Method for preparing a masterbatch of natural rubber and magnesium-doped silica

Patent metadata

Field	Value
Publication number	US-9505890-B2
Application number	US-201214350440-A
Country	US
Kind code	B2
Filing date	Oct 10, 2012
Priority date	Oct 11, 2011
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

Method for preparing a silica/natural rubber masterbatch, including: doping the silica with magnesium; preparing at least one dispersion of the resulting doped silica in water; bringing a natural rubber field latex into contact with the aqueous doped-silica dispersion and mixing them together so as to obtain a coagulum; recovering the coagulum; and drying the recovered coagulum so as to obtain the masterbatch.

First claim

The invention claimed is:

1. A method for preparing a masterbatch of silica/natural rubber comprising:
doping a silica with magnesium thereby obtaining a doped silica, wherein the level of magnesium doping in the silica is from 0.4 to 0.9% by weight per 100 parts by weight of silica;
preparing at least one dispersion of the resulting doped silica in water;
bringing a concentrated natural rubber latex into contact with the aqueous doped-silica dispersion, wherein the concentrated natural rubber latex and the aqueous doped-silica dispersion have a formulation pH upon contact with one another of greater than or equal to 8.5;
mixing the concentrated natural rubber latex and the aqueous doped-silica dispersion together, thereby obtaining a coagulum;
recovering the coagulum; and
drying the recovered coagulum, thereby obtaining the masterbatch.

2. The method according to claim 1 , wherein recovering the coagulum comprises filtering.

3. The method according to claim 1 , wherein the recovering of the coagulum comprises centrifuging.

4. The method according to claim 1 , wherein the silica is a precipitated silica.

5. The method according to claim 1 , wherein silica upon bringing the aqueous doped-silica dispersion and concentrated natural rubber latex into contact with each other is present in an amount between 20 phr and 150 phr (parts per one hundred parts by weight of rubber).

6. The method according claim 5 , wherein the amount of silica upon bringing the aqueous doped-silica dispersion and concentrated natural rubber latex into contact with each other is an amount between 30 phr and 100 phr.

7. The method according claim 6 , wherein the amount of silica upon bringing the aqueous doped-silica dispersion and concentrated natural rubber latex into contact with each other is an amount between 30 phr and 90 phr.

8. The method according claim 7 , wherein the amount of silica upon bringing the aqueous doped-silica dispersion and concentrated natural rubber latex into contact with each other is an amount between 30 phr and 70 phr.

9. The method according to claim 1 , further comprising adding an aqueous coupling agent dispersion before or upon bringing the aqueous magnesium-doped silica dispersion into contact with the concentrated natural rubber latex.

10. The method according to claim 1 , wherein the formulation pH is less than 10.

Assignees

• Michelin & Cie
• Michelin Rech Tech

Inventors

• De Gaudemaris Benoit
• Laffargue Geraldine
• Berriot Julien

Classifications

• C08J3/226 Primary

  using a polymer as a carrier · CPC title

• Y02T10/862

  Cross-Sectional Technologies · mapped topic

• C08K9/02

  Ingredients treated with inorganic substances · CPC title

• C08L7/02

  Latex · CPC title

• C08K3/36

  Silica · CPC title