Method for producing oligomer and catalyst

Patent metadata

Field	Value
Publication number	US-10815317-B2
Application number	US-201716084797-A
Country	US
Kind code	B2
Filing date	Feb 20, 2017
Priority date	Mar 16, 2016
Publication date	Oct 27, 2020
Grant date	Oct 27, 2020

Abstract

The present invention provides a method for preparing an oligomer and a catalyst comprising a step of oligomerizing a polymerizable monomer containing an olefin in the presence of a catalyst, which comprises (A) a complex of a diimine compound and at least one metal selected from the group consisting of Group 8 elements, Group 9 elements and Group 10 elements, (B) a mixture of a pyridine diimine compound and an iron salt and/or an iron complex, (C) methylaluminoxane and/or a boron compound, and (D) an organoaluminum compound other than methylaluminoxane and/or an organozinc compound. The components (A), (B), (C) and (D) described above are respectively as defined in the present Description.

First claim

The invention claimed is:

1. A method for preparing an oligomer, comprising:
a step of oligomerizing a polymerizable monomer comprising an olefin in the presence of a catalyst comprising
(A) a complex of a diimine compound represented by the following formula (1) and at least one metal selected from the group consisting of Group 8 elements, Group 9 elements and Group 10 elements,
(B) a mixture of a pyridine diimine compound represented by the following formula (3) and an iron salt and/or an iron complex represented by the following formula (5),
(C) methylaluminoxane and/or a boron compound, and
(D) an organoaluminum compound other than methylaluminoxane and/or an organozinc compound:

wherein Ar 1 and Ar 2 are the same or different and are respectively a group represented by the following formula (2):

wherein R 1 and R 5 are the same or different and are respectively a hydrogen atom or a hydrocarbyl group having 1 to 5 carbon atoms, the total number of carbon atoms of R 1 and R 5 is 1 or more and 5 or less, and R 2 , R 3 and R 4 are the same or different and are respectively a hydrogen atom or an electron-donating group:

wherein R′ is a hydrocarbyl group having 1 to 6 carbon atoms or an aromatic group having 6 to 12 carbon atoms, a plurality of R′ in the same molecule are the same or different, Ar 3 and Ar 4 are the same or different and are respectively a group represented by the following formula (4):

wherein R 6 and R 10 are the same or different and are respectively a hydrocarbyl group having 3 to 12 carbon atoms or an aromatic group having 6 to 12 carbon atoms, the total number of carbon atoms of R 6 and R 10 is 6 or more, and R 7 , R 8 and R 9 are the same or different and are respectively a hydrogen atom or an electron-donating group:

wherein R is a hydrocarbyl group having 1 to 6 carbon atoms or an aromatic group having 6 to 12 carbon atoms, a plurality of R in the same molecule are the same or different, Ar 5 and Ar 6 are the same or different and are respectively a group represented by the following formula (6), and Y is a chlorine atom or a bromine atom:

wherein R 11 and R 15 are the same or different and are respectively a hydrocarbyl group having 3 to 12 carbon atoms or an aromatic group having 6 to 12 carbon atoms, the total number of carbon atoms of R 11 and R 15 is 6 or more, and R 12 , R 13 and R 14 are the same or different and are respectively a hydrogen atom or an electron-donating group.

2. The method according to claim 1 , wherein a number average molecular weight (Mn) of the oligomer is 200 to 5000.

3. The method according to claim 1 , wherein the organoaluminum compound is at least one selected from the group consisting of trimethylaluminum, triethylaluminum, triisopropylaluminum, tripropylaluminum, tributylaluminum, triisobutylaluminum, trihexylaluminum, triphenylaluminum, diethylaluminum chloride, ethylaluminum dichloride and ethylaluminum sesquichloride.

4. The method according to claim 1 , wherein the organozinc compound is at least one selected from the group consisting of dimethylzinc, diethylzinc and diphenylzinc.

Assignees

• Eneos Corp

Inventors

• Aida Fuyuki
• Tagawa Kazuo

Classifications

• B01J31/22

  Organic complexes · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F4/7042 Primary

  NNN · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F110/02

  Ethene · CPC title