Process for producing a stabilizer dispersion and process for producing a thermoplastic composition stabilized with the stabilizer dispersion

Patent metadata

Field	Value
Publication number	US-10815342-B2
Application number	US-201716307339-A
Country	US
Kind code	B2
Filing date	Jun 6, 2017
Priority date	Jun 6, 2016
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

The invention relates to a process for producing a stabilizer dispersion S, wherein the stabilizer dispersion is an aqueous composition comprising at least one phenolic stabilizer A, at least one thio co-stabilizer B, at least one surfactant C and at least one silicon oil component D. Further the present invention is directed to a process for producing a thermoplastic moulding composition, in particular an composition based on acrylonitrile butadiene styrene copolymers (ABS), using the stabilizer dispersion S.

First claim

The invention claimed is:

1. A process for producing a stabilizer dispersion S comprising:
a) at least one phenolic stabilizer A;
b) at least one thio co-stabilizer B;
c) at least one surfactant C;
d) at least one silicon oil component D;
e) optionally, at least one further component E; and
f) an aqueous phase P comprising at least 80% by weight, based on the total aqueous phase P, water,
wherein the process comprises the following steps:

i) providing an aqueous composition comprising an aqueous phase P;
ii) adding at least one thio co-stabilizer B to the aqueous composition obtained in step i), wherein the temperature of the aqueous composition is higher than or equal to the melting point of the at least one thio co-stabilizer B;
iii) adding at least one phenolic stabilizer A to the aqueous composition obtained in step ii), wherein the temperature of the aqueous composition is higher than or equal to the melting point of the at least one thio co-stabilizer B;
iv) adding at least one surfactant C;
v) adding at least one silicon oil component D and optionally at least one further component E; and
vi) homogenization of the aqueous composition obtained in steps i) to v) wherein the aqueous composition is passed at least once through at least one homogenization device, wherein a stabilizer dispersion S, consisting of a continuous phase and at least one disperse phase, formed by particles of the disperse phase, is obtained, wherein the weight median particle size D50 of disperse phase particles of the stabilizer dispersion S obtained in step vi) is less than or equal to 3 μm.

2. The process according to claim 1 , wherein the at least phenolic stabilizer A is selected from the group consisting of octadecyl 3-(3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl)propionate; a butylated reaction product of p-cresol and dicyclopentadiene according to formula (IId)

with n=1-3; 1,1,3-tris(2′-methyl-4′-hydroxy-5′-tert-butylphenyl)butane; 2,2′-methylenebis(6-(1,1-dimethylethyl)-4-methyl-phenol); 4,4′-thiobis(3-methyl-6-tert-butylphenol); and compounds of the formula (I)

wherein R 1 is methyl or ethyl, R 2 is C 2 -C 20 -alkyl, and R 3 is C 1 -C 4 -alkyl.

3. The process according to claim 1 , wherein the at least one thio co-stabilizer B is a sulfide compound selected from the group consisting of dilauryl thiodipropionate, pentaerythritol tetrakis(octyl thiodipropionate), distearyl thiodipropionate, dimyristyl thiodipropionate, pentaerythritol tetrakis(β-lauryl thiodipropionate), 2,4-bis(n-octylthio)-6-(4′-hydroxy-3′,5′-di-tert-butylanilino)-1,3,5-triazine, trimethylolpropane tris(octyl thiodipropionate), trimethylolethane tris(octyl thiodipropionate), ethylene glycol bis(lauryl thiodipropionate), and didodecyl monosulfide.

4. The process according to claim 1 , wherein the surfactant C is selected from the group consisting of sodium and potassium salts of alkylsulfonates, arylalkylsulfonates, fatty acids, and salts of fatty acids.

5. The process according to claim 1 , wherein the solid content of the aqueous composition obtained in obtained in steps i) to v) is in the range of 65 to 90% by weight, based on the total aqueous composition.

6. The process according to claim 1 , wherein the temperature of the aqueous composition in steps ii) and iii) is in the range of 50 to 100° C.

7. The process according to claim 1 , wherein the process encompasses the steps
i) and iv) providing an aqueous composition comprising the aqueous phase P and the at least one surfactant C selected from fatty acids; and
v) adding the at least one silicon oil component D and as component E at least one alkaline compound.

8. The process according to claim 1 , wherein the process is carried out in a stirred tank equipped with at least one by-pass, wherein the at least one by-pass includes one or more homogenization nozzle and wherein the homogenization in step vi) is carried out by piping the aqueous composition through the at least one by-pass.

9. The process according to claim 1 , wherein the stabilizer dispersion S comprises:
0.1 to 65% by weight, based on the total weight of the stabilizer dispersion S, of the at least one phenolic stabilizer A;
0.1 to 65% by weight, based on the total weight of the stabilizer dispersion S, of the at least one thio co-stabilizer B;
0.1 to 20% by weight, based on the total weight of the stabilizer dispersion S, of the at least one surfactant C;
0.1 to 40% by weight, based on the total weight of the stabilizer dispersion S, of the silicon oil D; and
an amount of the aqueous phase P to make the total weight of the stabilizer dispersion 100% by weight.

10. The process according to claim 1 , wherein the stabilizer dispersion S comprises:
0.1 to 65% by weight, based on the total weight of the stabilizer dispersion S, of the at least one phenolic stabilizer A;
0.1 to 65% by weight, based on the total weight of the stabilizer dispersion S, of the at least one thio co-stabilizer B;
0.1 to 20% by weight, based on the total weight of the stabilizer dispersion S, of the at least one surfactant C;
0.1 to 40% by weight, based on the total weight of the stabilizer dispersion S, of the silicon oil D;
0.01 to 30% by weight, based on the total weight of the stabilizer dispersion S, of at least one further component E; and
an amount of the aqueous phase P to make the total weight of the stabilizer dispersion 100% by weight.

Assignees

• Ineos Styrolution Group Gmbh

Inventors

• Michels Gisbert
• Jansen Ulrich
• Eisentraeger Frank
• Kaminsky Stefan

Classifications

• C08J2455/02

  Acrylonitrile-Butadiene-Styrene [ABS] polymers · CPC title

• C08J2325/12

  with unsaturated nitriles · CPC title

• C08J2483/04

  Polysiloxanes · CPC title

• C08L25/12

  with unsaturated nitriles · CPC title

• C08F279/04

  Vinyl aromatic monomers and nitriles as the only monomers · CPC title