, and x+y+z+a=100, in which the half width of the diffraction peak of the (111) surface of Si in the range of 2θ=24 to 33° by X ray diffraction measurement of the alloy using CuKα ray is 0.7° or more, and the x is more than 23 and less than 64, the y is 4 or more and less than 34, and the z is more than 0 and less than 65.

First claim

What is claimed is:

1. A negative electrode active material for an electric device comprising an alloy represented by the following chemical formula (1):
Si x Sn y M z A a   (1)

wherein M is Zn, A is unavoidable impurities, x, y, z, and a represent % by mass values, and in that case, 23<x<64, 4≤y<34, 0<z<65, 0≤a<0.5, and x+y+z+a=100,
wherein the alloy is a ternary alloy having a uniform composition ratio throughout, and the half width of the diffraction peak of the (111) surface of Si in the range of 2θ=24 to 33° by X ray diffraction measurement of the alloy using CuKα ray is 1.4° or more and less than 9°.

2. The negative electrode active material for an electric device according to claim 1 , wherein the z is more than 27 and less than 61.

3. The negative electrode active material for an electric device according to claim 2 , wherein the y is less than 24 and the z is more than 38.

4. The negative electrode active material for an electric device according to claim 2 , wherein the x is 24 or more and less than 38.

5. An electric device comprising the negative electrode active material for an electric device set forth in claim 1 .

Assignees

• Nissan Motor

Inventors

• Miki Fumihiro
• Watanabe Manabu
• Chiba Nobutaka
• Kitaura Kei
• Wada Tohru

Classifications

• H01M4/386 Primary

  Silicon or alloys based on silicon · CPC title

• C22C13/00

  Alloys based on tin · CPC title

• C22C29/06

  based on carbides, but not containing other metal compounds · CPC title

• H01M4/42

  Alloys based on zinc · CPC title

• H01M4/387

  Tin or alloys based on tin · CPC title